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  • Fourier transform infrared spectrometry  (1)
  • Gas hydrate  (1)
  • Heliconius pachinus  (1)
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  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © The Author(s), 2006. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Journal of Petroleum Science and Engineering 56 (2007): 127-135, doi:10.1016/j.petrol.2006.02.003.
    Description: To improve our understanding of the interaction of methane gas hydrate with host sediment, we studied: (1) the effects of gas hydrate and ice on acoustic velocity in different sediment types, (2) effect of different hydrate formation mechanisms on measured acoustic properties (3) dependence of shear strength on pore space contents, and (4) pore-pressure effects during undrained shear. A wide range in acoustic p-wave velocities (Vp) were measured in coarse-grained sediment for different pore space occupants. Vp ranged from less than 1 km/s for gascharged sediment to 1.77 - 1.94 km/s for water-saturated sediment, 2.91 - 4.00 km/s for sediment with varying degrees of hydrate saturation, and 3.88 - 4.33 km/s for frozen sediment. Vp measured in fine-grained sediment containing gas hydrate was substantially lower (1.97 km/s). Acoustic models based on measured Vp indicate that hydrate which formed in high gas flux environments can cement coarse-grained sediment, whereas hydrate formed from methane dissolved in the pore fluid may not. The presence of gas hydrate and other solid pore-filling material, such as ice, increased the sediment shear strength. The magnitude of that increase is related to the amount of hydrate in the pore space and cementation characteristics between the hydrate and sediment grains. We have found, that for consolidation stresses associated with the upper several hundred meters of subbottom depth, pore pressures decreased during shear in coarse-grained sediment containing gas hydrate, whereas pore pressure in fine-grained sediment typically increased during shear. The presence of free gas in pore spaces damped pore pressure response during shear and reduced the strengthening effect of gas hydrate in sands.
    Description: This work was supported by the Coastal and Marine Geology, and Energy Programs of the U.S. Geological Survey and funding was provided by the Gas Hydrate Program of the U.S. Department of Energy.
    Keywords: Acoustic modeling ; Acoustic velocity ; Cementation ; Gas hydrate ; Physical properties ; Shear strength
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
    Format: application/pdf
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Cellular and molecular life sciences 45 (1989), S. 1006-1008 
    ISSN: 1420-9071
    Keywords: Butterfly ; neotropical ; Heliconius pachinus ; fourteen-membered lactone
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary A fourteen-membered lactone,(R)-(Z,E)-9,11-octadecadien-13-olide, was isolated from extruded abdominal glands of a Neotropical, nymphalid butterfly,Heliconius pachinus (Lepidoptera). This compound was obtained from mature adults of both sexes, but was not detected in young adults or pupae.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Microchimica acta 93 (1987), S. 47-62 
    ISSN: 1436-5073
    Keywords: Fourier transform infrared spectrometry ; chromatography ; interfacing
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Most previous interfaces between a Chromatograph and an FT-IR spectrometer have been applicable to only one type of chromatograph-gas, liquid, or supercritical fluid. In this paper, the similarities and differences between various chromatography/FT-IR interfaces are described, and an interface which should be equally applicable to all three types of chromatography is proposed. In each case, the mobile phase is eliminated while the eluting components are condensed in a small area on a moving substrate. The spectra are then measured using an FT-IR microscope. The methods by which the mobile phase is eliminated depend on the nature of the chromatography, while the infrared sampling technique is determined by the nature of the substrate. The relative merits of transmission, reflection-absorption, diffuse reflection, and diffuse transmission spectrometry are discussed.
    Type of Medium: Electronic Resource
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