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  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 32 (1994), S. 1217-1227 
    ISSN: 0887-6266
    Keywords: PMMA ; ethanol ; crack healing ; Case I ; Case II ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The crack healing induced by ethanol in poly(methyl methacrylate) (PMMA) has been studied at temperatures of 40-60°C. Crack healing occurs because the effective glass transition temperature of PMMA is reduced to below the test temperature by ethanol plasticization. It is found that crack closure rate is constant at a given temperature. The fracture strength of healed PMMA is lower than that of the original samples. By comparing the fracture stress with the morphology of the crack edge on the PMMA surface, we found that a high degree of swelling is responsible for the incomplete recovery of mechanical strength. The fractography of the completely healed sample shows a very different fracture morphology from that of virgin PMMA. The transport of ethanol in PMMA also is studied. At lower temperatures, transport is described by ideal Case II behavior. As the temperature increases, the kinetics shift from ideal Case II to anomalous behavior. The first stage of crack healing is controlled by Case I transport. © 1994 John Wiley & Sons, Inc.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 58 (1995), S. 2155-2159 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Electrically conductive polypyrrole (PPy)/poly(p-phenylene terephthalamide) (PPTA) composite fibers have been prepared by continuous vapor phase polymerization at a speed of 0.5 ∼ 1.5 m/min. The main parameters have been examined, and the conducting fibers with the best properties of electrical conductivity 0.68 s/cm, tensile strength 2731 N/mm2, and the elongation at break 4.8% were obtained by using FeCl3 · 6H2O as the oxidizing agent. The results of elemental analysis, wide-angle X-ray diffraction analysis and SEM of the composite fibers are also reported. © 1995 John Wiley & Sons, Inc.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Limitation Availability
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