ISSN:
1572-8854
Keywords:
Ruthenium(II) complex
;
organoruthenium compound
;
bis(1,2-diphenylphosphino)ethane ligand
;
ruthenium-nitro complex
;
crystal structure
;
cyclopentadienyl derivative
;
methanol solvate
Source:
Springer Online Journal Archives 1860-2000
Topics:
Geosciences
,
Physics
Notes:
Abstract The title complex crystallizes in the centrosymmetric monoclinic space group C2/c (No. 15) withZ=8. The structure was refined toR=4.49% for those 2745 independent reflections with 2θ=5–50o and |F σ|〉6σ(F). Ruthenium-ligand distances are as follows: Ru-P=2.284(2) and 2.286(2) Å, Ru-NO2=2.049(6) Å and Ru-C(Cp)=2.210(10)-2.246(9) Å. Bond lengths within the nitro ligand are N(1)-O(1)=1.226(10) Å and N(1)-O(2)=1.244(10) Å. The methanol of solvation is ordered but is subject to large thermal vibrational motions.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01668310
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