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Methylation of tin(II) and lead(II) in sediment by carbanion donors (1987)

Rapsomankis, Spyridon ; Donard, Olivier F X ; Weber, James H

New York, NY [u.a.] : Wiley-Blackwell

Applied Organometallic Chemistry 1 (1987), S. 115-118

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ISSN: 0268-2605

Keywords: Factorial experiment ; Methylcobalamin ; Model Cobalamins ; Methyltins ; Methylleads ; Methylmetals ; Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: A factorial experimental design determined separate and combined effects of MeCoB12 (methylcobalamin) and Me2Co(N4)+ (a methylcobalamin model) on methylation of Sn(II) and Pb(II) in sediment matrices. Total methyltin yields ranged from 1.4% to 3.2%, and total methyllead yields varied from 0.037% to 0.11%. No methylmetal products occurred in the absence of Me2Co(N4)+.

Additional Material: 2 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/aoc.590010203

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