ISSN:
0009-2940
Keywords:
Cyclopentadienyl complexes
;
Cyclooctatetraenyl complexes
;
Yttrium compounds
;
Terbium compounds
;
Lutetium compounds
;
Lanthanoides, organo-, alkoxides
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Organometallic Compounds of the Lanthanoids, 73[1]. - Synthesis and Structure of New Monocyclooctatetraenyl Complexes of Yttrium, Terbium, and Lutetium[(C8H8)Ln(μ1-Cl)(THF)]2 (Ln=Y, Lu) react with NaOR (R=Ph, C6H3Me2-2,6) to give the dinuclear cyclooctatetraenyl rare earth alkoxides [(C8H8)Ln(μ1-OR)(THF)]2 [R=Ph, Ln=Y (1a), Lu (1b); R=C6H3Me2-2,6, Ln=Y (2a), Lu (2b)]. The reactions of [(C8H8)Ln(μ1-Cl)(THF)]2 with LiOC(tBu)3, NaOSiPh3, and NaC5H3tBu2 result in the formation of (C8H8)LnOC(tBu)3(THF) [Ln=Y (3a), Lu (3b)], (C8H8)LnOSiPh3(THF) [Ln=Y (4a), Lu (4b)], and (C8H8)Tb(C5H3tBu2) (5), respectively. Treatment of (C8H8)Y(C5Me5) with acetylacetone yields (C5Me5)Y(acac)2 (6). The 1H-and 13C-NMR and mass spectra of the new compounds as well as the X-ray crystal structures of 1a and 5 are discussed.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19931260409
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