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  • Analytical Chemistry and Spectroscopy  (1)
  • Surface physics, nanoscale physics, low-dimensional systems  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 19 (1990), S. 13-26 
    ISSN: 1052-9306
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The determination of the amino acid composition and sequence of a peptide, using both conventional and tandem fast atom bombardment mass spectrometry, is presented. First a list of potential empirical formulae is generated using the accurate mass and isotopic peak intensity ratios from the molecular ion cluster. The formulae are mathematically analyzed to ensure that they correspond to linear peptides composed of 19 common amino acids. Then using the ions below m/z 160 Da, which are characteristic of the amino acid content of the peptide, the formulae are decomposed into possible amino acid compositions. From each composition sequences are generated and their predicted fragment ions are compared to ions present in the mass spectrum. A score based on the intensities and the occurrence of consecutive sequence fragments is calculated. Finally sequences with the ten highest scores are retained. Analyses performed on typical peptides with molecular weights below 1500 Da indicate that identification can generally be achieved using this approach.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2018-05-30
    Description: Author(s): Srujan Meesala, Young-Ik Sohn, Benjamin Pingault, Linbo Shao, Haig A. Atikian, Jeffrey Holzgrafe, Mustafa Gündoğan, Camille Stavrakas, Alp Sipahigil, Cleaven Chia, Ruffin Evans, Michael J. Burek, Mian Zhang, Lue Wu, Jose L. Pacheco, John Abraham, Edward Bielejec, Mikhail D. Lukin, Mete Atatüre, and Marko Lončar Here, the authors tune the color of light emitted by single-atom imperfections (silicon vacancy color centers) inside a diamond. Such tunable imperfections can be networked together to build a quantum internet, where information can be securely exchanged using the laws of quantum physics. One problem is that all the centers need to emit at precisely the same color or wavelength. The authors overcome this challenge by placing color centers inside a diamond nanostring. By adjusting the tension in the string, atoms are stretched inside the crystal and tune the center to emit photons of a desired wavelength. The tuning method involves bending the string with a force controlled handily with an electrical voltage. A symphony of such tunable diamond strings could serve as the backbone of a future quantum internet. [Phys. Rev. B 97, 205444] Published Tue May 29, 2018
    Keywords: Surface physics, nanoscale physics, low-dimensional systems
    Print ISSN: 1098-0121
    Electronic ISSN: 1095-3795
    Topics: Physics
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