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  • 1
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 125(5), (2020): e2020JC016123, doi:10.1029/2020JC016123.
    Description: The processes underlying the strong Kuroshio encountering a cape at the southernmost tip of Taiwan are examined with satellite‐derived chlorophyll and temperature maps, a drifter trajectory, and realistic model simulations. The interaction spurs the formation of submesoscale cyclonic eddies that trap cold and high‐chlorophyll water and the formation of frontal waves between the free stream and the wake flow. An observed train of eddies, which have relative vorticity about one to four times the planetary vorticity (f), is shed from the recirculation that occurs in the immediate lee of the cape as a result of flow separation. These propagate downstream at a speed of 0.5–0.6 m s−1. Farther downstream, the corotation and merging of two or three adjacent eddies are common owing to the topography‐induced slowdown of eddy propagation farther downstream. It is found that the relative vorticity of a corotating system (1.2f) is 70% weaker than that of a single eddy due to the increase of eddy diameter from ~16 to ~33 km, in agreement with Kelvin's circulation theorem. The shedding period of the submesoscale eddies is strongly modulated by either diurnal or semidiurnal tidal flows, which typically reach 0.2–0.5 m s−1, whereas its intrinsic shedding period is insignificant. The frontal waves predominate in the horizontal free shear layer emitted from the cape, as well as a density front. Energetics analysis suggests that the wavy features result primarily from the growth of barotropic instability in the free shear layer, which may play a secondary process in the headland wake.
    Description: Yu‐Hsin Cheng was supported by the CWB of Taiwan through Grant 1062076C. Ming‐Huei Chang was supported by the Ministry of Science and Technology of Taiwan (MOST) under Grants 103‐2611‐M‐002‐018, 105‐2611‐M‐002‐012, and 107‐2611‐M‐002‐015. Sen Jan was supported with MOST Grants 101‐2611‐M‐002‐018‐MY3, 103‐2611‐M‐002‐011, and 105‐2119‐M‐002‐042. Magdalena Andres was supported by the U.S. Office of Naval Research Grant N000141613069.
    Description: 2020-10-23
    Keywords: Kuroshio ; Submesoscale eddy ; Headland ; Recirculation ; Eddy corotation ; Barotropic instability
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 2
    Publication Date: 2022-05-26
    Description: © The Author(s), 2017. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Ocean Modelling 121 (2018): 49-75, doi:10.1016/j.ocemod.2017.11.008.
    Description: Lagrangian analysis is a powerful way to analyse the output of ocean circulation models and other ocean velocity data such as from altimetry. In the Lagrangian approach, large sets of virtual particles are integrated within the three-dimensional, time-evolving velocity fields. Over several decades, a variety of tools and methods for this purpose have emerged. Here, we review the state of the art in the field of Lagrangian analysis of ocean velocity data, starting from a fundamental kinematic framework and with a focus on large-scale open ocean applications. Beyond the use of explicit velocity fields, we consider the influence of unresolved physics and dynamics on particle trajectories. We comprehensively list and discuss the tools currently available for tracking virtual particles. We then showcase some of the innovative applications of trajectory data, and conclude with some open questions and an outlook. The overall goal of this review paper is to reconcile some of the different techniques and methods in Lagrangian ocean analysis, while recognising the rich diversity of codes that have and continue to emerge, and the challenges of the coming age of petascale computing.
    Description: EvS has received funding from the European Research Council (ERC) under the European Unions Horizon 2020 research and innovation programme (grant agreement No 715386). This research for PJW was supported as part of the Energy Exascale Earth System Model (E3SM) project, funded by the U.S. Department of Energy, Office of Science, Office of Biological and Environmental Research. Funding for HFD was provided by Grant No. DE-SC0012457 from the US Department of Energy. PB acknowledges support for this work from NERC grant NE/R011567/1. SFG is supported by NERC National Capability funding through the Extended Ellett Line Programme.
    Keywords: Ocean circulation ; Lagrangian analysis ; Connectivity ; Particle tracking ; Future modelling
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 22 (1999), S. 11-16 
    ISSN: 0935-6304
    Keywords: Pyrolysis gas chromatography ; microstructure determination ; syndiotactic copolymers ; styrenes ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---The composition and microstructure of syndiotactic para-methylstyrene/styrene copolymer was determined by a pyrolysis gas chromatography (Py-GC) method. This method uses the styrene and para-methylstyrene monomer peak intensities to determine the styrene and para-methylstyrene composition in the copolymer. The number average sequence length of styrene was calculated by using the triad peak intensities. Because of the low concentration of para-methylstyrene in the copolymer, the number average sequence length of para-methylstyrene was determined with formulas that incorporate the copolymer composition and the number average sequence length of styrene. The distribution of para-methylstyrene defined by the terms “percent of single units” and “percent of desired distribution” was calculated by the number average sequence of para-methylstyrene. This method has been tested with copolymers containing up to 24 mole% of para-methylstyrene. The composition results from Py-GC of para-methylstyrene and styrene copolymers used in this study were in excellent agreement with 1H-NMR results.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    X-Ray Spectrometry 23 (1994), S. 203-207 
    ISSN: 0049-8246
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Submicrometer phase quantitative analysis is always a challenging problem for electron beam microanalysis because the phase is smaller than the electron beam and the specimen interaction volume. In order to obtain more accurate composition information, other analytical techniques need to be used to clarify the elements present and characterize the valence state of major elements in that submicrometer phase In this study, the electron probe microanalyzer (EPMA) was used to determine the contamination phase in the tungsten carbide-cobalt ceramic system. The average size of the contamination phase was approximately 0.5 μm in diameter. The chemical composition of the contamination phase was elucidated by combining results from x-ray mapping, valence state determination and EPMA quantitative analysis data. The effect of the contamination phase in the tungsten carbide-cobalt ceramic system is also discussed.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    X-Ray Spectrometry 23 (1994), S. 272-277 
    ISSN: 0049-8246
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Owing to improvements in impregnation techniques, the impregnation of copper compounds into a zeolite framework to form copper zeolite catalysts results in more uniformly distributed and finer (nanoscale size) copper-containing particles. In order to determine the oxidation state of copper in a copper zeolite catalyst, a method utilizing the X-ray absorption-induced (absorption edge/self-absorption) effect was developed using electron probe microanalysis. This method can provide oxidation state information that is not possible with traditional quantitative microanalysis owing to the electron beam and specimen interaction volume. The advantages and limitations of this method are discussed.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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