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  • Activity coefficient  (2)
  • 33GG20080512-track; Algorithm; CT; DATE/TIME; Depth, bathymetric, interpolated/gridded; DEPTH, water; Distance; extracted from GLOBALVIEW-CO2; extracted from the 2-Minute Gridded Global Relief Data (ETOPO2); extracted from the NCEP/NCAR 40-Year Reanalysis Project; extracted from the World Ocean Atlas 2005; Fugacity of carbon dioxide (water) at equilibrator temperature (wet air); Fugacity of carbon dioxide (water) at sea surface temperature (wet air); Gordon Gunter; GU0802-2; LATITUDE; LONGITUDE; Pressure, atmospheric; Pressure, atmospheric, interpolated; Pressure at equilibration; Quality flag; Recomputed after SOCAT (Pfeil et al., 2013); Salinity; Salinity, interpolated; SOCAT; Surface Ocean CO2 Atlas Project; Temperature, water; Temperature at equilibration; Underway cruise track measurements; xCO2 (air), interpolated; xCO2 (water) at equilibrator temperature (dry air)  (1)
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  • 1
    ISSN: 1572-8927
    Keywords: Activity coefficient ; electromotive force ; Pitzer ; HCl ; Na2SO4 ; NaHSO4
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The electromotive force of HCl–Na2SO4 solutions has been determined from 5 to 50°C and ionic strengths from 0.5 to 6m with a Harned type cell $${\text{Pt; H}}_{\text{2}} ({\text{g, 1 atm}})|{\text{HCl(}}m_1 {\text{) + Na}}_{\text{2}} {\text{SO}}_{\text{4}} {\text{(}}m_2 {\text{)}}|{\text{AgCl, Ag}}$$ The results have been used to determine the activity coefficient of HCl in the mixtures. The activity coefficients have been analyzed with the Pitzer equations to account for the ionic interactions. The measurements were used to determine interaction coefficients (β0, β1) for NaHSO4 solutions from 5 to 50°C. The model represents the mean activity coefficients of HCl in the mixtures to ±0.005 over the entire temperature and concentration range of the measurements. The results have been combined with literature data to provide parameters that are valid from 0 to 250°C for NaHSO4 solutions.
    Type of Medium: Electronic Resource
    Location Call Number Limitation Availability
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  • 2
    ISSN: 1572-8927
    Keywords: Activity coefficient ; electromitive force ; Pitzer, HCl ; Na2SO4 ; NaHSO4
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The electromotive force of HCl−Na2SO4 solutions has been determined from 5 to 50°C and ionic strengths from 0.5 to 6m with a Harned type cell $$Pt; H_2 (g, 1 atm)|HCl(m_1 ) + Na_2 SO_4 (m_2 )|AgCl, Ag$$ The results have been used to determine the activity coefficient of HCl in the mixtures. The activity coefficiencts have been analyzed with the Pitzer equations to account for the ionic interactions. The measurements were used to determine interaction coefficients (β0, β1) for NaHSO4 solutions from 5 to 50°C. The model represents the mean activity coefficients HCl in the mixtures to ±0.005 over the entire temperature and concentration range of the measurements. The results have been combined with literature data to provide parameters that are valid from 0 to 250°C for NaHSO4 solutions.
    Type of Medium: Electronic Resource
    Location Call Number Limitation Availability
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  • 3
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    PANGAEA
    In:  NOAA-Atlantic Oceanographic and Meteorological Laboratory, Miami
    Publication Date: 2024-02-17
    Keywords: 33GG20080512-track; Algorithm; CT; DATE/TIME; Depth, bathymetric, interpolated/gridded; DEPTH, water; Distance; extracted from GLOBALVIEW-CO2; extracted from the 2-Minute Gridded Global Relief Data (ETOPO2); extracted from the NCEP/NCAR 40-Year Reanalysis Project; extracted from the World Ocean Atlas 2005; Fugacity of carbon dioxide (water) at equilibrator temperature (wet air); Fugacity of carbon dioxide (water) at sea surface temperature (wet air); Gordon Gunter; GU0802-2; LATITUDE; LONGITUDE; Pressure, atmospheric; Pressure, atmospheric, interpolated; Pressure at equilibration; Quality flag; Recomputed after SOCAT (Pfeil et al., 2013); Salinity; Salinity, interpolated; SOCAT; Surface Ocean CO2 Atlas Project; Temperature, water; Temperature at equilibration; Underway cruise track measurements; xCO2 (air), interpolated; xCO2 (water) at equilibrator temperature (dry air)
    Type: Dataset
    Format: text/tab-separated-values, 203856 data points
    Location Call Number Limitation Availability
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