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  • Chemistry  (4)
  • Arctic Amplification  (1)
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  • 1
    Publication Date: 2023-12-05
    Description: The Arctic is warming much faster than the global average. This is known as Arctic Amplification and is caused by feedbacks in the local climate system. In this study, we explore a previously proposed hypothesis that an associated wind feedback in the Barents Sea could play an important role by increasing the warm water inflow into the Barents Sea. We find that the strong recent decrease in Barents Sea winter sea ice cover causes enhanced ocean‐atmosphere heat flux and a local air temperature increase, thus a reduction in sea level pressure and a local cyclonic wind anomaly with eastward winds in the Barents Sea Opening. By investigating various reanalysis products and performing high‐resolution perturbation experiments with the ocean and sea ice model FESOM2.1, we studied the impact of cyclonic atmospheric circulation changes on the warm Atlantic Water import into the Arctic via the Barents Sea and Fram Strait. We found that the observed wind changes do not significantly affect the warm water transport into the Barents Sea, which rejects the wind‐feedback hypothesis. At the same time, the cyclonic wind anomalies in the Barents Sea increase the amount of Atlantic Water recirculating westwards in Fram Strait by a downslope shift of the West Spitsbergen Current, and thus reduce Atlantic Water reaching the Arctic basin via Fram Strait. The resulting warm‐water anomaly in the Greenland Sea Gyre drives a local anticyclonic circulation anomaly.
    Description: Plain Language Summary: The Barents Sea has been experiencing a rapid decrease in its winter sea ice extent during the last 30 years. The loss of sea ice creates new areas where, in winter, the relatively warm ocean loses heat to the cold atmosphere. As warm air rises, the warming reduces the sea level air pressure, changing the atmospheric circulation to develop a local anticlockwise wind system centered over the northern Barents Sea. The associated eastward winds in the Barents Sea Opening and southeastward winds in Fram Strait affect how warm water from the North Atlantic moves toward the Arctic. There has been a long debate on whether this wind anomaly can increase the warm Atlantic Water transport into the Barents Sea and thus cause a positive feedback mechanism for further reducing the sea ice through melting. We find that the observed atmospheric circulation changes have no significant impact on the Barents Sea warm water inflow and thus reject the wind feedback as a strong player in contributing to Arctic Amplification. However, strong anomalous southeastward winds in Fram Strait and the northern Nordic Seas cause a southward shift of the warm Atlantic Water recirculation and reduce its flow toward the Arctic.
    Description: Key Points: A hypothesis that a wind feedback contributes to Arctic Amplification is rejected by performing dedicated wind perturbation simulations. Winter sea ice retreat in the northern Barents Sea causes anomalous cyclonic winds by locally enhancing ocean heat loss. Anomalous cyclonic winds result in less Atlantic Water transport through Fram Strait.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: North‐German Supercomputing Alliance
    Description: https://github.com/FESOM/fesom2
    Description: https://doi.org/10.7265/N5K072F8
    Description: https://doi.org/10.5065/D6HH6H41
    Description: https://doi.org/10.5065/D6WH2N0S
    Description: https://github.com/FESOM/pyfesom2
    Description: https://doi.org/10.5281/zenodo.7458143
    Keywords: ddc:551 ; Barents Sea ; Arctic Amplification ; feedback ; Atlantic water ; modeling ; Fram Strait
    Language: English
    Type: doc-type:article
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  • 2
    ISSN: 0269-3879
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
    Notes: A procedure for the extraction and high performance liquid chromatographic (HPLC) determination of the photodynamic therapeutic agent 5,10,15,20-tetra(m-hydroxyphenyl)chlorin in human, rat and mouse tissues following intravenous administration of the drug is described. The tissue (tumour, skin, muscle and liver) was homogenized and extracted into a mixture of methanol:dimethyl sulphoxide:water (32:8:1 by vol.) containing, 5,10,15,20-tetra(p-hydroxyphenyl)chlorin as the internal standard. The precipitated proteins were removed by centrifugation and the supernatant was separated by reversed phase HPLC on a Hypersil-ODS column with 77% (v/v) acetonitrile in 0.1% trifluoroacetic acid as the mobile phase. The solute was detected with high sensitivity and specificity by a UV-VIS detector set at 423 nm.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 53 (1994), S. 1391-1392 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0269-3879
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
    Notes: A high performance liquid chromatographic method for the determination of the photodynamic chemotherapeutic agent 5,10,15,20-tetra(m-hydroxyphenyl)chlorin (m-THPC) in human plasma following intravenous infusion is described. The procedure involves extraction of the drug in plasma with methanol/dimethyl sulphoxide (4:1 v/v) containing 5,10,15,20-tetra(p-hydroxyphenyl)clorin as the internal standard and separation on a C18 reversed phase column with acetonitrile:0.1% trifluoroacetic acid (77:23 v/v) as the mobile phase. The drug was detected specifically and sensitively at its absorption maximum of 423 nm with a detection limit of 15 ng/mL (signal-to-noise ratio of 5). The intra- and inter-assay coefficients of variation (CV) on analysis of a plasma spiked with m-THPC (1 μg/mL) were 2.3 and 3.4% (n=6), respectively.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 55 (1995), S. 1111-1116 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A photosensitive polysiloxaneimide precursor was synthesized from oxydianiline, bis(p-aminophenoxy)dimethylsilane, and a diacid chloride. This diacid chloride was prepared by the reaction of thionyl chloride with a diacid, which resulted from the reaction of pyromellitic dianhydride with hydroxyethylacrylate in N-methylpyrrolidone (NMP). The adhesion properties between polyimide and substrates such as SiO2 wafer were improved with introduction of siloxane moiety into the polyimide chain. The dielectric constant decreased with increasing siloxane moiety content. The photocrosslinking reaction results show that an 88-90% gel fraction was reached under the irradiation of a high-pressure mercury lamp. © 1995 John Wiley & Sons, Inc.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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