In:
Zeitschrift für anorganische und allgemeine Chemie, Wiley, Vol. 636, No. 5 ( 2010-04), p. 770-774
Abstract:
The formation of coordination polymers from copper(I) bromide and P 4 S 3 , a potentially tetradentate P‐donor bridging ligand, was studied. Whereas (P 4 S 3 ) 3 (CuBr) 7 ( 1 ) formed in excellent yield, (P 4 S 3 )(CuBr) 3 ( 2 ) and (P 4 S 3 )(CuBr) ( 3 ) crystallized as mixtures. The new compounds were characterized by X‐ray crystallography and solid‐state 31 P MAS NMR spectroscopy. The structure of 1 consists of a 3D network of cylindrical (CuBr) n columns, castellated (CuBr) n chains and diatomic CuBr units. These building blocks are linked by tetradentate P 4 S 3 molecules. The structure of 2 comprises undulated (CuBr) n layers, which are intra‐ and interlayer linked by tridentate P 4 S 3 molecules. Compound 3 is a one‐dimensional polymer composed of four‐membered Cu 2 Br 2 rings, which are bridged by the P 3 bases of two P 4 S 3 molecules.
Type of Medium:
Online Resource
ISSN:
0044-2313
,
1521-3749
DOI:
10.1002/zaac.200900491
Language:
English
Publisher:
Wiley
Publication Date:
2010
detail.hit.zdb_id:
201094-X
detail.hit.zdb_id:
1481139-X
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