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  • 1
    ISSN: 1437-3262
    Keywords: Key words Iron ; Manganese ; Early diagenesis ; Redox cycling ; Surface sediment ; Argentine Basin
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Pore water and solid phase from surface sediments of the continental slope off Uruguay and from the Argentine Basin (southwestern Atlantic) were investigated geochemically to ascribe characteristic early diagenetic reactions of iron and manganese. Solid-phase iron speciation was determined by extractions as well as by Mössbauer spectroscopy. Both methods showed good agreement ( 〈6% deviation) for total-Fe speciation. The proportion of easy reducible iron oxyhydroxide relative to total-Fe oxides decreased from the continental slope to the deep sea which is attributed to an increase in crystallinity during transport as well as to a general decrease of iron mobilization. The product of iron reoxidation is Fe oxyhydroxide which made up less than 5% of total Fe. In addition to this fraction, a proportion of smectite bound iron was found to be redox reactive. This fraction made up to 10% of total Fe in sediments of the Argentine Basin and was quantitatively extracted by 1 N HCl. The redox reactive Fe(+II) fraction of smectite was almost completely reoxidized within 24 h under air atmosphere and may therefore considerably contribute to iron redox cycling if bioturbation occurs. In the case of the slope sediments we found concurrent iron and manganese release to pore water. It is not clear whether this is caused by dissimilatory iron and manganese reduction at the same depth or dissimilatory iron reduction alone inducing Mn(+IV) reduction by (abiotic) reaction with released Fe2+. The Argentine Basin sediment showed a significant manganese solid-phase enrichment above the denitrification depth despite the absence of a distinct pore-water gradient of Mn. This implies a recent termination of manganese mobilization and thus a non-steady-state situation with respect to sedimentation or to organic carbon burial rate.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2021-10-01
    Description: We present a dating method for deep-sea sediments that uses the natural radionuclide 230Th (half-life 75,380 years) in analogy to 210Pb with the constant rate of supply (CRS) model. Using an example from the western Indian sector of the Southern Ocean, we demonstrate how sets of values of 230Th, 232Th, and U isotopes activities can supply absolute age information for the last ~450,000 years, given a sufficient precision, resolution, and depth coverage of the analytical data in a suitable core. An assessment of age uncertainties resulting from analytical errors using a Monte Carlo approach and an analytical solution for error propagation shows good agreement. We also investigate errors due to a violation of model assumptions by variable focusing of deep-sea sediments by means of a simulated core. Finally, we use real examples from independently dated sediment cores containing carbonate, using previously existing 230Th data, to test the approach. The consideration of the systematic errors and the examples suggests that the uncertainties are smallest in the central part of the record and that the variability of focusing conditions controls the accuracy of the 230Th CRS dates. Our own example demonstrates an excellent agreement of the 230Th CRS method with independent age constraints, adding an important tool for dating marine records that does not depend on the presence of carbonate. The obtained values are also suitable to calculate 230Th-normalized preserved vertical rain rates of various sedimentary compounds, permitting an improved quantitative comparison of marine paleorecords with other archives like ice cores.
    Keywords: 551.701 ; dating method ; deep-sea sediments ; dust flux ; opal flux ; Southern Ocean
    Language: English
    Type: map
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