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  • 1
    Keywords: Chemistry, Organic ; Chemistry
    Description / Table of Contents: The volumes contain contributions on various topics related to the origin, distribution, chemistry, synthesis, biochemistry, function or use of various classes of naturally occurring substances ranging from small molecules to biopolymers. Each contribution is written by a recognized authority in his field and provides a comprehensive and up-to-date review of the topic in question.
    Type of Medium: Online Resource
    Pages: Online-Ressource (IX, 212 p. 12 illus., 1 coloured plate, digital)
    ISBN: 9783211493892
    Series Statement: Fortschritte der Chemie organischer Naturstoffe / Progress in the Chemistry of Organic Natural Products 88
    Language: English
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  • 2
    Publication Date: 2021-07-24
    Description: This project has focused on better understanding the potential impact of On-Farm Flood Capture and Recharge (OFFCR) on groundwater quality pertaining to salts and nitrate and on assessing potential management opportunities. To achieve these goals, we used a combination of field and modeling studies. For the field study, soil cores were taken to a depth of 30 feet in replicate across fields with three different specialty crops identified as important to the San Joaquin Valley (tomatoes, almonds, vineyards) and with potential suitability for OFFCR. A prime goal of the field study was to provide data for parameterizing two models developed to assess nitrate, salt and water transport through the vadose zone, prior to percolating into the groundwater aquifer.However, the field study also resulted in key findings that show its value as a stand-alone study: 1) Nitrate concentrations are highest in the upper vadose zone and affected by texture. Those effects are not evident in the deeper vadose zone. 2) Vadose zone nitrate concentrations are affected by the crop grown. These results suggest an opportunity for lower legacy mass transport for grapes and higher legacy mass transport for both tomatoes and almonds.3) Variability in individual farmers’ past and present fertilizer and water management practices contributes to different legacy salt and nitrate loads in the vadose zone.Data from the field study and other related and concurrent OFFCR field efforts were used during model development. The overall modeling approach was designed to model nitrate and salt transport for lands under OFFCR operation for different crop types, vadose zone characteristics and groundwater characteristics. The defined goals of this design and modeling approach were to: 1) model nitrate and salt movement through the vadose zone and into groundwater; 2) test the model against scenarios that consider different recharge rates, cultural practices, soil types, and depths to groundwater, assessing the timing and magnitude of loading through the vadose zone and the effects on underlying groundwater; and 3) recommend management practices to mitigate potential groundwater impacts. To achieve these goals, two models were integrated to simulate nitrate and salt transport through the vadose zone to groundwater under different scenarios: a 1D Hydrus model and an analytical groundwater model (AGM).
    Description: USDA Specialty Crop Block Grants, CA. Grant Agreement SCB14028
    Description: Nitrate Leaching Risk from Specialty Crop Fields During On-Farm Managed Floodwater Recharge in the Kings Groundwater Basin [USDA Project No: PIN #26174]
    Description: Groundwater Recharge Project, 2016
    Description: On-Farm Recharge Studies, Central Valley, CA
    Keywords: Agriculture ; Chemistry ; Earth Sciences ; Engineering ; Environment ; Management ; Planning ; Pollution ; on-farm recharge ; floodmar ; groundwater ; management ; agriculture ; water quality ; vadose zone ; nitrate ; BMPs ; Kings Groundwater Basin
    Repository Name: AquaDocs
    Type: monograph
    Format: application/pdf
    Format: application/pdf
    Format: 27
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Rapid Communications in Mass Spectrometry 9 (1995), S. 91-92 
    ISSN: 0951-4198
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: A sample of poly(methyl methacrylate) (PMMA), of which the molecular weight was known from light-scattering measurements, was subjected to gel-perrneation-chromatographic analysis, and the resulting Weight versus log molecular weight (MW) plot was converted by suitable computation to a Number versus linear MW plot. This could then be compared directly with the matrix-assisted laser desorption ionization MW distribution results obtained for the same sample. The MW distributions obtained by the two methods were significantly different. Two explanations for the discrepancy are offered.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 45 (1992), S. 937-945 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Processing operations such as milling, change the chemical structure of rubber. Infrared (IR) spectroscopy and electron spectroscopy for chemical analysis (ESCA) have been used to detect the formation of functional groups during the milling of natural rubber (NR), epoxidised natural rubber (ENR), styrene butadiene rubber (SBR), neoprene (CR), and acrylic rubber (AR). The concentration of carbonyl () groups as detected by IR spectroscopy increases with the time of milling for all the rubbers. The concentration of hydroxyl groups (—OH) in NR and ENR also increases during milling. ESCA spectra of the rubbers before and after milling reveal that the peaks are broader for milled rubber, and that the concentration of oxygen is also greater. In the case of ENR, however, the concentration of epoxide rings decreases and that of furan rings increases with the time of milling.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 58 (1995), S. 1947-1957 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The blends of epoxidized natural rubber (50 mol %) (ENR) and poly(ethylene-co-acrylic acid) (PEA) (6 wt %) are demonstrated to be partially miscible up to 50% by weight of PEA and completely miscible beyond this proportion. The miscibility has been confirmed by a DSC study which exhibits a single second-order transition (Tg) for the 30 : 70 and 50 : 50 (ENR : PEA) blends. For the 70 : 30 (ENR : PEA) blend, the Tg's shift toward an intermediate value but do not merge to form a single Tg, making the blend partially miscible. The miscibility has been assigned to the esterification reaction between - OH groups formed in situ during melt blending of ENR and - COOH groups of PEA. The occurrence of such reactions have been confirmed by UV and IR spectroscopic studies. The existence of a single phase of the blends beyond 50 wt % of PEA has been shown by SEM studies. © 1995 John Wiley & Sons, Inc.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 9 (1965), S. 3439-3450 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: It was shown that the realization of a straight log I-h2 curve may be a coincidence depending on the relative influence of heterogeneity of distribution and non-independent scattering, and a concave log I-h2 curve can represent a nonhomogeneous system amenable to Shull and Roess's method of analysis. The results indicate: (1) The I-h curve for a jute holo-cellulose film has a maximum, and that for a ramie film an inflexion point, each superimposed on a background of gradually declining intensity, and in either case the singularity is accentuated and shifted to a region of larger angle on alkali-treatment. (2) The log I-h2 plots for untreated, alkali-treated and stretched jute fibers give straight sections in the low-angle, and convex, concave, and straight sections, respectively, in the high-angle region. An interesting feature of the results for ramie is the realization of a straight logarithmic curve on mercerization. The curves for alkali-treated and stretched Fortisan fibers have also each of them two discernible linear parts, indicative of two groups of scatterers. (3) An evaluation of the log I-log h2 curves by Shull and Roess's method leads to figures for the diameters of the scattering elements in ramie comparable to those estimated from the corresponding log I-h2 plots.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 9 (1965), S. 3427-3437 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: It was shown that the shape of the scattering pattern is not only related to the shape but also to the face-orientation of the lamellar scattering units, and an actual observation of its characteristic shape depends on the amount and dispersion of their spiral angle. The following results were obtained: (1) For observing a cross-pattern, the critical spiral angles corresponding to minimum and maximum dispersions are 7.5° and 30° respectively, whereas in an actual fiber, coir, the critical angle is about 16.75°. (2) The jute pattern changes from a uniformly narrow to a triangular shape on disorientation and reverts to the former on reorientation. The corresponding changes in ramie are from a triangular to a uniformly wide and then to a uniformly narrow shape. Both native and disoriented cottons give weak, fan-shaped scattering superimposed on a more intense elliptical pattern. The pattern given by reoriented cotton is roughly a narrow streak. Delignified jute gives a somewhat shaving-brush-shaped pattern which changes to a uniformly wide streak on alkali treatment. (3) The extent of scattering decreases on swelling and increases on stretching in jute, ramie, and cotton, but decreases in stretched coir.
    Additional Material: 25 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 25 (1980), S. 1737-1744 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effect of heat treatment in the presence and absence of a nonionic surfactant (Triton X-100) on selected properties of polyester fabric was studied over the temperature range 180-220°C. Although significant heat-induced area shrinkage was evident (4.9-9.5%) in the treated polyester fabrics, stiffness, wrinkle recovery, tensile properties, moisture regain, and density of the fabrics showed only slight changes. The moisture-related properties of surfactant/heat-treated polyester were greatly improved compared to untreated control polyester or polyester subjected to heat treatment alone. Oligomer formation on the surface of surfactant-treated polyester was altered as a result of the presence of surfactant on heating compared to polyester heated alone at 180-220°C. Polyester heat treated in the presence and absence of surfactant showed increased dye uptake and more depth of color with 1,4-substituted anthraquinone dyes than untreated polyester, and these effects increased with increasing treatment temperature.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 21 (1979), S. 775-785 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Equine liver alcohol dehydrogenase (EC 1.1.1.1) has been purified by a new scheme using a blue agarose gel (Blue Sepharose) as an affinity sorbent. Starting amounts of 0.6 to 10 kg liver have been processed to enzyme possessing 1.5 U/mg average specific activity, in about three to four days. Some parameters concerning adsorption of enzyme to the blue gel as well as recovery therefrom have been explored.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 25 (1979), S. 900-903 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This study concerns the determination of stagnation point and minimum pressure point film thicknesses when a vertical flat plate is withdrawn from a reservoir containing non-Newtonian liquids. Upon consideration of three types of liquids, namely, Ellis, power law, and Bingham liquids, it has been found that stagnation point or minimum pressure point film thickness is a function of two parameters, one characterizing the liquid and the other representing parallel flow film thickness. It has also been shown that in the case of power law liquids, both the stagnation point and minimum pressure point exist, while in the case of Bingham liquids, the existence of one or both the points for a given nondimensional parallel flow film thickness depends upon the value of the Bingham number. Furthermore, it has been found that there may be situations when both the points can coincide; for example, in the case of Newtonian liquids, the two points coincide if the parallel flow film thickness is \documentclass{article}\pagestyle{empty}\begin{document}$ \sqrt {2 - \sqrt 3 } $\end{document}.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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