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  • 165-999A; AGE; Alkenone C37:2, δ13C; Calculated; Calculated from UK'37 (Müller et al, 1998); Carbon dioxide, aquatic; Carbon dioxide, partial pressure; Carbon dioxide, partial pressure, standard deviation; Caribbean Sea; DEPTH, sediment/rock; DRILL; Drilling/drill rig; Fractionation of organic carbon; Globigerinoides ruber, δ13C; Henry's law constant; Isotopic fractionation; Joides Resolution; Leg165; Monte Carlo method; Phosphate; Physiological factors, sum; Salinity; Sample code/label; Sea surface temperature; δ13C, biomass; δ13C, carbon dioxide, aquatic; δ13C, carbon dioxide, gaseous  (1)
  • 165-999A; AGE; Alkenone, unsaturation index UK'37; Alkenone C37:2, δ13C; Carbon dioxide, intracellular; Carbon dioxide, partial pressure; Carbon dioxide, partial pressure, standard deviation; Carbon dioxide, partial pressure maximum; Carbon dioxide, partial pressure minimum; Caribbean Sea; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Globigerinoides ruber, δ13C; Henry's law constant; Isotopic fractionation; Isotopic fractionation, during photosynthis; Joides Resolution; Leg165; Ocean Drilling Program; ODP; Sample code/label; Sea surface temperature, annual mean; δ13C, biomass; δ13C, carbonate; δ13C, carbon dioxide, aquatic; δ13C, carbon dioxide, gaseous  (1)
  • Paleoclimate  (1)
Document type
Keywords
Years
  • 1
    Publication Date: 2022-05-26
    Description: © The Author(s), 2017. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Proceedings of the National Academy of Sciences of the United States of America 114 (2017): 13114-13119, doi: 10.1073/pnas.1702143114.
    Description: During the Mid-Pleistocene Transition (MPT; 1,200–800 kya), Earth’s orbitally paced ice age cycles intensified, lengthened from ∼40,000 (∼40 ky) to ∼100 ky, and became distinctly asymmetrical. Testing hypotheses that implicate changing atmospheric CO2 levels as a driver of the MPT has proven difficult with available observations. Here, we use orbitally resolved, boron isotope CO2 data to show that the glacial to interglacial CO2 difference increased from ∼43 to ∼75 μatm across the MPT, mainly because of lower glacial CO2 levels. Through carbon cycle modeling, we attribute this decline primarily to the initiation of substantive dust-borne iron fertilization of the Southern Ocean during peak glacial stages. We also observe a twofold steepening of the relationship between sea level and CO2-related climate forcing that is suggestive of a change in the dynamics that govern ice sheet stability, such as that expected from the removal of subglacial regolith or interhemispheric ice sheet phase-locking. We argue that neither ice sheet dynamics nor CO2 change in isolation can explain the MPT. Instead, we infer that the MPT was initiated by a change in ice sheet dynamics and that longer and deeper post-MPT ice ages were sustained by carbon cycle feedbacks related to dust fertilization of the Southern Ocean as a consequence of larger ice sheets.
    Description: Research was supported by National Environmental Research Council (NERC) Studentship NE/I528626/1 (to T.B.C.); NERC Grant NE/P011381/1 (to T.B.C., M.P.H., G.L.F., E.J.R., and P.A.W.); NERC Fellowships NE/K00901X/1 (to M.P.H.), NE/I006346/1 (to G.L.F. and R.D.P), and NE/H006273/1 (to R.D.P.); Royal Society Wolfson Awards (to G.L.F. and P.A.W.); Australian Research Council Laureate Fellowship FL1201000050 (to E.J.R.); Swiss National Science Foundation Grant PP00P2-144811 (to S.L.J.); ETH Research Grant ETH-04 11-1 (to S.L.J.); European Research Council Consolidator Grant (ERC CoG) Grant 617462 (to H.P.); and NERC UK IODP Grant NE/F00141X/1 (to P.A.W.).
    Keywords: Boron isotopes ; MPT ; Geochemistry ; Carbon dioxide ; Paleoclimate
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Location Call Number Limitation Availability
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  • 2
    Publication Date: 2023-08-17
    Keywords: 165-999A; AGE; Alkenone C37:2, δ13C; Calculated; Calculated from UK'37 (Müller et al, 1998); Carbon dioxide, aquatic; Carbon dioxide, partial pressure; Carbon dioxide, partial pressure, standard deviation; Caribbean Sea; DEPTH, sediment/rock; DRILL; Drilling/drill rig; Fractionation of organic carbon; Globigerinoides ruber, δ13C; Henry's law constant; Isotopic fractionation; Joides Resolution; Leg165; Monte Carlo method; Phosphate; Physiological factors, sum; Salinity; Sample code/label; Sea surface temperature; δ13C, biomass; δ13C, carbon dioxide, aquatic; δ13C, carbon dioxide, gaseous
    Type: Dataset
    Format: text/tab-separated-values, 940 data points
    Location Call Number Limitation Availability
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  • 3
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    PANGAEA
    In:  Supplement to: Badger, Marcus P S; Schmidt, Daniela N; Mackensen, Andreas; Pancost, Richard D (2013): High-resolution alkenone palaeobarometry indicates relatively stable pCO2 during the Pliocene (3.3-2.8 Ma). Philosophical Transactions of the Royal Society A-Mathematical Physical and Engineering Sciences, 371(2001), 20130094, https://doi.org/10.1098/rsta.2013.0094
    Publication Date: 2024-01-09
    Description: Temperature reconstructions indicate that the Pliocene was ~3 °C warmer globally than today, and several recent reconstructions of Pliocene atmospheric CO2 indicate that it was above pre-industrial levels and similar to those likely to be seen this century. However, many of these reconstructions have been of relatively low temporal resolution, meaning that these records may have failed to capture variations associated with the 41 Kyr glacial-interglacial cycles thought to operate in the Pliocene. Here we present a new, high temporal resolution alkenone carbon isotope based record of pCO2 spanning 2.8 to 3.3 million years ago from ODP Site 999. Our record is of high enough resolution (~19 Kyrs) to resolve glacial-interglacial changes beyond the intrinsic uncertainty of the proxy method. The record suggests that Pliocene CO2 levels were relatively stable, exhibiting variation less than 55 ppm. We perform sensitivity studies to investigate the possible effect of changing sea surface temperature, which highlights the importance of accurate and precise SST reconstructions for alkenone palaeobarometry, but demonstrate that these uncertainties do not affect our conclusions of relatively stable pCO2 levels during this interval.
    Keywords: 165-999A; AGE; Alkenone, unsaturation index UK'37; Alkenone C37:2, δ13C; Carbon dioxide, intracellular; Carbon dioxide, partial pressure; Carbon dioxide, partial pressure, standard deviation; Carbon dioxide, partial pressure maximum; Carbon dioxide, partial pressure minimum; Caribbean Sea; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Globigerinoides ruber, δ13C; Henry's law constant; Isotopic fractionation; Isotopic fractionation, during photosynthis; Joides Resolution; Leg165; Ocean Drilling Program; ODP; Sample code/label; Sea surface temperature, annual mean; δ13C, biomass; δ13C, carbonate; δ13C, carbon dioxide, aquatic; δ13C, carbon dioxide, gaseous
    Type: Dataset
    Format: text/tab-separated-values, 535 data points
    Location Call Number Limitation Availability
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