ISSN:
1572-879X
Keywords:
Shape selectivity
;
epoxidation of alkenes
;
titanium catalyst
;
catalyst pore size
;
titanosilicate catalyst
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Reactant shape selectivity of supported titanium catalysts for epoxidation of cyclohexene and 2-hexene has an excellent correlation with the pore diameter of the catalysts. With titanosilicate the preference to cis isomer epoxidation is small compared to TiO2-SiO2 probably because of the restriction of its diffusion imposed by the zeolite micropore structure.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00772079
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