ISSN:
0268-2605
Keywords:
Clusters
;
thermal decomposition
;
conductivity
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The conductivity of microcrystalline mono- or biscarbyne capped tricobalt clusters and a preliminary study of the physical properties of the thermally decomposed materials are presented. Solid materials with high conductivites are produced by the controlled decomposition of the non- conducting carbonyl clusters in which there are two cluster units or an alkyne/cluster system. Processes leading to conducting solids were studied by thermogravimetric, mass spectral, DRIFT and SEM techniques. Bi-capped clusters are thermally stable insulators but it is suggested that doped materials will show increased conductivity.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/aoc.590040509
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