ISSN:
1572-9001
Keywords:
Acyl azides
;
Curtius rearrangement
;
enthalpy of formation
;
enthalpy of reaction
;
phenyl/vinyl thermochemical equivalence, resonance energy
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract By means of the generic isodesmic reaction C6H5COX + RCH3 → C6H5COCH3 + RX, the phenyl/vinyl thermochemical equivalence, and an experimental determination of the enthalpy of the Curtius rearrangement of acryloyl azide, the resonance energy of acyl azides was ascertained to be ca. 29 kJ mol−1.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1022055304484
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