In:
Zeitschrift für Naturforschung B, Walter de Gruyter GmbH, Vol. 45, No. 3 ( 1990-3-1), p. 377-381
Abstract:
The reaction of racemic jasmonic acid with either (R)-mandelic acid or its (S)-enantiomer resulted in a mixture of diastereomeric esters. Both the O-[(±)-jasmonoyl]-(R)-mandelic acids (2a, 2b) and the O-[(±)-jasmonoyl] -(S)-mandelic acids (3a, 3b) could be separated by silica gel chromatography. By hydrolysis of the pure diastereomers, resolved (+)-JA (la) and (–)-JA (lb) were obtained. The structures and the purity of all compounds were confirmed by 1 H NMR, MS, GC/MS, IR and ORD.
Type of Medium:
Online Resource
ISSN:
1865-7117
,
0932-0776
DOI:
10.1515/znb-1990-0312
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
1990
detail.hit.zdb_id:
2078109-X
detail.hit.zdb_id:
124635-5
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