ISSN:
1572-8927
Keywords:
Thermodynamics
;
electrolyte mixtures
;
activity coefficients
;
osmotic coefficients
;
Pitzer equations
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The parameters for symmetrical mixing of ions of the same sign in the virial-coefficient (Pitzer) system are evaluated from literature data for 25°C in a manner consistent with the higher-order limiting law of Friedman. Twenty-four systems involve cation mixing with a common anion and fourteen involve anion mixing with a common cation. Heat of mixing data were similarly treated in a recent publication; the results give the temperature coefficients of some of these same parameters. The combined results yield the mixing parameters as functions of temperature on a basis both self-consistent and in accord with the limiting law. The results also yield, for a few systems without a common ion, predicted values in good agreement with experimental data.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00649736
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