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  • 1
    Electronic Resource
    Electronic Resource
    Model filled polymers. V. Synthesis of crosslinked monodisperse polymethacrylate beads (1992)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 30 (1992), S. 137-144 
    Details
    ISSN: 0887-624X
    Keywords: fillers ; emulsifier free emulsion polymerization ; monodisperse beads ; polymethacrylates ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Monodisperse polymethacrylate beads of varied size and crosslink density are prepared by emulsion copolymerization of methacrylate and divinyl monomers in the absence of emulsifiers. The sizes of polybutyl and polyethyl methacrylate beads decreased with increasing polymerization temperature, while polymethyl methacrylate beads were largely unchanged in size. The molar mass of polymer in polymethyl metnacrylate beads markedly exceeded that in polystyrene beads. The rate of polymerization increased, and bead size decreased, with increasing initiator concentration or decreasing monomer concentration. The polymethacrylate beads are used as filler particles in polymer composites.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1992.080300118
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  • 2
    Electronic Resource
    Electronic Resource
    Mn(III) - porphyrin-based thiocyanate-selective membrane electrodes: Characterization and application in flow injection determination of thiocyanate in saliva (1989)
    Weinheim : Wiley-Blackwell
    Electroanalysis 1 (1989), S. 477-484 
    Details
    ISSN: 1040-0397
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The response properties of a new thiocyanate-selective solvent-polymeric membrane electrode are reported. The membrane contains (5,10,15,20-tetrakis(2,4,6-triphenylphenyl)porphyrinato)manganese(III) chloride (Mn[TPPP]CI) in a plasticized polyvinyl chloride matrix. The electrode deviates from the Hofmeister selectivity pattern by responding to thiocyanate preferentially over inorganic anions (perchlorate, chloride, iodide, and bromide) and several organic anions often present in biological samples (ascorbate, citrate, urate, and salicylate). The performance of this electrode as an ion-selective detector in a low-dispersion, flow-injection system is also evaluated. While selectivity in such a nonequilibrium flow arrangement is found to be somewhat different than that observed under equilibrium conditions, the electrode's response and selectivity is still adequate to allow for measurement of thiocyanate in biological samples. This application is demonstrated via the flow-injection analysis (FIA) detection of thiocyanate in 22 human saliva samples with good correlation to a classical colorimetric method (r = 0.981).
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/elan.1140010602
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Isolation of predominantly submicron-sized UHMWPE wear particles from periprosthetic tissues (1995)
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 29 (1995), S. 127-131 
    Details
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: A method of tissue digestion using sodium hydroxide was applied to the isolation and recovery of ultra-high-molecular-weight polyethylene (UHMWPE) particles from tissues around failed total hip replacements. Density gradient ultracentrifugation of the digested tissues was performed to separate the UHMWPE from cell debris and other particulates. Fourier transform infrared spectroscopy and differential scanning calorimetry (DSC) verified that the recovered particles were UHMWPE. When viewed by scaning electron microscopy, individual particles were clearly observed and were either rounded or elongated. The majority were submicron in size. The application of this method to the study or particles from periprosthetic tissues may elucidate aspects of biomaterial particles size and shape that are important to the biologic response to, and clinical outcome of, total joint replacement. © 1995 John wiley & Sons, Inc.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jbm.820290118
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