ISSN:
1572-879X
Keywords:
Oxidative propene dimerisation
;
1,5-hexadiene
;
Bi-Zn-O
;
Bi48ZnO73
;
kinetic behaviour
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The oxidative dimerisation of propene to 1,5-hexadiene has been investigated on Bi-Zn-O catalysts. The Bi48ZnO73 phase, observed in the catalysts calcined at 700 ° C is an active and selective catalyst for the formation of 1,5-hexadiene. The best catalytic performance (1,5-hexadiene selectivity ≈ 64%) has been obtained at 525 ° C, with a propene to oxygen ratio of 26, on a catalyst formed by Bi48ZnO73 with a small excess of ZnO.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00769163
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