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  • Rare earth  (2)
  • Arctic Ocean  (1)
  • 1
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 39 (2012): L07606, doi:10.1029/2012GL051574.
    Description: The carbon system of the western Arctic Ocean is undergoing a rapid transition as sea ice extent and thickness decline. These processes are dynamically forcing the region, with unknown consequences for CO2 fluxes and carbonate mineral saturation states, particularly in the coastal regions where sensitive ecosystems are already under threat from multiple stressors. In October 2011, persistent wind-driven upwelling occurred in open water along the continental shelf of the Beaufort Sea in the western Arctic Ocean. During this time, cold (〈−1.2°C), salty (〉32.4) halocline water—supersaturated with respect to atmospheric CO2 (pCO2 〉 550 μatm) and undersaturated in aragonite (Ωaragonite 〈 1.0) was transported onto the Beaufort shelf. A single 10-day event led to the outgassing of 0.18–0.54 Tg-C and caused aragonite undersaturations throughout the water column over the shelf. If we assume a conservative estimate of four such upwelling events each year, then the annual flux to the atmosphere would be 0.72–2.16 Tg-C, which is approximately the total annual sink of CO2 in the Beaufort Sea from primary production. Although a natural process, these upwelling events have likely been exacerbated in recent years by declining sea ice cover and changing atmospheric conditions in the region, and could have significant impacts on regional carbon budgets. As sea ice retreat continues and storms increase in frequency and intensity, further outgassing events and the expansion of waters that are undersaturated in carbonate minerals over the shelf are probable.
    Description: Funding for this work was provided by the National Science Foundation (ARC1041102 – JTM, OPP0856244-RSP, and ARC1040694- LWJ), the National Oceanic and Atmospheric Administration (CIFAR11021- RHB) and the West Coast & Polar Regions Undersea Research Center (POFP00983 – CLM and JM).
    Description: 2012-10-11
    Keywords: Arctic Ocean ; CO2 fluxes ; Ocean acidification ; Upwelling
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: text/plain
    Format: image/tiff
    Format: application/msword
    Format: application/pdf
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 27 (1998), S. 803-815 
    ISSN: 1572-8927
    Keywords: Rare earth ; complexation ; carbonate ; ICP–MS
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Carbonate stability constants for yttrium and all rare earth elements have been determined at 25°C and 0.70 molal ionic strength by solvent exchange and inductively coupled plasma–mass spectrometry (ICP–MS). Measured stability constants for the formation of $${\text{MCO}}_3^ +$$ and $${\text{M}}\left( {{\text{CO}}_{\text{3}} } \right)_2^--$$ from M3+ are in good agreement with previous direct measurements, which involved the use of radio-chemical techniques and trivalent ions of Y, Ce, Eu, Gd, Tb, and Yb. Direct ICP–MS measurements of $${\text{MCO}}_3^ +$$ and $${\text{M}}\left( {{\text{CO}}_{\text{3}} } \right)_2^--$$ formation constants are also in general agreement with modeled stability constants for the metals La, Pr, Nd, Sm, Dy, Ho, Er, Tm, and Lu, based on linear-free energy relationship (LFER). The experimental procedures developed in this work can be used for assessing the complexation behavior of other geochemically important ligands such as phosphate, sulfate, and fluoride.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Aquatic geochemistry 4 (1998), S. 103-121 
    ISSN: 1573-1421
    Keywords: Rare earth ; Rare earth ; fractionation ; model ; riverine ; oceanic ; estuarine
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Fractionation of yttrium (Y) and the rare earth elements (REEs) begins in riverine systems and continues in estuaries and the ocean. Models of yttrium and rare earth (YREE) distributions in seawater must therefore consider the fractionation of these elements in both marine and riverine systems. In this work we develop a coupled riverine/marine fractionation model for dissolved rare earths and yttrium, and apply this model to calculations of marine YREE fractionation for a simple two-box (riverine/marine) geochemical system. Shale-normalized YREE concentrations in seawater can be expressed in terms of fractionation factors (λ ij ) appropriate to riverine environments ( $$\lambda _{ij}^{river}$$ ) and seawater ( $$\lambda _{ij}^{ocean}$$ ): $$\log \frac{{\left( {M_i } \right)_T^{ocean} }}{{\left( Y \right)_T^{ocean} }} = log\;\lambda _{ij}^{ocean} + ((\lambda _{ij}^{river} )^{ - 1} - 1)\;log\frac{{[Y]_T^{river} }}{{[Y^0 ]_T^{river} }}$$ where $$\left( {M_i } \right)_T^{ocean}$$ and $$\left( Y \right)_T^{ocean}$$ are input-normalized total metal concentrations in seawater and $$[Y]_T^{river} /[Y^0 ]_T^{river}$$ is the ratio of total dissolved Y in riverwater before $$([Y^0 ]_T^{river} )$$ and after $$([Y]_T^{river} )$$ commencement of riverine metal scavenging processes. The fractionation factors (λ ij ) are calculated relative to the reference element, yttrium, and reflect a balance between solution and surface complexation of the rare earths and yttrium.
    Type of Medium: Electronic Resource
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