Keywords:
Nuclear magnetic resonance - Collected works.
;
Electronic books.
Description / Table of Contents:
For those wanting to become rapidly acquainted with specific areas of NMR, this title provides unrivalled scope of coverage.
Type of Medium:
Online Resource
Pages:
1 online resource (440 pages)
Edition:
1st ed.
ISBN:
9781847553584
Series Statement:
Issn Series
URL:
https://ebookcentral.proquest.com/lib/geomar/detail.action?docID=1185825
DDC:
016.538362
Language:
English
Note:
Nuclear Magnetic Resonance -- Contents -- Chapter 1 Nuclear Shielding -- 1 Introduction -- 2 Basic Aspects of Nuclear Shielding -- A General Theory -- B Basic Physical Aspects -- 3 Calculations of Nuclear Shielding -- 4 Transmission of Shielding Effects within Molecules -- A Introduction -- B Inductive Effects -- C Resonance Effects -- D Magnetic Anisotropy Effects -- E Electric Field Effects -- F The Ring-current Effect -- G Van der Waals and Steric Effects -- H Intramolecular Hydrogen Bonding -- I Isotope Shifts -- 5 Shieldings of Particular Nuclear Species -- A Introduction -- B Carbon Chemical Shifts -- C Fluorine Chemical Shifts -- D Phosphorus Chemical Shifts -- E Nitrogen Chemical Shifts -- F Chemical Shifts of Nuclei Other than H,C,F,P, and N -- 6 Chemical Shift Anisotropy -- Chapter 2 Nuclear Spin-Spin Coupling -- 1 Introduction -- 2 Basic Theory: Notation and Abbreviations -- A Sum-Over-States Perturbation Theory (SOS) -- B Finite Perturbation Theory (FPT) -- C Semi-empirical Molecular Orbital Methods -- D Units -- 3 Theoretical Work -- A Calculations on H2 or HD -- B Ab Initio Calculations of Coupling in Small Molecules -- C Semi-empirical Calculations -- D π-Electron Coupling -- E Nuclear-spin and Electron-spin Coupling -- F Solvent Effects -- 4 Coupling of Directly Bonded Nuclei -- A Coupling in HD -- B Coupling between 13C and 1H -- C Coupling between 15N and 1H -- D Coupling between 31P and 1H -- E Coupling between 1H and Other Nuclei -- F 1J(13C,13C), 1J(l3C,15N), 1(11B,13C), and 1J(11B,11B) -- G Coupling between 13C and 31P -- H Coupling between 13C and 19F -- I Coupling between 13C and Metals -- J Coupling to 19F, except 1J(19F,31P) and 1J(19F,13C) -- K Coupling between 31P and 19F -- L Other One-Bond Couplings involving 31P -- 5 Coupling between Nuclei Separated by Two Chemical Bonds, 2J.
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A Geminal Proton-Proton Coupling across Carbon -- B Geminal Proton-Proton Coupling across Other Elements -- C 2J(13CC1H) -- D Coupling of Other Nuclei to Protons via Carbon, 2J(XC1H) -- (i) X = 199Hg -- (ii) X = 11B and 27A1 -- (iii) X = 73Ge, 119,117Sn, and 207Pb -- (iv) X = 15,14N and 31P -- (v) X = 77Se -- (vi) X = 19F -- (vii)X = 183W and 19SPt -- E 2J(19FC19F) -- F 2J(13CC13C), 2J(31PC13C), and 2J(15NC13C) -- G 2J(31PN13C) and 2/(31PN31P) -- H 2J(31PM13C), where M is a metal -- I 2J(31PM31P), where M is a Metal -- J 2J(13CO13C) and 2J(31PO13C) -- K Other Two-bond Coupling Constants -- 6 Coupling between Nuclei Separated by Three Chemical Bonds, 3J -- A Coupling of Protons via Two Carbon Atoms -- B Three-bond Coupling of Protons via Other Atoms -- C Three-bond Coupling of Carbon to Protons -- D Three-bond Coupling of Other Nuclei to Protons via Two Carbon Atoms, 3J(XCC1H) -- (i) X = 15,14N -- (ii) X = 11B and 27A1 -- E Three-bond Coupling to Fluorine via Two Carbon Atoms, 3J(XCC19F) -- (i) X = 1H -- (ii) X = 19F -- (iii) X = 15N and 199Hg -- F Three-bond Couplings between Phosphorus and Hydrogen, 3J(31PXC1H) -- (i) X = O -- (ii) X = N -- (iii) X = S -- (iv) X = a Group IVB Element -- (v) X = Au and Pt -- G 3J(13CCC31P) and 3/(13CC031P) -- H 3J(13CCC13C) -- I 3J(199HgXC1H) -- J 3J(195PtXC1H), X = N, P, and As -- K Other Three-bond Coupling Constants -- 7 Coupling between Nuclei Separated by Four Chemical Bonds, 4J -- A 4J(1HCCC1H) -- B Other Four-bond (H,H) Couplings -- C Four-bond Coupling of 13C, 14N, and 31P to 1H via Carbon Atoms -- D Four-bond Coupling of Metals to Protons -- E 4J(1HCCC19F) and 4J(19FCCC19F) -- F Other Four-bond Couplings -- 8 Coupling between Nuclei Separated by Five Chemical Bonds, 5J -- A 5J(1HCCCC1H) -- B 5J(1HCCXC1H), X = N, O, and S -- C Five-bond Coupling of 1H to 19F -- D Other Five-bond Couplings.
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9 Coupling between Nuclei Separated by Six or More Chemical Bonds -- A 6J -- B 7J and 8J -- 10 Coupling in Aromatic Systems -- A (1H,1H) Coupling in Benzenoid Aromatic Systems -- B (1H,1H) Coupling in Heteroaromatic Systems -- C Coupling in Metal-Cyclopentadienyl Compounds -- D (1H,19F) Coupling in Aromatic Systems -- E (1H,13C) Coupling in Aromatic Systems -- F (1H,31P) Coupling in Aromatic Systems -- G Coupling of Protons to Other Nuclei in Aromatic Systems -- H (13C,15N) Coupling in Aromatic Systems -- I Other Couplings in Aromatic Systems -- 11 'Through-space' Coupling -- 12 Isotope Effects -- 13 Experimental Work of Significance for the Measurement or Interpretation of Spin-Spin Coupling Constants -- A Multiple-resonance Experiments -- B Bandshape Analyses -- C Effects of Paramagnetic Materials -- D Fourier-transform Experiments -- E Other Experimental Techniques -- Chapter 3 Nuclear Spin Relaxation -- 1 Introduction -- 2 Spin Relaxation in Gases -- A Introduction -- B Theoretical Developments -- C Diatomic Molecules -- D Polyatomic Molecules -- E Spin Diffusion Measurements -- 3 Spin Relaxation in Liquids -- A Introduction -- B Pure Liquids -- Linear Molecules -- Spherically Symmetric Molecules -- Axially Symmetric Molecules -- Asymmetric Molecules -- C Internal Rotation of Methyl Groups -- D Molecular Motion and Association in Mixtures of Liquids -- Molecular Rotation Studies -- Molecular Association Studies -- Aqueous Solutions of Non-electrolytes -- Hydrogen-bonded Systems -- E Ionic Solutions -- Diamagnetic Solutions -- Paramagnetic Solutions -- F Relaxation by Translational Diffusion -- G Spin-diffusion Measurements in Liquids -- H Transverse Relaxation and Spin-echo Studies -- Spin-echo Spectroscopy -- Selective Measurement of Transverse Relaxation Rates -- Chemical Exchange Studies -- I Models for Molecular Rotation.
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J Studies of Critical Phenomena in Fluids -- K 13C Relaxation Studies -- Small Molecules -- Complex Molecules -- L 15N Relaxation Studies -- M 31P Relaxation Studies -- N Determination of Spin Interaction Constants from Spin-Relaxation Measurements -- Scalar Spin-Spin Coupling Constants -- Nuclear Quadrupole Coupling Constants -- Spin-Rotation Interaction Constants and Chemical Shielding Anisotropics -- O Miscellaneous Papers -- 4 Spin Relaxation in Liquid Crystals -- A Nematic Phases -- B Cholesteric Phases -- C Isotropic Phases -- D Spin-diffusion Studies -- 5 Spin Relaxation in Solids -- A Spin-Lattice Relaxation in the Rotating Frame and Dipolar Relaxation -- B Spin-Lattice Relaxation by Anisotropic Chemical Shielding Interaction -- C Spin-Lattice Relaxation by Spin-Rotation Interaction -- D Spin-Lattice Relaxation by Nuclear Quadrupole Interaction -- E Spin-Lattice Relaxation due to Paramagnetic Impurities -- F Investigations of Molecular Reorientation -- Molecular Solids -- Internal Rotation in Molecular Solids -- Internal Rotation in Ionic Solids -- Spin-Lattice Relaxation by Quantum Mechanical Rotation at Low Temperatures -- G Investigations of Self-diffusion -- General Developments -- Metals -- Metal Hydrides -- Ionic Crystals -- Molecular Crystals -- H Studies of Molecules Bound to Solid Surfaces -- I Ferroelectric Materials -- Chapter 4 Experimental Techniques -- 1 Introduction -- 2 Probes -- A Variable Temperature -- B High Pressure -- C High Field -- 3 Frequency Generation -- 4 Pulse-sequence Generation -- 5 Continuous-wave Spectroscopy -- A Double-resonance Techniques -- B 'Other' Nuclei -- C Use of Computers -- D Relaxation Measurements -- 6 High-resolution Fourier-transform Spectroscopy -- A Introduction -- B Fourier Spectrometers -- C Relaxation Measurements -- T1 -- Spin Echoes -- D Gated Double Resonance.
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E Difference Spectroscopy -- 7 General Pulsed Spectroscopy -- A Introduction -- B Spectrometers -- C Relaxation Measurements in Liquids -- T1ρ -- Spin Echoes -- T1 -- D High-resolution Studies in Solids -- Chapter 5 Spectral Analysis -- 1 Introduction -- 2 New Methods of Studying Known Spin Systems -- A Proton Spin-echo N.M.R. Spectra of 2,2-Dichloro-1,1-difluoroethane: Sub-spectral Analysis -- B Spin Hamiltonian for Twofold Symmetry -- Matrix Elements of the Hamiltonian with Symmetrized Spin Operators -- Symmetry Properties of the | A,M > -- Basis Functions -- C Double-quantum Effects in the Spectrum of 2-Bromothiazole -- D The Direct Method Applied to Nuclear Magnetic Double Resonance -- 3 Known Spin Systems -- A AB-Based N.M.R. Systems: Choice of Bounds for θ in Trigonometric Forms of Co-factors in Mixed Wave-functions -- B Systems involving Protons Only -- Saturated Acyclic Systems -- (i) n-Propyl derivatives -- [AB]2C3 -- (ii) 2,2'-Dihalogenodiethyl ethers -- [AB]2 -- Saturated Cyclic Systems -- (i) 1,3-Dioxans -- AB, AMX, ABX, [AX]2 -- (ii) D-Aldopentapyranosyl derivatives -- ABX -- (iii) N-Substituted styreneimines -- ABX -- (iv) L-Azetidine-2-carboxylic acid (L-ACA) and N-acetyl-L-azetidine-2-carboxylic acid (N-A-L-ACA) -- ABCDE -- (v) 1,2,3-Substituted prolines -- ABCDEF -- Olefinic Compounds: Dichloropentenes -- ABCDE -- Unsaturated Five-membered Ring Compounds -- (i) 3,5-Disubstituted 1,2-dihydro-furans and -thiophens -- ABX, ABXY3, ABXY2, ABC -- (ii) Dimers of cyclopentadienyl compounds -- Sesquiterpenoids -- ABX{H} -- Aromatic Systems -- Aromatic substitution patterns -- Biologically important aromatic acids -- Benzocycloheptenes -- Carbanions and Ion Pairing -- [AM]2X, AMRX, [AX]2, AA'X -- Aryldi-t-butylmethanol -- Acridine and Five Monomethyl Derivatives -- 'ABCDX' -- Sulphur Heterocycles -- syn- and anti-2-Furanaldoximes.
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C Compounds containing Fluorine.
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