Keywords:
Organometallic compounds - Collected works.
;
Electronic books.
Description / Table of Contents:
This Specialist Periodical Report aims to reflect the growing interest in the potential of organometallic chemistry.
Type of Medium:
Online Resource
Pages:
1 online resource (539 pages)
Edition:
1st ed.
ISBN:
9781847553911
Series Statement:
Issn Series
URL:
https://ebookcentral.proquest.com/lib/geomar/detail.action?docID=1185874
DDC:
547.05
Language:
English
Note:
Organometallic Chemistry -- Contents -- Chapter 1 Group I. The Alkali and Coinage Metals -- 1 Lithium -- Structural and Bonding Studies -- Polylithio-compounds -- Halogenocarbon Derivatives -- Some Organic Reactions -- 2 Sodium and Potassium -- 3 Copper, Silver, and Gold -- Copper and Silver π-Complexes -- σ-Bonded Organo-copper and -silver Compounds -- Gold -- Chapter 2 Group II. The Alkaline Earths and Zinc and its Congeners -- 1 Beryllium -- 2 Magnesium -- Preparation and Composition -- Reactions -- Inversions and Rearrangements -- Halogenocarbon Derivatives -- 3 Calcium, Strontium, and Barium -- 4 Zinc and Cadmium -- 5 Mercury -- Preparative Reactions -- Mercuration and Demercuration Reactions -- Other Reactions -- Carbene Precursors -- Chapter 3 Group III. Boron, Aluminium, Gallium, Indium, and Thallium -- 1 Introduction -- 2 Boron -- General -- Preparations -- Radical Reactions -- Mechanisms and Kinetics -- Preparative Reactions involving Radicals -- Non-radical Mechanisms and Kinetics -- Nucleophilic Displacements at Tetrahedral Boron Centres -- Displacement of the Alkyl Groups attached to Boranes -- Olefin Elimination and Addition -- Reactions of R3B -- Organic Reactions of R3B -- Hydrido-organoboranes -- Compounds containing Boron-Nitrogen Bonds -- Borinic and Boronic Acids and their Derivatives -- Synthesis -- Reactions -- Compounds containing Boron-Chalcogen Bonds -- Compounds containing Boron-Halogen Bonds -- 3 Aluminium -- Preparations and Reactions -- Structures, Bonding, and Exchange Reactions -- Organic Applications -- Mechanisms and Kinetics -- Various Reactions -- Transition-metal-Organoaluminium Systems -- 4 Gallium -- 5 Indium -- 6 Thallium -- Trialkylthalliums-R3T1 -- Dialkylthallium and Diarylthallium Compounds-R2T1X -- Monoalkylthallium and Monoarylthallium Compounds-RT1X2 -- Organic Reactions.
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Thallium(i) Cyclopentadienides -- Chapter 4 Group III. The Carboranes -- Chapter 5 Group IV. The Silicon Group -- 1 Introduction -- 2 Formation of the Carbon-Metal Bond Synthesis -- Reactions of M-C Compounds -- 3 Cleavage of the Carbon-Metal Bond -- 4 Mechanistic Studies of Carbon-Metal Bond Cleavage -- Rearrangement Reactions involving the Silicon-Carbon Bond -- 5 Thermochemical, Spectroscopic, and Structural Studies -- 6 Cyclopentadienyl Derivatives of the Group IV Elements -- 7 Addition Reactions -- 8 Alkali-metal Derivatives R3MM' -- 9 Catenation -- 10 Carbenes and their Silicon Group Congeners -- 11 Mercury Derivatives -- 12 Free Radicals -- 13 Hydrides of Silicon and Germanium -- 14 Organotin Hydrides -- 15 Boron Derivatives -- 16 Nitrogen Derivatives -- Diazo-compounds -- Azides -- Addition Reactions -- Silazanes -- Aminosilanes -- 17 Phosphine, Arsine, and Stibine Derivatives -- 18 Silicon-Oxygen Compounds -- Alkoxysilanes and Siloxanes -- Rearrangements involving Compounds containing the Si-O Bond -- Silyl Esters -- Organosilicon Peroxides -- 19 Germanium-Oxygen Compounds -- 20 Tin-Oxygen Compounds -- 21 Sulphur Derivatives -- 22 Lead-Oxygen and Lead-Halogen Compounds -- 23 Halogen Exchange Reactions -- 24 Complexes of Silicon, Germanium, Tin, and Lead -- 25 Structural Determinations -- 26 Bonding in Group IV Organometallic Compounds -- Chapter 6 Metal Carbonyls -- 1 Introduction -- 2 Spectroscopic Studies -- 3 Preparation of Carbonyl Compounds -- 4 Hydrido(carbonyl)metal Complexes -- 5 Halogeno- and Azido-(carbonyl)metal Complexes -- Chapter 7 Organometallic Compounds containing Metal-Metal Bonds -- 1 Introduction -- 2 Compounds containing Transition Metal-Transition Metal Bonds -- Compounds containing Isolated Bonds and Bond Sequences -- Transition Metal Clusters.
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3 Compounds containing Bonds between Transition Metals and the Elements of Groups IB-VB -- Group IB -- Group IIB -- Group IIIB -- Boron -- Aluminium -- Indium and Thallium -- Group IV -- General Preparative Work -- The Nature of the Metal-Metal Bond -- Titanium Group -- Chromium Group -- Manganese Group -- Iron Group -- Cobalt Group -- Nickel Group -- Group V -- 4 Compounds containing Group IIB-Group IV Element Bonds -- Chapter 8 Substitution Reactions of Metal and Organo-metal Carbonyls with Group V and VI Donor Ligands -- 1 Introduction -- 2 General Papers on Metal Carbonyl Complexes -- 3 Group V -- 4 Group VI -- Complexes of Cr°, Mo° and W° -- Halogenocarbonyl Complexes of and IIMo WII -- Cyclopentadienyl Carbonyl Complexes of MoII and WII -- 5 Group VII -- Complexes of Mn° and Re0 -- Cyclopentadienyl Carbonyl Complexes of MnI -- Other Complexes of MnI and ReI -- 6 Group VIII: Fe, Ru, and Os -- Complexes of the Cluster Carbonyls -- Mononuclear Complexes of Fe° and Ru° -- Complexes containing the M2(CO)6 Unit (M = Fe or Ru) -- Cyclopentadienyl Carbonyl Complexes of FeII -- Other Complexes of FeII, RuII, and OsII -- 7 Group VIII: Co, Rh, and Ir -- Complexes of Co0, Rh°, and Ir° -- Complexes of Co1, Rh1, and Ir1 -- 8 Group VIII: Ni, Pd, and Pt -- 9 Copper -- Chapter 9 Carbene, Nitrene, and Related Complexes -- 1 Synthesis of Carbene Complexes -- 2 Structure and Bonding in Carbene Complexes -- 3 Reactions of Carbene Complexes -- 4 Nitrene Complexes -- Chapter 10 Complexes containing Metal-Carbon σ-Bonds -- 1 σ-Bonded Complexes -- Group IV -- Group V -- Group VI -- Group VII -- Group VIII -- Group I -- 2 Compounds Derived from Carbonylmetal Anions -- 3 Insertion Reactions -- Carbon Monoxide (and Decarbonylation Reactions) -- Sulphur Dioxide -- Olefins and Acetylenes -- Tetracyanoethylene -- Isocyanides -- 4 ortho-Metallation and Related Reactions.
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Nitrogen Donors -- Phosphorus Donors -- Carbon Donors -- Sulphur Ligands -- 5 Formation of M-C σ-Bonds from Olefin or Diene Complexes -- 6 Cobaloximes, Cobalamins, and Related Compounds -- 7 Organic Derivatives of Schiff-base Complexes -- Chapter 11 Hydrocarbon-Metal π-Complexes -- 1 Bonding in Mono-olefin and Acetylene Complexes -- 2 Mono-olefin Complexes -- 3 Mono-olefin Chelate Complexes -- 4 Acetylene Complexes -- 5 Acyclic Conjugated Diolefin Complexes -- 6 Cyclic Conjugated Diolefin Complexes -- Cyclobutadiene Complexes -- Cyclopentadiene Complexes -- Complexes of Six- and Seven-membered Rings -- Complexes of Eight-membered Rings -- 7 Complexes of Chelating Unconjugated Diolefins -- 8 Cationic Metal-Olefin and -Acetylene Complexes -- 9 Complexes Derived from Allenes and from Trimethyl-enemethane -- 10 Complexes of Polycyclic Hydrocarbons -- Chapter 12 π-Allylic Complexes -- 1 General Developments -- 2 Tantalum -- 3 Iron, Ruthenium, and Osmium -- 4 Cobalt, Rhodium, and Iridium -- 5 Nickel, Palladium, and Platinum -- Chapter 13 π-Cyclopentadlenyl, Arene, and Related Compounds -- 1 Introduction -- 2 π-Cyclopentadienyl Complexes -- Features of General Interest -- Group IV -- Preparation of Complexes -- Other Studies -- Group V -- Group VI -- Preparation of Complexes -- Other Studies -- Group VII -- Group VIII: Fe, Ru, and Os -- Preparation of Complexes -- Other Studies -- Group VIII: Co, Rh, and Ir -- Group VIII: Ni, Pd, and Pt -- Preparation of Complexes -- Other Studies -- Other Metals -- 3 π-Arene Complexes -- Group VI -- Preparation of Complexes -- Other Studies -- Group VII -- Group VIII: Fe, Ru, and Os -- Group VIII: Co, Rh, and Ir -- Group VIII: Ni -- Uranium -- 4 Carborane Complexes -- The [B9C211]2- Ligand and Related Systems -- Other Carborane Ligands -- Theory of Bonding in Carborane Complexes -- 5 Complexes with Other Related Ligands.
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Tris(pyrazolyl)borate Complexes -- Borabenzene Complexes -- Borazole Complexes -- Pyrrole and Pyrrolyl Complexes -- Thiophen Complexes -- Chapter 14 Substitution Reactions of Hydrocarbon-Metal π-Complexes -- 1 Introduction -- 2 Results of General Interest -- 3 Individual Systems -- OC6H6)Cr(CO)3 (Benchrotrene) -- [(Tropylium)Cr(CO)3]+ and Related Complexes -- (π-C5H5)Mn(CO)3 (Cymantrene) -- (π-C4H4)Fe(CO)3 -- (π-Diene)Fe(CO)3 Complexes -- [(π-C5H5)Fe(π-C6H6)]+ Complexes -- (π-CsHs)2Co and Derived (π-C5H5)Co(π-diene) Complexes -- Cobalt-Carbon Cluster Compounds -- 4 Chemistry of the Iron-group Metallocenes (Ferrocene, Ruthenocene, and Osmocene) -- General -- General Chemistry -- Proton N.M.R. Studies -- Stereochemistry of Ferrocenes -- Biferrocenyls and Bridged Ferrocenes (Ferro-cenophanes) -- Polymeric Ferrocene Derivatives -- Ferrocene Derivatives containing Heteroatoms -- Boron -- Silicon and Germanium -- Phosphorus and Arsenic -- Sulphur -- Transition Metals -- Ferricinium Salts -- Chapter 15 Oxidative-addition and Related Reactions -- 1 Niobium and Tantalum -- 2 Chromium, Molybdenum, and Tungsten -- 3 Iron, Ruthenium, and Osmium -- 4 Cobalt, Rhodium, and Iridium -- 5 Nickel, Palladium, and Platinum -- Chapter 16 Homogeneous Catalysis -- 1 General -- 2 Hydrogenation -- 3 Isomerization -- 4 Skeletal Rearrangements -- 5 Rearrangement of Strained Cycloalkanes -- 6 Hydroformylation and Related Reactions -- 7 Dimerization and Oligomerization -- 8 Oxidation -- 9 Synthesis -- Reduction of Dinitrogen -- Chapter 17 X-Ray and Electron Diffraction Studies of Organometallic Compounds -- 1 Introduction -- Coverage -- Symbols, Abbreviations, and Conventions -- 2 Main Table Listing Compounds and Structural Data -- 3 Cross-reference Lists -- Metal Listings -- Ligand Listings -- Author Index.
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