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  • Center for Marine Environmental Sciences; CTD/Rosette; CTD-RO; Date/Time of event; Density, mass density; Density, sigma-theta (0); DEPTH, water; Difference; EISPAC/WESTWIND; Elevation of event; Event label; GeoB17401-1; GeoB17403-1; GeoB17404-1; GeoB17407-1; GeoB17412-1; GeoB17413-2; GeoB17417-1; GeoB17420-1; GeoB17424-1; GeoB17426-1; GeoB17428-2; GeoB17432-1; GeoB17433-1; GeoB17434-1; GeoB17436-2; Latitude of event; Longitude of event; MARUM; Nitrate; Oxygen; Oxygen saturation; Phosphate; Pressure, water; Salinity; Silicate; SO228; Sonne; Temperature, water; δ13C, dissolved inorganic carbon; δ13C, dissolved inorganic carbon, standard deviation; δ15N, nitrate; δ15N, nitrate, standard deviation; δ18O, nitrate; δ18O, standard deviation  (1)
  • ddc:551  (1)
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  • 1
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    PANGAEA
    In:  Supplement to: Lehmann, Nadine; Granger, Julie; Kienast, Markus; Brown, Kevin S; Rafter, Patrick A; Martínez Méndez, Gema; Mohtadi, Mahyar (2018): Isotopic evidence for the evolution of subsurface nitrate in the Western Equatorial Pacific. Journal of Geophysical Research: Oceans, 123(3), 1684-1707, https://doi.org/10.1002/2017JC013527
    Publication Date: 2024-07-22
    Description: Subsurface waters from both hemispheres converge in the Western Equatorial Pacific (WEP), some of which form the Equatorial Undercurrent (EUC) that influences equatorial Pacific productivity across the basin. Measurements of nitrogen (N) and oxygen (O) isotope ratios in nitrate (d15N-NO3 and d18O-NO3), the isotope ratios of dissolved inorganic carbon (d13C-DIC), and complementary biogeochemical tracers reveal that northern and southern WEP waters have distinct biogeochemical histories. Organic matter remineralization plays an important role in setting the nutrient characteristics on both sides of the WEP. However, remineralization in the northern WEP contributes a larger concentration of the nutrients, consistent with the older "age" of northern thermocline- and intermediate-depth waters. Remineralization introduces a relatively low d15N-NO3 to northern waters, suggesting the production of sinking organic matter by N2 fixation at the surface - consistent with the notion that N2 fixation is quantitatively important in the North Pacific. In contrast, remineralization contributes elevated d15N-NO3 to the southern WEP thermocline, which we hypothesize to derive from the vertical flux of high-d15N material at the southern edge of the equatorial upwelling. This signal potentially masks any imprint of N2 fixation from South Pacific waters. The observations further suggest that the intrusion of high d15N-NO3 and d18O-NO3 waters from the eastern margins is more prominent in the northern than southern WEP. Together, these north-south differences enable the examination of the hemispheric inputs to the EUC, which appear to derive predominantly from southern hemisphere waters.
    Keywords: Center for Marine Environmental Sciences; CTD/Rosette; CTD-RO; Date/Time of event; Density, mass density; Density, sigma-theta (0); DEPTH, water; Difference; EISPAC/WESTWIND; Elevation of event; Event label; GeoB17401-1; GeoB17403-1; GeoB17404-1; GeoB17407-1; GeoB17412-1; GeoB17413-2; GeoB17417-1; GeoB17420-1; GeoB17424-1; GeoB17426-1; GeoB17428-2; GeoB17432-1; GeoB17433-1; GeoB17434-1; GeoB17436-2; Latitude of event; Longitude of event; MARUM; Nitrate; Oxygen; Oxygen saturation; Phosphate; Pressure, water; Salinity; Silicate; SO228; Sonne; Temperature, water; δ13C, dissolved inorganic carbon; δ13C, dissolved inorganic carbon, standard deviation; δ15N, nitrate; δ15N, nitrate, standard deviation; δ18O, nitrate; δ18O, standard deviation
    Type: dataset
    Format: text/tab-separated-values, 88998 data points
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  • 2
    Publication Date: 2023-03-21
    Description: Gas exchange between the atmosphere and ocean interior profoundly impacts global climate and biogeochemistry. However, our understanding of the relevant physical processes remains limited by a scarcity of direct observations. Dissolved noble gases in the deep ocean are powerful tracers of physical air-sea interaction due to their chemical and biological inertness, yet their isotope ratios have remained underexplored. Here, we present high-precision noble gas isotope and elemental ratios from the deep North Atlantic (~32°N, 64°W) to evaluate gas exchange parameterizations using an ocean circulation model. The unprecedented precision of these data reveal deep-ocean undersaturation of heavy noble gases and isotopes resulting from cooling-driven air-to-sea gas transport associated with deep convection in the northern high lati-tudes. Our data also imply an underappreciated and large role for bubble-mediated gas exchange in the global air-sea transfer of sparingly soluble gases, including O2, N2, and SF6. Using noble gases to validate the physical representation of air-sea gas exchange in a model also provides a unique opportunity to distinguish physical from biogeochemical signals. As a case study, we compare dissolved N2/Ar measurements in the deep North Atlantic to physics-only model predictions, revealing excess N2 from benthic denitrification in older deep waters (below 2.9 km). These data indicate that the rate of fixed N removal in the deep Northeastern Atlantic is at least three times higher than the global deep-ocean mean, suggesting tight coupling with organic carbon export and raising potential future implications for the marine N cycle.
    Description: NSF, UK NERC, University of Oxford Advanced Research Computing facility
    Description: https://www.bco-dmo.org/project/887496
    Description: research
    Keywords: ddc:551 ; gas exchange ; nitrogen cycle ; overturning circulation ; air-sea interaction ; noble gases
    Language: English
    Type: doc-type:article , publishedVersion
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