ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
X-ray analysis of a crystalline product obtained by electrochemical oxidation of the Ni(II)-seco-corrinoid 1 has established the structure as that of a 1,19 oxygen-bridged porphyrinoid 2. The crystals (perchlorate salt of 2) are triclinic, space group P1, with a = 10.205, b = 11.616, c = 14.52Å, α = 115.30, β = 107.34, γ = 85.90°, Z = 2. The structure was solved by the heavy-atom method and refined by full-matrix least-squares analysis to a final R factor of 9.4%. Some features of the molecular structure are discussed.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19760590547
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