Beschreibung: The Late Cretaceous-Early Paleogene is the most recent period of Earth history that experienced sustained global greenhouse warmth and was characterised by a dynamic carbon cycle. Yet, knowledge of ambient climate conditions and the evolution of atmospheric pCO2 at this time, along with their relation to forcing mechanisms, are still poorly constrained. Here we present an unprecedented 14.75 million year long high-resolution orbitally-tuned record of paired climate change and carbon-cycling (based on the oxygen and carbon isotope composition of benthic foraminiferal tests) compiled to date for the enigmatic Late Cretaceous to Early Eocene, and compare these records to the most up-to-date compilation of atmospheric pCO2 records for this time. We identify eccentricity as the dominant pacemaker of the observed climate and carbon cycle changes, through the modulation of precession. The carbon cycle (e.g., d13C) lagged changes in climate by ~22,800 years within the long eccentricity (405,000 year) band and ~3,000-4,500 years within the short eccentricity (100,000 year) band, suggesting that light carbon was released as a positive feedback to warming induced by small changes in orbital forcing. The majority of the hyperthermals of this time period occur during maxima in the long eccentricity cycle, with the exception of the Paleocene-Eocene Thermal Maximum and Late Maastrichtian warming event, which are likely to have been triggered by Large Igneous Province volcanism.

Beschreibung: The Late Paleocene and Early Eocene were characterised by warm greenhouse climates, punctuated by a series of rapid warming and ocean acidification events known as "hyperthermals", thought to have been paced or triggered by orbital cycles. While these hyperthermals, such as the Paleocene Eocene Thermal Maximum (PETM), have been studied in great detail, the background low-amplitude cycles seen in carbon and oxygen-isotope records throughout the Paleocene-Eocene have hitherto not been resolved. Here we present a 7.7 million year (myr) long, high-resolution, orbitally-tuned, benthic foraminiferal stable-isotope record spanning the late Paleocene and early Eocene interval (~52.5 - 60.5 Ma) from Ocean Drilling Program (ODP) Site 1262, South Atlantic. This high resolution (~2-4 kyr) record allows the changing character and phasing of orbitally-modulated cycles to be studied in unprecedented detail as it reflects the long-term trend in carbon cycle and climate over this interval. The main pacemaker in the benthic oxygen-isotope (d18O) and carbon-isotope (d13C) records from ODP Site 1262, are the long (405 kyr) and short (100 kyr) eccentricity cycles, and precession (21 kyr). Obliquity (41 kyr) is almost absent throughout the section except for a few brief intervals where it has a relatively weak influence. During the course of the Early Paleogene record, and particularly in the latest Paleocene, eccentricity-paced negative carbon-isotope excursions (d13C, CIEs) and coeval negative oxygen-isotope (d18O) excursions correspond to low carbonate (CaCO3) and coarse fraction (%CF) values due to increased carbonate dissolution, suggesting shoaling of the lysocline and accompanied changes in the global exogenic carbon cycle. These negative CIEs and d18O events coincide with maxima in eccentricity, with changes in d18O leading changes in d13C by ~6 (±5) kyr in the 405-kyr band and by ~3 (±1) kyr in the higher frequency 100-kyr band on average. However, these phase lags are not constant, with the lag in the 405-kyr band extending from ~4 (±5) kyr to ~21 (±2) kyr from the late Paleocene to the early Eocene, suggesting a progressively weaker coupling of climate and the carbon-cycle with time. The higher amplitude 405-kyr cycles in the latest Paleocene are associated with changes in bottom water temperature of 2-4ºC, while the most prominent 100 kyr-paced cycles can be accompanied by changes of up to 1.5ºC. Comparison of the 1262 record with a lower resolution, but orbitally-tuned benthic record for Site 1209 in the Pacific allows for verification of key features of the benthic isotope records which are global in scale including a key warming step at 57.7 Ma.

Beschreibung: Recent studies have shown that the Early Eocene Climatic Optimum (EECO) was preceded by a series of short-lived global warming events, known as hyperthermals. Here we present high-resolution benthic stable carbon and oxygen isotope records from ODP Sites 1262 and 1263 (Walvis Ridge, SE Atlantic) between ~54 and ~52 million years ago, tightly constraining the character, timing, and magnitude of six prominent hyperthermal events. These events, which include Eocene Thermal Maximum (ETM) 2 and 3, are studied in relation to orbital forcing and long-term trends. Our findings reveal an almost linear relationship between d13C and d18O for all these hyperthermals, indicating that the eccentricity-paced co-variance between deep-sea temperature changes and extreme perturbations in the exogenic carbon pool persisted during these events towards the onset of the EECO, in accord with previous observations for the Paleocene Eocene Thermal Maximum (PETM) and ETM2. The covariance of d13C and d18O during H2 and I2, which are the second pulses of the "paired" hyperthermal events ETM2-H2 and I1-I2, deviates with respect to the other events. We hypothesize that this could relate to a relatively higher contribution of an isotopically heavier source of carbon, such as peat or permafrost, and/or to climate feedbacks/local changes in circulation. Finally, the d18O records of the two sites show a systematic offset with on average 0.2 per mil heavier values for the shallower Site 1263, which we link to a slightly heavier isotopic composition of the intermediate water mass reaching the northeastern flank of the Walvis Ridge compared to that of the deeper northwestern water mass at Site 1262.

Beschreibung: We examine a single interglacial during the late Pliocene (KM5c, ca. 3.205 +/- 0.01 Ma) when atmospheric CO2 concentrations were higher than pre-industrial, but similar to today and to the lowest emission scenarios for this century. As orbital forcing and continental configurations were also similar to today, we are able to focus on equilibrium climate system response to modern and near-future CO2. We have synthesised largely published datasets, scrutinised their age models, and generated mean absolute SSTs and their anomaly relative to the pre-industrial. Here we present those values for both alkenone and foraminifera-Mg/Ca proxies.