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  • Seafloor massive sulfides  (2)
  • Analytic techniques  (1)
  • Atlantic; BC; Box corer; BXC-02; BXC-05; FLAME 2; POS240; POS240_316; POS240_343; Poseidon  (1)
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  • 1
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    PANGAEA
    In:  Supplement to: Chavagnac, Valerie; German, Christopher R; Milton, J Andy; Palmer, Martin R (2005): Sources of REE in sediment cores from the Rainbow vent site (36°14'N, MAR). Chemical Geology, 216(3-4), 329-352, https://doi.org/10.1016/j.chemgeo.2004.11.015
    Publication Date: 2023-06-27
    Description: A geochemical investigation was carried out on two sediment cores collected at 2 and 5 km from the Rainbow hydrothermal vent site. Bulk sediment compositions indicate that these cores record clear enrichments in Fe, Cu, Mn, V, P and As from hydrothermal plume fallout (Cave et al., 2002, doi:10.1016/S0016-7037(02)00823-2). Sequential dissolution of the bulk sediments has been used to discriminate between a leach (biogenic and oxy-hydroxide) component and a residual phase (detrital and sulphide/sulphate fractions). Major element data (Al, Fe, Ti, Mn, Mg, Ca, Si and index%) reveal that the hydrothermal input, as recorded in the leach phase, is much stronger than apparent from bulk sediment analyses alone. REE patterns for the leach phase record contributions from both biogenic carbonate (mimicking seawater REE patterns) and hydrothermal oxy-hydroxides, with the latter exhibiting positive Eu anomalies (hydrothermal derived) and negative Ce anomalies (seawater derived). Based on major element and REE data, the residue contains contributions from aeolian dust input, local MORB material and a hydrothermal component. Ternary REE mixing calculations indicate that most of the REE within the residual fraction (~80%) is derived from hydrothermal material, while detrital contributions to the REE budget, as deep-sea clay and volcanic debris, are 〈20%. By combining bulk and REE data for the various end-member components of the residue, we calculate that the chemical composition of the residue hydrothermal end-member is high in Ca (6-15%) and with a Nd/Sr ratio of 0.004. These characteristics indicate the presence of low-solubility hydrothermal sulphate (rather than sulphide) material within the residue component of Rainbow hydrothermal sediments.
    Keywords: Atlantic; BC; Box corer; BXC-02; BXC-05; FLAME 2; POS240; POS240_316; POS240_343; Poseidon
    Type: Dataset
    Format: application/zip, 4 datasets
    Location Call Number Limitation Availability
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  • 2
    Publication Date: 2022-05-25
    Description: Author Posting. © The Author(s), 2009. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Marine Policy 34 (2010): 728-732, doi:10.1016/j.marpol.2009.12.001.
    Description: The potential emergence of an ocean mining industry to exploit seafloor massive sulfides could present opportunities for oceanographic science to facilitate seafloor mineral development in ways that lessen environmental harms.
    Description: The authors are grateful for support from the Elisabeth and Henry Morss, Jr. Colloquia Fund, the ChEss (Chemosynthetic Ecosystems) Project of the Census of Marine Life, InterRidge, the Ridge 2000 Program of the National Science Foundation, and the authors’ institutions.
    Keywords: Ocean mining ; Seafloor massive sulfides ; Law of the sea ; Economics ; Environmental assessment
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
    Format: application/pdf
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  • 3
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 10 (2009): Q05T05, doi:10.1029/2008GC002314.
    Description: This paper demonstrates that a Raman spectroscopy, point-counting technique can be used for phase analysis of minerals commonly found in deep-sea hydrothermal plumes, even for minerals with similar chemical compositions. It also presents our robust autonomous identification algorithm and spectral database, both of which were developed specifically for deep-sea hydrothermal studies. The Raman spectroscopy expert algorithm was developed and tested against multicomponent mixtures of minerals relevant to the deep-sea hydrothermal environment. It is intended for autonomous classification where many spectra must be examined with little or no human involvement to increase analytic precision, accuracy, and data volume or to enable in situ measurements and experimentation.
    Description: Support for J.A.B. was provided through a RIDGE 2000 Postdoctoral Fellowship (NSF OCE-0550331).
    Keywords: Hydrothermal ; Mineralogy ; Optical instruments ; Raman spectroscopy ; Analytic techniques ; Chemical sensor
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
    Format: text/plain
    Format: application/zip
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  • 4
    Publication Date: 2022-05-25
    Description: © The Author(s), 2015. This is the author's version of the work and is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Chemical Geology 420 (2016): 114-126, doi: 10.1016/j.chemgeo.2015.11.006.
    Description: Here, we review the relationship between the distribution of modern-day seafloor hydrothermal activity along the global mid-ocean ridge crest and the nature of the mineral deposits being formed at those sites. Since the first discovery of seafloor venting, a sustained body of exploration has now prospected for one form of hydrothermal activity in particular – high temperature “black smoker” venting - along 〉30% of the global mid ocean ridge crest. While that still leaves most of that ~60,000km continuous network to be explored, some important trends have already emerged. First, it is now known that submarine venting can occur along all mid-ocean ridges, regardless of spreading rate, and in all ocean basins. Further, to a first approximation, the abundance of currently active venting, as deduced from water column plume signals, can be scaled linearly with seafloor spreading rate (a simple proxy for magmatic heat-flux). What can also be recognized, however, is that there is an “excess” of high temperature venting along slow and ultra-slow spreading ridges when compared to what was originally predicted from seafloor spreading / magmatic heat-budget models. An examination of hydrothermal systems tracked to source on the slow spreading Mid Atlantic Ridge reveals that no more than half of the sites responsible for the “black smoker” plume signals observed in the overlying water column are associated with magmatic systems comparable to those known from fast- spreading ridges. The other half of all currently known active high-temperature submarine systems on the Mid-Atlantic Ridge are hosted under tectonic control. These systems appear both to be longer-lived than, and to give rise to much larger sulfide deposits than, their magmatic counterparts - presumably as a result of sustained fluid flow. A majority of these tectonic-hosted systems also involve water-rock interaction with ultramafic sources. Importantly, from a mineral resource perspective, this subset of tectonic-hosted vent-sites also represents the only actively-forming seafloor massive sulfide deposits on mid-ocean ridges that exhibit high concentrations of Cu and Au in their surface samples (〉10wt.% average Cu content and 〉3ppm average Au). Along ultraslow-spreading ridges, first detailed examinations of hydrothermally active 74 sites suggest that sulfide deposit formation at those sites may depart even further from the spreading-rate model than slow-spreading ridges do. Hydrothermal plume distributions along ultraslow ridges follow the same (~50:50) distribution of “black smoker” plume signals between magmatic and tectonics settings as the slow spreading MAR. However, the first three “black smoker” sites tracked to source on any ultra-slow ridges have all revealed high temperature vent-sites that host large polymetallic sulfide deposits in both magmatic as well as tectonic settings. Further, deposits in both types of setting have now been revealed to exhibit moderate to high concentrations of Cu and Au, respectively. An important implication is that ultra- slow ridges may represent the strongest mineral resource potential for the global ridge crest, despite being host to the lowest magmatic heat budget.
    Description: Preparation of this review has benefited from research support to CRG, SP and MDH from the Woods Hole Oceanographic Institution, USA, from GEOMAR and the Helmholtz Foundation, Germany and from NSERC, Canada. The opportunity to discuss ideas and bring together our different perspectives - from water column geochemistry and seafloor massive sulfide studies - was facilitated by a Research Award from the Alexander von Humboldt Foundation to CRG.
    Description: 2016-11-14
    Keywords: Hydrothermal activity ; Seafloor massive sulfides ; Mid-ocean ridges ; Exploration ; Copper ; Gold
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
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