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  • Mantle geochemistry  (2)
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  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 10 (2009): Q03006, doi:10.1029/2008GC002324.
    Description: We report 87Sr/86Sr and 143Nd/144Nd data on clinopyroxenes recovered from 10 ocean island lavas from three different hot spots (Samoa, Society, and Cook-Austral island chains). The clinopyroxenes recovered from eight of the 10 lavas analyzed in this study exhibit 87Sr/86Sr disequilibrium with respect to the host lava. The 87Sr/86Sr ratios in clinopyroxene separates are 95–3146 ppm (0.0095–0.31%) different from their respective host whole rocks. Clinopyroxenes in three lavas have 143Nd/144Nd ratios that are 70–160 ppm (0.007–0.016%) different from the host lavas. The 87Sr/86Sr and 143Nd/144Nd disequilibrium in one lava (the oldest lava considered in this study, Mangaia sample MGA-B-47) can be attributed to posteruptive radiogenic ingrowth, but the isotope disequilibrium in the other, younger lavas cannot be explained by this mechanism. In five of the lava samples, two populations of clinopyroxene were isolated (black and green, separated by color). In four out of five of these samples, the 87Sr/86Sr ratios of the two clinopyroxene populations are isotopically different from each other. In addition to 87Sr/86Sr disequilibrium, the two clinopyroxene populations in one of the lavas (Tahaa sample TAA-B-26) have 143Nd/144Nd ratios that are ∼100 ppm different from each other. Given the resilience of clinopyroxene to seawater alteration and the likelihood that the Sr and Nd isotope composition of fresh clinopyroxene separates provides a faithful record of primary magmatic compositions, the clinopyroxene-clinopyroxene isotope disequilibrium in these four lavas provides strong evidence that a mechanism other than seawater alteration has generated the observed isotopic disequilibrium. This study confirms the isotopic diversity in ocean island lavas previously observed in olivine-hosted melt inclusions. For example, the Sr isotopic variability previously observed in olivine-hosted melt inclusions is mirrored by the isotopic diversity in clinopyroxenes isolated from many of the same Samoan lavas. The isotopic data from melt inclusions and clinopyroxenes are not consistent with shallow assimilation of sediment or with entrainment of xenocrystic clinopyroxene from the oceanic crust or upper mantle. Instead, the data are interpreted as reflecting isotopic heterogeneity in the mantle sources of the lavas. The isotopic diversity in clinopyroxenes and melt inclusions suggests that a single lava can host components derived from isotopically diverse source regions.
    Description: NSF grant EAR-0509891 to SRH is gratefully acknowledged.
    Keywords: Clinopyroxene ; Melt inclusion ; Mantle geochemistry ; Sr-87/Sr-86 ; Nd-143/Nd-144 ; Trace elements
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
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  • 2
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2014. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 15 (2014): 2301–2318, doi:10.1002/2013GC005221.
    Description: The Samoan islands of Ta'u and Ofu/Olosega (Ofol hereafter) are single shield volcanoes that have erupted alkali basalt for the past 70 and 440 kyr, respectively. They are 20 km apart, and are the easternmost subaerial expressions of the Samoan plume. The isotopic data for these islands are published; we report here the first major and trace element data for Ofol. The two islands are similar isotopically and in trace elements. Their high 3He/4He marks them as being a FOZO mantle end-member. By comparing data from both volcanoes, we test the efficacy of melting models in constraining the mantle compositions and their P-T of melting. We show that the mantle sources are similar, with spidergrams that peak at Ta (4× BSE), and Lu ∼0.5× BSE. Melts and mantle sources both have Lu/Hf ratios that are too low to support measured 176Hf/177Hf ratios, pointing to a young enrichment event in the mantle source. Degrees of melting are 6.5% for Ta'u and 5.2% for Ofol. P-T of melting show a wide, overlapping range, but define a precise array; average values are 1475°C—77 km for Ta'u and 1550°C—110 km for Ofol. The deepest P-T estimate is 4.2 GPa and 1550°C. The P-T array is either a melting adiabat, or a mixing line of melts equilibrated at various depths. Kinetic modeling shows melt re-equilibration will be likely for ascent velocities (m/yr) less than 40/(conduit radius in cm)2. P-T estimates for melting may typically be minimum values.
    Description: We thank the National Science Foundation for their many years of support of our studies in Samoa (OCE- 0351437, EAR-0509891, EAR-0652707, EAR-0318137, OCE-1153894).
    Description: 2014-12-06
    Keywords: Mantle geochemistry ; Mantle plume ; Samoa ; Isotope geochemistry
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/msword
    Format: application/pdf
    Format: application/vnd.ms-excel
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