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  • Polymer and Materials Science  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 41 (1990), S. 2285-2300 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The grafting of maleic anhydride (MAn) to low density polyethylenes (PEs) dissolved in 1,2-dichlorobenzene (DCB) has been studied. Grafting was successful at temperatures of about 160°C both in air without initiator and under nitrogen with the radical initiator 2,5-di(t-butylperoxy)-2,5-dimethyl-3-hexyne (LPO). The presence of succinic anhydride grafts was shown by FTIR spectroscopy of the product; 1H-NMR spectroscopy indicates that the grafts consist of single succinic anhydride units. The graft content was determined by nonaqueous titration, and the extent of crosslinking inferred from the melt flow rates (MFR) of the products. The effects of concentration of initiator, MAn, and PE on the graft content were determined; the influence of PE structure, reaction time, and temperature was also studied. Melt blending of the grafted PE with polystyrene containing oxazoline functional groups (OPS) was investigated using a Rheomix mixer. The interpolymer reaction which occurs during blending was studied by means of FTIR, and the morphology of the blends by scanning electron microscopy (SEM). Information was also gained from the change in torque viscosity during the blending process.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0730-6679
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Blending of immiscible polymers offers attractive opportunities for developing new materials with useful combinations of properties. However, simple blends often have poor mechanical properties and unstable morphologies. Compatibilization of such blends is necessary. Preformed graft or block copolymers have been traditionally added to act as compatibilizers. Another route, however, is to generate these copolymer compatibilizers in situ during melt blending using functionalized polymers. In this review, a variety of reactive polymers that have been utilized in the reactive compatibilization of polymer blends is examined. They are classified into six major categories according to the types of reactive groups they have, namely, maleic anhydride, carboxylic acids, carboxylic acid derivatives, primary and secondary amines, hydroxyl and epoxide, and reactive groups capable of ionic bonding. Their preparation methods and applications and the chemical reactions they undergo during melt blending are presented. © 1992 John Wiley & Sons, Inc.
    Additional Material: 8 Tab.
    Type of Medium: Electronic Resource
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