ISSN:
0022-3832
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The copolymerizations of N-vinylsuccinimide (VSI) and of N,N-methyl vinyl p-toluenesulfonamide (VSA) with vinyl acetate (VAc), acrylonitrile (AN), stryrene (St), methyl acrylate (MA), methyl methacrylate (MMA), and n-butyl vinyl ether (BVE) were examianed at 60°C., using benzoyl peroxide or azobisiobutyronitrile as initiator. The monomer reactivity ratios and the monomer reactivity factors of VSI and VSA were as follows. VSI as monomer 1: r1 = 15, r2 = 0 (VBE); r1 = 0.09, r2 = 7.0 (St); r1 = 6.05, r2 = 0.185 (VAc); r1 = 0.4. r2 = 1.2 (MA); r1 = 0.16, r2 = 0.54 (AAAN), Q1 = 0.15, e1M/s = -0.26. VSA as monomer 1: r1 = 0, r2 = 0.42 (AN); r1 = 0, r2 = 4.68 (MMA) r1 = 0, r2 = 12.3 (St); Q1 = 0.092, e2 = -0.87. The difference in copolymeizability between VSI and VSA sesms to arise primarily from the difference in thieir polarity factors.
Additional Material:
11 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1959.1203713116
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