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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Reaction kinetics and catalysis letters 67 (1999), S. 95-102 
    ISSN: 1588-2837
    Keywords: CuO−SiO2gel ; methanol dehydrogenation ; methyl formate
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract CuO−SiO2 gel catalysts were prepared by sol-gel method and were characterized by UV-Visible diffuse reflectance spectroscopy (DRS), X-ray diffraction (XRD) and temperature-programmed reduction (TPR). It was found that the copper loadings have a strong influence on the reduction and catalytic properties of CuO−SiO2 gels. A great part of copper oxide is highly dispersed as confirmed by TPR, XRD and DRS data. The catalysts are shown to be active and selective toward methyl formate formation in methanol dehydrogenation due to the presence of highly dispersed copper over SiO2.
    Type of Medium: Electronic Resource
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