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  • Clay minerals  (2)
  • 11031300 Multicorer1; 11080952 Multicorer4; 11091335 Multicorer5; 11101338 Pistoncore5; 11120107 Multicorer8; 11161400 Multicorer11; 11172115 Multicorer12; 11181007 Multicorer13; 11191756 Piston core 8, TT013-PC72; 11230530 Multicorer18; 11240508 Multicorer19; 11270742 Multicorer22; 11290827 Multicorer25; 11291231 Pistoncore13; 12062238 Multicorer37; 178-1098B; Drake Passage; DRILL; Drilling/drill rig; Equatorial Pacific; GC; Gravity corer; JGOFS; Joides Resolution; Joint Global Ocean Flux Study; Leg178; MUC; MultiCorer; Ocean Drilling Program; ODP; PC; Piston corer; Thomas G. Thompson; TT013; TT013_104; TT013_113; TT013_114; TT013_148; TT013_23; TT013_27; TT013_32; TT013_4; TT013_41; TT013_58; TT013_63; TT013_66; TT013_72; TT013_88; TT013_93; W8803B; W8803B-51GC; Wecoma  (1)
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  • 1
    Publikationsdatum: 2022-05-25
    Beschreibung: © The Author(s), 2017. This is the author's version of the work. It is posted here under a nonexclusive, irrevocable, paid-up, worldwide license granted to WHOI. It is made available for personal use, not for redistribution. The definitive version was published in Chemical Geology 451 (2017): 38-54, doi:10.1016/j.chemgeo.2017.01.008.
    Beschreibung: Sedimentary records in the southwestern South China Sea reflect the evolving erosion and drainage systems that have operated in Southeast Asia during the Neogene. Analyses of the chemistry and clay mineral composition of sediments from International Ocean Discovery Program (IODP) Site U1433 allow us to examine these processes over the last 17 Ma. Sediment older than 8 Ma was deposited relatively slowly. Sr and Nd isotopes indicate a variable provenance with sequences of less and more altered material accompanied by strong changes in the proportion of smectite. Sediment flux was probably from Indochina, as well as from a more primitive volcanic source, most likely the Palawan ophiolite and/or Luzon. Sediments younger than 8 Ma show a more stable Sr and Nd isotope character, indicating sources close to those seen in the modern Mekong River, although with some influx from smaller rivers draining the Indochina margin especially from 4–8 Ma. Our data are consistent with seismic estimates for an onset to the Mekong in its present location after 8 Ma, following an avulsion from the Gulf of Thailand.
    Beschreibung: Funding for this research was provided by U.S. Science Support Program and the Charles T. McCord chair in petroleum geology at Louisiana State University.
    Schlagwort(e): Geochemistry ; Clay minerals ; Isotopes ; Provenance
    Repository-Name: Woods Hole Open Access Server
    Materialart: Preprint
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 2
    Publikationsdatum: 2022-10-19
    Beschreibung: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Zhou, P., Ireland, T., Murray, R. W., & Clift, P. D. Marine sedimentary records of chemical weathering evolution in the western Himalaya since 17 Ma. Geosphere, 17(3), (2021): 824–853, https://doi.org/10.1130/GES02211.1.
    Beschreibung: The Indus Fan derives sediment from the western Himalaya and Karakoram. Sediment from International Ocean Discovery Program drill sites in the eastern part of the fan coupled with data from an industrial well near the river mouth allow the weathering history of the region since ca. 16 Ma to be reconstructed. Clay minerals, bulk sediment geochemistry, and magnetic susceptibility were used to constrain degrees of chemical alteration. Diffuse reflectance spectroscopy was used to measure the abundance of moisture-sensitive minerals hematite and goethite. Indus Fan sediment is more weathered than Bengal Fan material, probably reflecting slow transport, despite the drier climate, which slows chemical weathering rates. Some chemical weathering proxies, such as K/Si or kaolinite/(illite + chlorite), show no temporal evolution, but illite crystallinity and the chemical index of alteration do have statistically measurable decreases over long time periods. Using these proxies, we suggest that sediment alteration was moderate and then increased from 13 to 11 Ma, remained high until 9 Ma, and then reduced from that time until 6 Ma in the context of reduced physical erosion during a time of increasing aridity as tracked by hematite/goethite values. The poorly defined reducing trend in weathering intensity is not clearly linked to global cooling and at least partly reflects regional climate change. Since 6 Ma, weathering has been weak but variable since a final reduction in alteration state after 3.5 Ma that correlates with the onset of Northern Hemispheric glaciation. Reduced or stable chemical weathering at a time of falling sedimentation rates is not consistent with models for Cenozoic global climate change that invoke greater Himalayan weathering fluxes drawing down atmospheric CO2 but are in accord with the idea of greater surface reactivity to weathering.
    Beschreibung: This study was made possible by samples provided by the IODP. The work was partially funded by a grant from The U.S. Science Support Program (USSSP), as well as additional funding from the Charles T. McCord Jr. Endowed Chair in petroleum geology at LSU.
    Schlagwort(e): Alteration ; Arabian Sea ; Arid environment ; Asia ; Bengal Fan ; Chemical composition ; Chemical weathering ; Chlorite ; Chlorite group ; Clay minerals ; Climate change ; Cooling ; Crystallinity ; Emission spectra ; Erosion ; Expedition 355 ; Glaciation ; Goethite ; Grain size ; Hematite ; Himalayas ; ICP mass spectra ; Illite ; Indian Ocean ; Indus Fan ; International Ocean Discovery Program ; IODP Site U1456 ; IODP Site U1457 ; Kaolinite ; Karakoram ; Magnetic properties ; Magnetic susceptibility ; Marine environment ; Mass spectra ; Mineral assemblages ; Moisture ; Oxides ; Paleoclimatology ; Paleoenvironment ; Paleomagnetism ; Provenance ; Reactivity ; Reconstruction ; Sediment transport ; Sedimentary rocks ; Sedimentation ; Sedimentation rates ; Sheet silicates ; Silicates ; Spectra ; Terrestrial environment ; Transport ; Weathering
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 3
    facet.materialart.
    Unbekannt
    PANGAEA
    In:  Supplement to: Kryc, Kelly A; Murray, Richard W; Murray, David W (2003): Al-to-oxide and Ti-to-organic linkages in biogenic sediment: relationships to paleo-export production and bulk Al/Ti. Earth and Planetary Science Letters, 211(1-2), 125-141, https://doi.org/10.1016/S0012-821X(03)00136-5
    Publikationsdatum: 2024-02-01
    Beschreibung: To increase our understanding of the mechanisms that control the distribution of Al and Ti within marine sediment, we performed sequential extractions targeting the chemical signatures of the loosely bound, exchangeable, carbonate, oxide, organic, opal, and residual fraction of sediment from a carbonate-dominated regime (equatorial Pacific) and from a mixed opal-terrigenous regime (West Antarctic Peninsula). We observe a systematic partitioning of Al and Ti between sediment phases that is related to bulk Al/Ti. We show that, where we can quantify an Al(excess) component, the dissolved Al is preferentially affiliated with the oxide fraction, resulting in Al/Ti molar ratios of 500-3000. This is interpreted as the result of surface complexation in the water column of dissolved Al onto oxyhydroxides. We also observe a previously undetected Ti(excess) with as much as 80% of the total Ti in the organic fraction, which is most likely a function of metal-organic colloidal removal from the water column. In samples where the excess metals are obscured by the detrital load, the Al and Ti are almost exclusively found in the residual phase. This argues for the paired removal of Al (preferentially by the oxide component) and Ti (preferentially by the organic component) from the water column by settling particulate matter. This research builds upon earlier work that shows changes in the bulk ratio of Al to Ti in carbonate sediment from the central-equatorial Pacific that coincide with changes in the sedimentary bulk accumulation rate (BAR). The ratios that are observed are as much as three times higher than typical shale values, and were interpreted as the result of scavenging of dissolved Al onto particles settling in the water column. Because this non-terrigenous Al(excess) accounts for up to 50% of the total sedimentary Al inventory and correlates best with BAR, the bulk Al/Ti may be a sensitive tracer of particle flux and, therefore, export production. Because we show that the excess metals are the result of scavenging processes, the bulk Al/Ti may be considered a sensitive proxy for this region.
    Schlagwort(e): 11031300 Multicorer1; 11080952 Multicorer4; 11091335 Multicorer5; 11101338 Pistoncore5; 11120107 Multicorer8; 11161400 Multicorer11; 11172115 Multicorer12; 11181007 Multicorer13; 11191756 Piston core 8, TT013-PC72; 11230530 Multicorer18; 11240508 Multicorer19; 11270742 Multicorer22; 11290827 Multicorer25; 11291231 Pistoncore13; 12062238 Multicorer37; 178-1098B; Drake Passage; DRILL; Drilling/drill rig; Equatorial Pacific; GC; Gravity corer; JGOFS; Joides Resolution; Joint Global Ocean Flux Study; Leg178; MUC; MultiCorer; Ocean Drilling Program; ODP; PC; Piston corer; Thomas G. Thompson; TT013; TT013_104; TT013_113; TT013_114; TT013_148; TT013_23; TT013_27; TT013_32; TT013_4; TT013_41; TT013_58; TT013_63; TT013_66; TT013_72; TT013_88; TT013_93; W8803B; W8803B-51GC; Wecoma
    Materialart: Dataset
    Format: application/zip, 17 datasets
    Standort Signatur Einschränkungen Verfügbarkeit
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