Keywords:
Electron paramagnetic resonance.
;
Electronic books.
Description / Table of Contents:
Reflecting the growing volume of published work in this field, researchers will find this book an invaluable source of information on current methods and applications.
Type of Medium:
Online Resource
Pages:
1 online resource (297 pages)
Edition:
1st ed.
ISBN:
9781847553522
Series Statement:
Issn Series
URL:
https://ebookcentral.proquest.com/lib/geomar/detail.action?docID=1185460
DDC:
538.364
Language:
English
Note:
Electron Spin Resonance -- Contents -- Chapter 1 Organic Radical Ions -- 1 Introduction -- 2 Bibliography -- 3 General Technique -- 4 Calculations of Hyperfine Coupling Constants -- 5 Radical Cations -- 5.1 Reviews -- 5.2 Experimental Methods -- 5.3 π-Systems -- 5.4 Alkanes -- 5.5 Heteronuclear Radical Cations -- 5.6 Reactivity of Radical Cations -- 6 Radical Anions -- 6.1 Experimental Methods -- 6.2 Carbonyl and Thiocarbonyl Compounds -- 6.3 Alkenes -- 6.4 Radicals Centred on Heteroatoms -- 6.5 Cyclic π-Systems -- 6.6 Counterion Interactions -- 6.7 Quinones -- 6.8 Heteroaromatic Compounds -- 7 References -- Chapter 2 Organic and Organometallic Free Radicals -- 1 Introduction -- 2 Carbon-centred Radicals -- 2.1 Structure -- 2.2 Rearrangements -- 2.3 Fragmentation, Atom Abstraction and Radical Addition -- 3 Nitrogen-centred Radicals -- 4 Oxygen-centred Radicals -- 5 Nitroxides and Spin Trapping -- 5.1 Nitroxides -- 5.2 Nitroso Compounds -- 5.3 Nitrones -- 5.4 Miscellanea -- 6 Developments in Theory -- 7 Acknowledgement -- 8 References -- Chapter 3 EPR and ENDOR of Metalloproteins -- 1 Introduction -- 2 Copper -- 2.1 Blue Copper Sites -- 2.2 Type 2 Copper Sites -- 2.3 Binuclear Sites and Multi-centered Copper Proteins -- 3 Iron -- 3.1 Non-heme Iron Proteins -- 3.2 Heme-iron Proteins -- 3.3 Iron-Sulfur Proteins -- 4 Nickel -- 5 Molybdenum and Tungsten -- 6 Vanadium -- 7 Manganese -- 8 Conclusions -- 9 Acknowledgements -- 10 References -- Chapter 4 Spin Labels and Spin Probes in Polymers -- 1 Introduction -- 2 Structure of Polymer Coil -- 2.1 Determination of Conformational State and Polymer Chain Sizes of Spin Labelled Macromolecules in Solids -- 2.2 Spatial Organization of Polymer-metal Coils in Liquid Solutions -- 3 Polymer solutions -- 3.1 Segmental Mobility of Spin Labelled Macromolecules -- 3.1.1 Poly(acrylic) and Poly(methacrylic) Acids.
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3.1.2 Poly(octyl isocyanate) -- 3.2 Phase Separation in Polymer Solutions -- 3.3 Segmental Mobility and Conformation of Spin Labelled Macromolecules at the Solid/Liquid Interface -- 3.4 Associative Polymer Systems in Solutions -- 3.4.1 Complexes of Poly(ethylene) Oxide and Sodium Dodecyl Sulfate -- 3.4.2 Complexes of Sodium Poly(alkylacrylate)s and Alkyltrimethylammonium Bromides -- 3.4.3 Self-assembling Structure Polymers -- 3.4.4 Starburst Dendrimers -- 4 Swollen Polymers, Gels and Concentrated Solutions -- 5 Solid Polymers -- 5.1 Structural and Dynamic Microheterogeneity of Polymers near the Glass Transition Temperature -- 5.2 Influence of Hydrogen Bonding on the Spin Probe Rotational Mobility in Solid Polymers -- 5.2.1 Hydrogen Bonding and Probe Size Effects in Linear Epoxy Polymers -- 5.2.2 Hydrogen Bonding in Silica-filled Polyethylene -- 5.3 Features of the Spin Probe and Spin Label Dynamics in Polymer Blends and Polyblock Copolymers -- 5.3.1 Blends of the Miscible Pairs of Polymers -- 5.3.2 Blends of the Immiscible Pairs of Polymers -- 5.3.3 Polyblock Copolymers with Soft and Rigid Blocks -- 5.4 The Polymer Surface Characterization by Using Nitroxide Radicals -- 5.5 Influence of Chemical Transformations of Polymers on the Molecular Dynamics of Spin Labels and probes -- 6 Conclusion -- 7 References -- Chapter 5 Applications of EPR to Fullerene Research -- 1 Introduction -- 2 Radical Ions of C60 -- 2.1 The C60- Radical -- 2.2 The EPR Spectrum of C602- -- 2.3 The EPR Spectrum of C603- -- 3 Endohedral Fullerenes -- 4 Muonium-containing C60 and C70 Radicals -- 4.1 MuC60 and the Mu/H Hyperfine Anomaly -- 4.2 13C Hyperfine Interactions in MuC60 -- 4.3 Muon Addition to C70 -- 5 Free Radical Adducts of C60 and C70 -- 5.1 Addition of Alkyl Radicals to C60 -- 5.2 Addition of other Free Radicals to C60 -- 5.3 Free Radical Adducts of C70.
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6 The Excited Triplet State of C60 -- 7 Summary -- 8 Acknowledgements -- 9 References -- Chapter 6 EPR Imaging -- 1 Introduction -- 2 EPR Imaging Techniques -- 2.1 Gradients -- 2.2 Localized Detection -- 2.3 Pulsed Experiments -- 2.4 Double Resonance -- 2.5 Image Reconstruction -- 3 Instrumentation -- 3.1 Gradients -- 3.2 Frequencies Lower than X-band -- 4 Applications -- 4.1 Diffusion -- 4.2 Low Frequency and In Vivo -- 4.3 Geosciences and Material Science -- 5 Summary -- 6 Acknowledgment -- 7 References -- Chapter 7 Time Domain EPR -- 1 Introduction -- 2 ESEEM -- 2.1 S=1/2, I=1/2 -- 2.1.1 1H, 15N -- 2.1.2 31P, 117,119Sn, 29Si -- 2.2 S=1/2, I=1, 14N -- 2.2.1 Qualitative Analysis -- 2.2.2 Quantitative Analysis using Approximate Equations -- 2.2.3 Quantitative Analysis - Numerical Simulations -- 2.3 S=1/2, I=1, 2H -- 2.3.1 Frequence Domain Analysis without the Quadrupole Interaction -- 2.3.2 Quantitative analysis using Approximate Equations -- 2.3.3 Time Domain Analysis -- 2.4 S=1/2, I> -- 1, 17O, 27Al, 79,81Br, 35Cl, 7Li -- 2.5 S> -- 1/2, I> -- 1/2 -- 2.5.1 Qualitative Analysis -- 2.5.2 Quantitative Analysis -- 2.6 Coherent Raman Beats -- 2.7 Electron-Electron Interactions -- 2.8 Theory -- 3 2D ESEEM -- 3.1 S=1/2, I=1/2 -- 3.2 S=1/2, I=1 -- 4 Pulsed ENDOR -- 4.1 1H, 2H -- 4.2 17O, 55Mn, 57Fe -- 4.3 19F -- 4.4 High Field -- 5 Echo Detected EPR, Relaxation and Nutation Measurement -- 5.1 ED-EPR -- 5.2 Relaxation Measurements -- 5.3 Nutation Experiments -- 6 FT-EPR -- 6.1 1D FT-EPR -- 6.2 2D FT-EPR -- 6.3 Nutation Experiments -- 7 New Methods -- 7.1 Measuring Nuclear Frequencies Without RF Pulses -- 7.2 Pulsed ENDOR -- 7.3 FT-EPR and Others -- 7.4 Instrumentation-High Field -- 8 Concluding Remarks -- 9 References -- Chapter 8 Recent Computer Applications in EPR Spectroscopy -- 1 Introduction -- 2 Computers in Data Acquisition and Data Analysis.
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2.1 Data Acquisition -- 2.1.1 CW EPR -- 2.1.1.1 Varian Systems -- 2.1.1.2 Bruker Systems -- 2.1.1.3 JEOL Systems -- 2.1.1.4 Other Systems -- 2.1.2 EPR Imaging -- 2.1.3 ENDOR, ELDOR and Pulsed Systems -- 2.1.4 High-field EPR -- 2.2 Processing EPR Data -- 2.2.1 Correcting for Field Inhomogeneity -- 2.2.2 Base-line correction -- 2.2.3 Imaging -- 2.2.4 Stochastic ENDOR -- 3 Spectral Simulation -- 3.1 Least-squares Simulations of Inhomogeneously Broadened EPR Spectra -- 3.2 Examples -- 3.2.1 Measurement of Oxygen Concentration by EPR -- 3.2.2 Measurement of Nitroxide Metabolism and Oxygen Consumption in Baby Hamster Kidney Cells and Transformed Hamster Cells by EPR -- 4 Computers in Communication and Information Exchange -- 4.1 Anonymous FTP Sites Associated with EPR -- 4.2 The Worldwide Web -- 4.2.1 EPR Centers -- 4.2.1.1 http://ierc.scs.uiuc.edu/epr.html -- 4.2.1.2 http://www.biophysics.mcw.edu//BRI-EPR/ -- 4.2.1.3 http://spin.aecom.yu.edu/ -- 4.2.2 Database Sites -- 4.2.2.1 http://www.rad.nd.edu -- 4.2.2.2 http://alfred.niehs.nih.gov:80/LMB/stdb/ -- 4.2.2.3 http://emrs.chm.bris.ac.uk/emr/EMR.html -- 4.2.3 Conference Sites -- 4.2.3.1 http://www.du.edu/~seaton/eprsym.html -- 4.2.4 Commercial Sites -- 4.2.4.1 http://www.bruker.com/ and http://www.bruker.de/ -- 4.2.4.2 http://www.jeol.com/ -- 4.2.4.3 http://www.wwnet.com/~sss/ -- 4.2.4.4 http://www.wilmad.com -- 4.2.5 Educational Sites -- 4.2.5.1 http://www.chem.vt.edu/chem-ed/spec/spin/epr.htm -- 4.2.6 Other Related Sites -- 4.2.6.1 http://endorl.chem.nwu.edu/endor/html -- 4.2.6.2 http://biosci.cbs.umn.edu/biophys/biophys.html -- 4.3 Future Prospects -- 4.3.1 Running EPR Spectrometers through the Worldwide Web -- 4.4 Electronic Mail Addresses -- 4.4.1 Manufacturers of EPR Equipment -- 4.4.2 EPR-related Supplies -- 4.4.3 EPR-related Repair and Design Services, and Software -- 4.5 List and News Servers.
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4.6 Data Bases on the Internet -- 4.6.1 Data Bases Maintained by Individuals -- 4.6.2 Spin Trap and Magnetic Resonance Data Base at the Laboratory of Molecular Biophysics at the National Institute of Enviornmental Health Science -- 4.6.3 Notre Dame Radiation Chemistry Data Center -- 4.6.4 Richard Cammack's Data Base on EPR Software -- 4.7 Examples -- 4.7.1 An Anonymous FTP Session with xenon.ch.ilstu.edu -- 4.7.2 Joining the EPR-list and Sending a Message to the list -- 4.7.3 Searching the Notre Dame Radiation Chemistry Data Center -- 5 Acknowledgments -- 6 References -- Author Index.
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