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  • 1
    In: Plant Biotechnology Journal, Wiley, Vol. 18, No. 8 ( 2020-08), p. 1796-1809
    Abstract: Kenaf is an annual crop that is widely cultivated as a source of bast (phloem) fibres, the phytoremediation of heavy metal‐contaminated farmlands and textile‐relevant compounds. Leaf shape played a unique role in kenaf improvement, due to the inheritance as a single locus and the association with fibre development in typical lobed‐leaf varieties. Here we report a high‐quality genome assembly and annotation for var. ‘Fuhong 952’ with 1078 Mbp genome and 66 004 protein‐coding genes integrating single‐molecule real‐time sequencing, a high‐density genetic map and high‐throughput chromosome conformation capture techniques. Gene mapping assists the identification of a homeobox transcription factor LATE MERISTEM IDENTITY 1 ( HcLMI1 ) gene controlling lobed‐leaf. Virus‐induced gene silencing (VIGS) of HcLMI1 in a lobed‐leaf variety was critical to induce round (entire)‐like leaf formation. Candidate genes involved in cell wall formation were found in quantitative trait loci (QTL) for fibre yield and quality‐related traits. Comparative genomic and transcriptome analyses revealed key genes involved in bast fibre formation, among which there are twice as many cellulose synthase A (CesA) genes due to a recent whole‐genome duplication after divergence from Gossypium . Population genomic analysis showed two recent population bottlenecks in kenaf, suggesting domestication and improvement process have led to an increase in fibre biogenesis and yield. This chromosome‐scale genome provides an important framework and toolkit for sequence‐directed genetic improvement of fibre crops.
    Type of Medium: Online Resource
    ISSN: 1467-7644 , 1467-7652
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2020
    detail.hit.zdb_id: 2136367-5
    SSG: 12
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  • 2
    In: Plant Biotechnology Journal, Wiley, Vol. 19, No. 11 ( 2021-11), p. 2235-2248
    Abstract: Cultivated jute, which comprises the two species Corchorus capsularis and C. olitorius , is the second most important natural fibre source after cotton. Here we describe chromosome‐level assemblies of the genomes of both cultivated species. The C. capsularis and C. olitorius assemblies are each comprised of seven pseudo‐chromosomes, with the C. capsularis assembly consisting of 336 Mb with 25,874 genes and the C. olitorius assembly containing 361 Mb with 28 479 genes. Although the two Corchorus genomes exhibit collinearity, the genome of C. olitorius contains 25 Mb of additional sequences than that of C. capsularis with 13 putative inversions, which might give a hint to the difference of phenotypic variants between the two cultivated jute species. Analysis of gene expression in isolated fibre tissues reveals candidate genes involved in fibre development. Our analysis of the population structures of 242 cultivars from C. capsularis and 57 cultivars from C. olitorius by whole‐genome resequencing resulted in post‐domestication bottlenecks occurred ~2000 years ago in these species. We identified hundreds of putative significant marker‐trait associations (MTAs) controlling fibre fineness, cellulose content and lignin content of fibre by integrating data from genome‐wide association studies (GWAS) with data from analyses of selective sweeps due to natural and artificial selection in these two jute species. Among them, we further validated that CcCOBRA1 and CcC4H1 regulate fibre quality in transgenic plants via improving the biosynthesis of the secondary cell wall. Our results yielded important new resources for functional genomics research and genetic improvement in jute and allied fibre crops.
    Type of Medium: Online Resource
    ISSN: 1467-7644 , 1467-7652
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2021
    detail.hit.zdb_id: 2136367-5
    SSG: 12
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  • 3
    In: Advanced Science, Wiley, Vol. 7, No. 18 ( 2020-09)
    Abstract: Dynamic control of liquid wetting behavior on smart surfaces has attracted considerable concern owing to their important applications in directional motion, confined wetting and selective separation. Despite much progress in this regard, there still remains challenges in dynamic liquid droplet manipulation with fast response, no loss and anti‐contamination. Herein, a strategy to achieve dynamic droplet manipulation and transportation on the electric field adaptive superhydrophobic elastomer surface is demonstrated. The superhydrophobic elastomer surface is fabricated by combining the micro/nanostructured clusters of hydrophobic TiO 2 nanoparticles with the elastomer film, on which the micro/nanostructure can be dynamically and reversibly tuned by electric field due to the electric field adaptive deformation of elastomer film. Accordingly, fast and reversible transition of wetting state between Cassie state and Wenzel state and tunable adhesion on the surface via electric field induced morphology transformation can be obtained. Moreover, the motion states of the surface droplets can be controlled dynamically and precisely, such as jumping and pinning, catching and releasing, and controllable liquid transfer without loss and contamination. Thus this work would open the avenue for dynamic liquid manipulation and transportation, and gear up the broad application prospects in liquid transfer, selective separation, anti‐fog, anti‐ice, microfluidics devices, etc.
    Type of Medium: Online Resource
    ISSN: 2198-3844 , 2198-3844
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2020
    detail.hit.zdb_id: 2808093-2
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  • 4
    Online Resource
    Online Resource
    Wiley ; 2006
    In:  ChemInform Vol. 37, No. 24 ( 2006-06-13)
    In: ChemInform, Wiley, Vol. 37, No. 24 ( 2006-06-13)
    Type of Medium: Online Resource
    ISSN: 0931-7597 , 1522-2667
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2006
    detail.hit.zdb_id: 2110203-X
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  • 5
    Online Resource
    Online Resource
    Wiley ; 2021
    In:  Angewandte Chemie Vol. 133, No. 27 ( 2021-06-25), p. 15176-15180
    In: Angewandte Chemie, Wiley, Vol. 133, No. 27 ( 2021-06-25), p. 15176-15180
    Abstract: Triphenylphosphine (TPP)‐based luminescent compounds are rarely investigated because of the low photoluminescence quantum yield (PLQY). Here, we demonstrate that introducing steric hindrance groups to the TPP moiety and separating the orbitals involved in the transition can drastically suppress the non‐radiative decay induced by structural distortion of TPP in the excited state. High PLQY up to 0.89 as well as thermally activated delayed fluorescence are observed from the intramolecular charge‐transfer (ICT) molecules with substituted TPP donors (sTPPs) in doped films. The red organic light‐emitting diodes employing these emitters achieve comparable external quantum efficiencies to the control device containing a classical phosphorescent dye, revealing the great potential of the ICT emitters based on electrochemically stable sTPPs.
    Type of Medium: Online Resource
    ISSN: 0044-8249 , 1521-3757
    URL: Issue
    RVK:
    RVK:
    Language: English
    Publisher: Wiley
    Publication Date: 2021
    detail.hit.zdb_id: 505868-5
    detail.hit.zdb_id: 506609-8
    detail.hit.zdb_id: 514305-6
    detail.hit.zdb_id: 505872-7
    detail.hit.zdb_id: 1479266-7
    detail.hit.zdb_id: 505867-3
    detail.hit.zdb_id: 506259-7
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  • 6
    Online Resource
    Online Resource
    Wiley ; 2021
    In:  Angewandte Chemie International Edition Vol. 60, No. 27 ( 2021-06-25), p. 15049-15053
    In: Angewandte Chemie International Edition, Wiley, Vol. 60, No. 27 ( 2021-06-25), p. 15049-15053
    Abstract: Triphenylphosphine (TPP)‐based luminescent compounds are rarely investigated because of the low photoluminescence quantum yield (PLQY). Here, we demonstrate that introducing steric hindrance groups to the TPP moiety and separating the orbitals involved in the transition can drastically suppress the non‐radiative decay induced by structural distortion of TPP in the excited state. High PLQY up to 0.89 as well as thermally activated delayed fluorescence are observed from the intramolecular charge‐transfer (ICT) molecules with substituted TPP donors (sTPPs) in doped films. The red organic light‐emitting diodes employing these emitters achieve comparable external quantum efficiencies to the control device containing a classical phosphorescent dye, revealing the great potential of the ICT emitters based on electrochemically stable sTPPs.
    Type of Medium: Online Resource
    ISSN: 1433-7851 , 1521-3773
    URL: Issue
    RVK:
    Language: English
    Publisher: Wiley
    Publication Date: 2021
    detail.hit.zdb_id: 2011836-3
    detail.hit.zdb_id: 123227-7
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  • 7
    In: Acta Geologica Sinica - English Edition, Wiley, Vol. 94, No. 4 ( 2020-08), p. 1276-1300
    Abstract: The discoveries of oil and gas reservoirs in the volcanic rocks of the Songliao Basin (SB) have attracted the attention of many researchers. However, the lack of studies on the genesis of the volcanic rocks has led to different opinions being presented for the genesis of the SB. In order to solve this problem, this study selected the volcanic rocks of the Yingcheng Formation in the Southern Songliao Basin (SSB) as the research object, and determined the genesis and tectonic setting of the volcanic rocks by using LA‐ICP‐MS zircon U‐Pb dating and a geochemical analysis method (major elements, trace elements, and Hf isotopes). The volcanic rocks of the Yingcheng Formation are mainly composed of rhyolites with minor dacites and pyroclastic rocks. Our new zircon U‐Pb dating results show that these volcanic rocks were erupted in the Early Cretaceous (113–118 Ma). The primary zircons from the rhyolites have ∊Hf (t) values of +4.70 to +12.46 and two‐stage model age (TDM 2 ) of 876–374 Ma. The geochemical data presented in this study allow these rhyolites to be divided into I‐type rhyolites and A‐type rhyolites, both of which were formed by the partial melting of the crust. They have SiO 2 contents of 71.62 wt.%–75.76 wt.% and Al 2 O 3 contentsof 10.88 wt.% to 12.92 wt.%. The rhyolites have distinctively higher REE contents than those of ordinary granites, with obvious negative Eu anomalies. The light to heavy REE fractionation is not obvious, and the La N /Yb N (average value = 9.78) is less than 10. The A‐type rhyolites depleted in Ba, Sr, P, and Ti, with relatively low Nb/Ta, indicating that the rocks belong A 2 subtype granites formed in an extensional environment. The adakitic dacites are characterized by high Sr contents (624 to 1,082 ppm), low Y contents (10.6 to 12.6 ppm), high Sr/Y and Sr/Yb ratios, and low Mg# values (14.77 to 36.46), indicating that they belong to “C” type adakites. The adakitic dacite with high Sr and low Yb were likely generated by partial melting of the lower crust under high pressure conditions at least 40 km depth. The I‐type rhyolites with low Sr and high Yb, and the A‐type rhyolites with very low Sr and high Yb, were formed in the middle and upper crust under low pressure conditions, respectively. In addition, the formation depths of the former were approximately 30 km, whereas those of the latter were less than 30 km. The geochemical characteristics reveal that the volcanic rocks of Yingcheng Formation were formed in an extensional environment which was related to the retreat of subducted Paleo‐Pacific Plate. At the late Early Cretaceous Period, the upwelling of the asthenosphere mantle and the lithosphere delamination caused by the retreat of the subducted Paleo‐Pacific Plate, had resulted in lithosheric extension in the eastern part of China. Subsequently, a large area of volcanic rocks had formed. The SB has also been confirmed to be a product of the tectonic stress field in that region.
    Type of Medium: Online Resource
    ISSN: 1000-9515 , 1755-6724
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2020
    detail.hit.zdb_id: 2420386-5
    SSG: 6,25
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  • 8
    In: Acta Geologica Sinica - English Edition, Wiley, Vol. 86, No. 3 ( 2012-06), p. 568-578
    Abstract: The Kalatongke Cu–Ni sulfide deposits located in the East Junggar terrane, northern Xinjiang, western China are the largest magmatic sulfide deposits in the Central Asian Orogenic Belt (CAOB). The chemical and carbon isotopic compositions of the volatiles trapped in olivine, pyroxene and sulfide mineral separates were analyzed by vacuum stepwise‐heating mass spectrometry. The results show that the released volatiles are concentrated at three temperature intervals of 200–400°C, 400–900°C and 900–1200°C. The released volatiles from silicate mineral separates at 400–900°C and 900–1200°C have similar chemical and carbon isotopic compositions, which are mainly composed of H 2 O (av. ∼92 mol%) with minor H 2 , CO 2 , H 2 S and SO 2 , and they are likely associated with the ore‐forming magmatic volatiles. Light δ 13 C CO2 values (from –20.86‰ to –12.85‰) of pyroxene indicate crustal contamination occurred prior to or synchronous with pyroxene crystallization of mantle‐derived ore‐forming magma. The elevated contents of H 2 and H 2 O in the olivine and pyroxene suggest a deep mantle‐originated ore‐forming volatile mixed with aqueous volatiles from recycled subducted slab. High contents of CO 2 in the ore‐forming magma volatiles led to an increase in oxygen fugacity, and thereby reduced the solubility of sulfur in the magma, then triggered sulfur saturation followed by sulfide melt segregation; CO 2 contents correlated with Cu contents in the whole rocks suggest that a supercritical state of CO 2 in the ore‐forming magma system under high temperature and pressure conditions might play a key role in the assemblage of huge Cu and Ni elements. The volatiles released from constituent minerals of intrusion 1* have more CO 2 and SO 2 oxidized gases, higher CO 2 /CH 4 and SO 2 /H 2 S ratios and lighter δ 13 C CO2 than those of intrusions 2 # and 3 # . This combination suggests that the higher oxidation state of the volatiles in intrusion 1 # than intrusions 2 # and 3 # , which could be one of key ore‐forming factors for large amounts of ores and high contents of Cu and Ni in intrusion 1 # . The volatiles released at 200–400°C are dominated by H 2 O with minor CO 2 , N 2 +CO and SO 2 , with δ 13 C CO2 , values (–25.66‰ to –22.98‰) within the crustal ranges, and are considered to be related to secondary tectonic– hydrothermal activities.
    Type of Medium: Online Resource
    ISSN: 1000-9515 , 1755-6724
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2012
    detail.hit.zdb_id: 2420386-5
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  • 9
    In: ChemElectroChem, Wiley, Vol. 5, No. 18 ( 2018-09-12), p. 2584-2592
    Abstract: To enhance the rate capability and cycling stability of Si‐based materials in lithium‐ion batteries, three‐dimensional graphene nanoribbons (GNRs) enlacing Si@TiO 2 nanoparticles are synthesized by magnesiothermic reduction, sol‐gel and electrostatic adsorption processes. The rigid clamping layer of TiO 2 on the surface of Si prevents the whole electrode from undergoing volumetric variation. GNRs act as bridges to interconnect the adjacent Si@TiO 2 nanoparticles to form a successively conductive network with decreased inner resistance. Moreover, the effect of two other kinds of carbon resources (polydopamine and resorcinol formaldehyde) on the electrochemical performance of Si@TiO 2 are also discussed. The Si@TiO 2 @GNRs composite shows an enhanced discharge capacity of 1295 mAh g −1 at a current density of 0.5 A g −1 in the 300 th cycle and achieve an outstanding rate capacity of 689.3 mAh g −1 even at 10.0 A g −1 . The design of the double protecting structure provides an alternative strategy to enhance the electrochemical performance of M‐based materials (M=Si, Sn, and Ge).
    Type of Medium: Online Resource
    ISSN: 2196-0216 , 2196-0216
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2018
    detail.hit.zdb_id: 2724978-5
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  • 10
    In: ChemElectroChem, Wiley, Vol. 5, No. 2 ( 2018-01-12), p. 375-382
    Abstract: Lithium−sulfur (Li−S) batteries, which possess a high theoretical capacity of 1675 mAh g −1 and energy density of 2600 Wh kg −1 , are regarded as appealing candidates for next‐generation power storage systems. However, poor electrochemical performance, mainly attributed to polysulfide diffusion, obstructs their practical application. Herein, a simple graphite‐modified separator with a preformed solid electrolyte interphase (SEI) is first fabricated to suppress the polysulfide shuttle. Particularly, the formed SEI film on the graphite surface inhibits the graphite exfoliation caused by co‐intercalation of solvents. Thus, the stable graphite layer with a preformed SEI can function as an effective physical barrier to suppress the polysulfide shuttle and enhance the utilization of the trapped active material. As a result, the cell using the graphite‐modified separator exhibits a high capacity of 698 mAh g −1 (0.2 C) after 100 cycles with a low capacity decay of 0.13 % per cycle. Even under relatively high sulfur loading (2.5 mg cm −2 ), it shows a reversible capacity of 519 mAh g −1 after 200 cycles.
    Type of Medium: Online Resource
    ISSN: 2196-0216 , 2196-0216
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2018
    detail.hit.zdb_id: 2724978-5
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