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Synthesis of the First Lanthanoid(II) Pyrazolate Complex by Redox Transmetallation from Thallium and Mercury Reagents (1998)

Deacon, Glen B. ; Delbridge, Ewan E. ; Skelton, Brian W. ; [et al.]

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 1998 (1998), S. 543-545

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ISSN: 1434-1948

Keywords: Lanthanoid(II) complexes ; Ytterbium ; Thallium ; η2-Pyrazolate complexes ; Diphenylmercury ; Redox transmetallation ; X-ray crystal structure ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Ytterbium metal reacts with thallium(I) 3,5-diphenylpyrazolate, or with diphenylmercury and 3,5-diphenylpyrazole (Ph2pzH) in tetrahydrofuran or 1,2-dimethoxyethane (DME) giving, after appropriate isolation, the first lanthanoid(II) pyrazolate complex, [Yb(Ph2pz)2(DME)2]. The molecular structure reveals eight coordinate ytterbium(II) with two cisoid η2-3,5-diphenylpyrazolate and two chelating 1,2-dimethoxyethane ligands.

Type of Medium: Electronic Resource

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