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  • 1
    Electronic Resource
    Electronic Resource
    Paradigms and Paradoxes Are Acyl Azides Resonance Stabilized? (1999)
    Springer
    Structural chemistry 10 (1999), S. 327-329 
    Details
    ISSN: 1572-9001
    Keywords: Acyl azides ; Curtius rearrangement ; enthalpy of formation ; enthalpy of reaction ; phenyl/vinyl thermochemical equivalence, resonance energy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract By means of the generic isodesmic reaction C6H5COX + RCH3 → C6H5COCH3 + RX, the phenyl/vinyl thermochemical equivalence, and an experimental determination of the enthalpy of the Curtius rearrangement of acryloyl azide, the resonance energy of acyl azides was ascertained to be ca. 29 kJ mol−1.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022055304484
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  • 2
    Electronic Resource
    Electronic Resource
    Evaluation of strain in heterosiliranes: Systematics, surprises, and problems (1996)
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 58 (1996), S. 707-715 
    Details
    ISSN: 0020-7608
    Keywords: Chemistry ; Theoretical, Physical and Computational Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A series of different isodesmic and homodesmic reactions defining strain energies in 3-membered rings are described and discussed. One isodesmic and one homodesmic reaction are applied numerically with the purpose of estimating strain in heterosiliranes including second-row and third-row heteroatoms. All molecules involved are optimized using SCF/6-31G**, and energies are calculated using MP2/6-31G**//SCF/6-31G** calculations. The results are discussed with reference to limitations of the chosen models. © 1996 John Wiley & Sons, Inc.
    Additional Material: 6 Tab.
    Type of Medium: Electronic Resource
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    Paper (German National Licenses)
  • 3
    Electronic Resource
    Electronic Resource
    Li12Si7: Theoretical Interest Aroused (1982)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 21 (1982), S. 1424-1428 
    Details
    ISSN: 0570-0833
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.198214240
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  • 4
    Electronic Resource
    Electronic Resource
    Li12Si7: Theoretical Interest Aroused (1982)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 21 (1982), S. 632-633 
    Details
    ISSN: 0570-0833
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: No Abstract.The complete manuscript of this communication appears in: Angew. Chem. Suppl. 1982, 1424. DOI:10.1002/anie.198214240
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.198206321
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  • 5
    Electronic Resource
    Electronic Resource
    Li12Si7  -  eine theoretische Untersuchung (1982)
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 94 (1982), S. 649-649 
    Details
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: No Abstract.Das vollständige Manuskript dieser Zuschrift erscheint in: Angew. Chem. Suppl. 1982, 1424-1428
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/ange.19820940829
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