ISSN:
1572-8854
Keywords:
Ruthenium(II) complex
;
tri-n-propylphosphine
;
bipyridyl
;
crystal structure
;
disorder
Source:
Springer Online Journal Archives 1860-2000
Topics:
Geosciences
,
Physics
Notes:
Abstract The complexcis-[Ru(bpy)2(PPr3)Cl+][ClO 4 − ] · 0.5 (toluene) crystallizes as a racemate in the monoclinic space group P21/n. Both the PPr3 ligand and the toluene of crystallization are subject to disorder. Ruthenium—ligand distances are: Ru−PPr3=2.348(2) Å, Ru−Cl=2.426(2) Å and Ru−N(bpy)=2.035(6)–2.112(5) Å.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01991962
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