Keywords:
Organometallic compounds.
;
Organometallic chemistry.
;
Electronic books.
Description / Table of Contents:
This Specialist Periodical Report aims to reflect the growing interest in the potential of organometallic chemistry.
Type of Medium:
Online Resource
Pages:
1 online resource (321 pages)
Edition:
1st ed.
ISBN:
9781847558503
Series Statement:
Issn Series
URL:
https://ebookcentral.proquest.com/lib/geomar/detail.action?docID=1185900
DDC:
547.05
Language:
English
Note:
Organometallic Chemistry -- Contents -- Groups 1 and 11: The Alkali and Coinage Metals -- 1 Alkali Metals -- 1.1 Introduction -- 1.2 Alkyl Derivatives -- 1.3 Alkenyl, Allyl, Vinyl, Alkynyl and Related Derivatives -- 1.4 Aryl Derivatives -- 1.5 Cyclopentadienyl and Related Derivatives -- 2 Copper, Silver and Gold -- 2.1 Introduction -- 2.2 Copper Compounds -- 2.3 Silver Compounds -- 2.4 Gold Compounds -- References -- Group 2 (Be-Ba) and Group 12 (Zn-Hg) -- 1 Scope and Organisation of the Review -- 2 Group 2 -- 3 Group 12 -- References -- Scandium, Yttrium and the Lanthanides -- 1 Introduction -- 2 Hydrocarbyls of Various Kinds -- 3 Half Sandwich Cyclopentadienyl Complexes -- 4 Metallocene Derivatives -- 5 Ansa Metallocene Ligand Chemistry -- 6 Indenyl and Fluorenyl Complexes -- 7 Functionalized Cyclopentadienyls and Related Ligands -- 7.1 Functional Groups with Nitrogen Donors -- 7.2 Functional Groups with Group 16 Donors -- 8 Hydride Complexes -- 9 Allyls -- 10 Cyclo-Octatetraenyl Complexes -- 11 Nitrogen-Donor Ancillaries -- 11.1 Ketiminate Chemistry -- 11.2 Amido Ancillary Groups -- 12 Organophosphorus Supporting Ligands -- 13 Aryloxide Ancillaries -- 14 Compounds with Boron-Based Ligands -- 15 Materials Chemistry -- 16 Applications in Organic Synthesis -- 16.1 Stoichiometric Reactions -- 16.2 Catalysis -- 17 Polymerization Catalysis -- 17.1 Neutral Olefins and Dienes -- 17.2 Acrylate and Polar Monomer Polymerization -- 18 Theoretical and Computational Studies -- 18.1 Structure and Bonding -- 18.3 Agostic Interactions -- 18.4 Interaction of Small Molecules -- 18.5 Calculating Chemical Reactivity -- 18.6 Pretend Molecules -- 19 Spectroscopic Studies -- References -- Carboranes, Including Their Metal Complexes -- 1 Introduction -- 2 Theoretical and Computational Studies -- 3 Heteroboranes, Carboranes and Heterocarboranes -- 3.1 {B3 and B4}.
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3.2 {B8, B9 and B10} -- 3.3 {B12} -- 3.4 {PCB8} -- 3.5 {SB8} -- 3.6 {CB6, CB7, CB8, CB9} -- 3.7 {CB11} -- 3.8 {NC2B7} -- 3.9 {As2C2B7} -- 3.10 {C2B9} -- 3.11 {C2B10} -- 3.12 {C2B11} -- 4 Metallaboranes and Metallacarboranes -- 4.1 {MB3 and MB4} -- 4.2 {MB5} -- 4.3 {MB6 and MB8} -- 4.4 {MCB8} -- 4.5 {MCB9} -- 4.6 {MCB10} -- 4.7 {MC2B4} -- 4.8 {C2B8} -- 4.9 {MC2B9} -- 4.10 {MC2B10} -- 4.11 {MPC2B8} -- 4.12 {M2C3B8} -- 4.13 {exo-C2B9} -- 5 Biological Carborane Chemistry and BNCT -- 6 Weakly Coordinating Anions and Catalysis -- 7 Crystal Engineered Supramolecular and Polymeric (Metalla)carborane Materials -- References -- Group III - B, Al, Ga, In, Tl -- 1 General -- 2 Boron -- 2.1 B(C6F5)3 and Related Boranes -- 2.2 Borate Anions -- 2.3 Ligand Systems Based Around a Tri- or Tetra-Coordinate Boron Centre -- 2.4 Boron Hydrides -- 2.5 Boron-Based Ligand Systems -- 2.6 Boratabenzenes and Related Systems -- 2.7 Boron-Containing Materials and Sensors -- 2.8 Boronic Acids/Esters and Suzuki Type Coupling Reactions -- 2.9 Boron Functionalized Cyclopentadienyl Ligands -- 2.10 Miscellaneous -- 3 Aluminium -- 3.1 Hydrides -- 3.2 Aluminate Complexes -- 3.3 Aluminium Derivatives Containing Bonds to Group 15 Donors -- 3.4 Aluminium Derivatives Containing Bonds to Oxygen -- 3.5 Aluminium Organometallics in Organic Synthesis -- 3.6 Miscellaneous Examples -- 4 Gallium -- 4.1 Subvalent Gallium Species and Clusters -- 4.2 Complexes Containing Subvalent Gallium Species as Ligands -- 4.3 Arylgallium Species -- 4.4 Gallium Hydrides -- 4.5 Gallium Derivatives Containing Bonds to Group 15 or Group 16 Elements -- 4.6 Miscellaneous -- 5 Indium -- 5.1 Subvalent Indium and Indium Clusters -- 5.2 Indium Derivatives Containing Bonds to Groups 15 or 16 -- 5.3 Miscellaneous Examples -- 6 Thallium -- References -- Group 14: Silicon, Germanium, Tin and Lead -- 1 Overview.
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2 Multiple Bonds in Group 14 -- 3 Tetrylenes -- 4 Radicals, Cations and Anions -- 5 Homoaromatics and Other Ring Systems -- 6 π-Bonded Complexes -- 7 Group 14 Organometallics as Ligands at Transition Metal Centres -- References -- Recent Advances in the Chemistry of Phosphaalkynes: Building Blocks for Novel Organophosphorus Compounds -- 1 Introduction -- 2 Synthesis of New Phosphaalkynes -- 3 Phosphagrignard Reagents and Related Compounds -- 4 Synthesis of Four-Membered Rings -- 5 Synthesis of Higher Phosphaalkyne Oligomers -- 6 Synthesis of Cluster Compounds -- 7 Conclusions and Outlook -- References -- Organo-Transition Metal Cluster Complexes -- Abbreviations -- 1 Introduction -- 2 General Reviews -- 3 Spectroscopic Studies -- 4 Theory -- 5 Structural Studies -- 6 High-Nuclearity Clusters -- 6.1 Homonuclear High-Nuclearity Clusters -- 6.2 Heteronuclear High-Nuclearity Clusters -- 7 Group 6 -- 8 Group 7 -- 9 Group 8 -- 9.1 Iron -- 9.2 Ruthenium -- 9.3 Osmium -- 9.4 Mixed-Metal Clusters Containing Only Group 8 Metals -- 9.5 Group 8 Clusters in Catalysis -- 10 Group 9 -- 10.1 Cobalt -- 10.2 Rhodium -- 10.3 Iridium -- 10.4 Group 9 Mixed-Metal Clusters -- 11 Group 10 -- 12 Group 11 -- 13 Mixed-Metal Clusters -- 13.1 Group 5 -- 13.2 Group 6 -- 13.3 Group 7 -- 13.4 Group 8 -- 13.5 Group 9 -- 13.6 Group 10 -- 13.7 Clusters Containing Three Different Metals -- References -- Complexes Containing Metal-Carbon σ-Bonds of the Groups Iron, Cobalt and Nickel, Including Carbenes and Carbynes -- 1 Introduction -- 2 Reviews and Articles of General Interest -- 3 Metal-Carbon σ-Bonds Involving Group 8, 9 and 10 Metals -- 3.1 The Iron Triad -- 3.2 The Cobalt Triad -- 3.3 The Nickel Triad -- 4 Carbene and Carbyne Complexes of Group 8, 9 and 10 -- References -- Organic Aspects of Organometallic Chemistry -- 1 Introduction -- 2 Methods for C-C Bond Formation.
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3 Methods for C-X Bond Formation -- 4 Metal Mediated Cyclisation and Cycloisomerisation Reactions -- 5 Nicholas and Pauson-Khand Type Reactions -- References.
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