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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 60 (1996), S. 87-93 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The mechanism of enhanced PVC impact strength of poly(vinyl chloride) modified by an acrylic graft copolymer was studied by the three-point bending test on a U-notched bar. In the mechanism, the void formation from the modifier released the constrained strain. The release suppresses the stress below the fibril strength in the material; consequently, stable deformation can develop over a large area and, thus, the impact strength of PVC modified by the acrylic graft copolymer is improved. © 1996 John Wiley & Sons, Inc.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 62 (1996), S. 1387-1393 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effects of the mechanical properties of an acrylic graft copolymer and a silicone/acrylic composite rubber graft copolymer on the toughening of poly(vinyl chloride) (PVC) are examined. In the experiment for improvement of impact resistance of PVC, toughness of the blend polymer of a silicone/acrylic composite rubber graft copolymer is improved remarkably. The effect is attributed to the suppression of stress concentration below the fibril strength of the polymer alloy effectively by releasing the constraint of strain resulting from easy void formation at low stress. © 1996 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 37 (1959), S. 215-227 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The copolymerizations of N-vinylsuccinimide (VSI) and of N,N-methyl vinyl p-toluenesulfonamide (VSA) with vinyl acetate (VAc), acrylonitrile (AN), stryrene (St), methyl acrylate (MA), methyl methacrylate (MMA), and n-butyl vinyl ether (BVE) were examianed at 60°C., using benzoyl peroxide or azobisiobutyronitrile as initiator. The monomer reactivity ratios and the monomer reactivity factors of VSI and VSA were as follows. VSI as monomer 1: r1 = 15, r2 = 0 (VBE); r1 = 0.09, r2 = 7.0 (St); r1 = 6.05, r2 = 0.185 (VAc); r1 = 0.4. r2 = 1.2 (MA); r1 = 0.16, r2 = 0.54 (AAAN), Q1 = 0.15, e1M/s = -0.26. VSA as monomer 1: r1 = 0, r2 = 0.42 (AN); r1 = 0, r2 = 4.68 (MMA) r1 = 0, r2 = 12.3 (St); Q1 = 0.092, e2 = -0.87. The difference in copolymeizability between VSI and VSA sesms to arise primarily from the difference in thieir polarity factors.
    Additional Material: 11 Tab.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Letters 3 (1965), S. 569-571 
    ISSN: 0449-2986
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Limitation Availability
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