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  • 1
    In: Journal of Environmental Quality, Wiley, Vol. 47, No. 4 ( 2018-07), p. 786-794
    Abstract: Stored liquid dairy manure is a hotspot for methane (CH 4 ) emission, thus effective mitigation strategies are required. We assessed sodium persulfate (Na 2 S 2 O 8 ), potassium permanganate (KMnO 4 ), and sodium hypochlorite (NaOCl) for impacts on the abundance of microbial communities and CH 4 production in liquid dairy manure. Liquid dairy manure treated with different rates (1, 3, 6, and 9 g or mL L −1 slurry) of these chemicals or their combinations were incubated under anoxic conditions at 22.5 ± 1.3°C for 120 d. Untreated and sodium 2‐bromoethanesulfonate (BES)‐treated manures were included as negative and positive controls, respectively, whereas sulfuric acid (H 2 SO 4 )‐treated manure was used as a reference. Quantitative real‐time polymerase chain reaction was used to quantify the abundances of bacteria and methanogens on Days 0, 60, and 120. Headspace CH 4 /CO 2 ratios were used as a proxy to determine CH 4 production. Unlike bacterial abundance, methanogen abundance and CH 4 /CO 2 ratios varied with treatments. Addition of 1 to 9 g L −1 slurry of Na 2 S 2 O 8 and KMnO 4 reduced methanogen abundance (up to ∼28%) and peak CH 4 /CO 2 ratios (up to 92‐fold). Except at the lowest rate, chemical combinations also reduced the abundance of methanogens (up to ∼17%) and CH 4 /CO 2 ratios (up to ninefold), although no impacts were observed when 3% NaOCl was used alone. With slurry acidification, the ratios reduced up to twofold, whereas methanogen abundance was unaffected. Results suggest that Na 2 S 2 O 8 and KMnO 4 may offer alternative options to reduce CH 4 emission from stored liquid dairy manure, but this warrants further assessment at larger scales for environmental impacts and characteristics of the treated manure. Core Ideas Chemical oxidants were assessed for potential effects on methanogens and methane production. The abundance of methanogens and CH 4 production were affected by Na 2 S 2 O 8 and KMnO 4 . Na 2 S 2 O 8 and KMnO 4 had similar effects on CH 4 production compared with acidification. Na 2 S 2 O 8 and KMnO 4 may provide options to mitigate CH 4 emissions from stored liquid dairy manure.
    Type of Medium: Online Resource
    ISSN: 0047-2425 , 1537-2537
    Language: English
    Publisher: Wiley
    Publication Date: 2018
    detail.hit.zdb_id: 120525-0
    detail.hit.zdb_id: 2050469-X
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  • 2
    In: Journal of Environmental Quality, Wiley, Vol. 50, No. 4 ( 2021-07), p. 817-835
    Abstract: Current CH 4 emission models for stored manure have limited accuracy. A microbial model component is needed to capture CH 4 emission dynamics. Emission responds differently to short‐ and long‐term perturbations. Temperature dynamics, organic matter flow, and biodegradability must be known.
    Type of Medium: Online Resource
    ISSN: 0047-2425 , 1537-2537
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2021
    detail.hit.zdb_id: 120525-0
    detail.hit.zdb_id: 2050469-X
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  • 3
    In: Journal of Environmental Quality, Wiley, Vol. 45, No. 6 ( 2016-11), p. 1829-1837
    Abstract: Anaerobic digestion of dairy manure has environmental benefits, but the impact of effluent (i.e., digestate [DG]) application on environmental nitrogen (N) losses from soils has not been well quantified. Our objective was to evaluate how field application of DG affected nitrous oxide (N 2 O) emissions and nitrate (NO 3 ) leaching compared with raw dairy manure (RM) in spring versus fall applications. We measured N losses year‐round for 2.5 yr in silage corn on tile‐drained clay soil in Alfred, Ontario, Canada. Treatments were: digestate applied in spring (DS) and fall (DF), raw dairy manure applied in spring (RS) and fall (RF), urea applied in spring, and a control. Overall, the source of N had no effect on annual N 2 O emissions (overall average DG and RM, 4.9 kg N 2 O–N ha −1 yr −1 ), but more NO 3 leached from DS than RS treatments (8.8 and 4.8 kg NO 3 –N ha −1 yr −1 on average, respectively). Estimated indirect N 2 O emissions from leached NO 3 –N were small ( 〈 0.2 kg N 2 O–N ha −1 yr −1 ). Timing of application did not affect annual N 2 O emissions but did shift emissions to the non‐growing season for fall applications (65% on average) and to the growing season for spring applications (60% on average). Overall environmental N losses (N 2 O–N + NO 3 –N) from DG were similar to RM when applied at the same time. For the conditions of our study, downstream emissions from anaerobic digestion (i.e., emissions induced by applied digestate) do not present an adverse trade‐off to the environmental benefits incurred during the biogas production phase. Core Ideas Biodigestion has environmental benefits, but N losses from soils are uncertain. Nitrous oxide emissions and NO 3 leaching were evaluated. Digested and raw manure had similar annual N losses. Application in spring had lower annual NO3 losses than fall application. Soil emissions were not a trade‐off to environmental benefits of biogas production.
    Type of Medium: Online Resource
    ISSN: 0047-2425 , 1537-2537
    Language: English
    Publisher: Wiley
    Publication Date: 2016
    detail.hit.zdb_id: 120525-0
    detail.hit.zdb_id: 2050469-X
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  • 4
    In: Journal of Environmental Quality, Wiley, Vol. 45, No. 6 ( 2016-11), p. 1822-1828
    Abstract: A significant need exists to improve our understanding of the extent of greenhouse gas emissions from the storage of livestock manure to both improve the reliability of inventory assessments and the impact of beneficial management practice adoption. Factors affecting the extent and variability of greenhouse gas emissions from stored dairy manure were investigated. Emissions from six slurries stored in clean concrete tanks under identical “warm‐season” conditions were monitored consecutively over 173 d (18°C average air temperature). Methane (CH 4 ) emissions varied considerably among the manures from 6.3 to 25.9 g m −2 d −1 and accounted for ∼96% of the total CO 2 equivalent greenhouse gas emissions. The duration of the lag period, when methane emissions were near baseline levels, varied from 30 to 90 d from the beginning of storage. As a result, CH 4 emissions were poorly correlated with air temperature prior to the time of peak emissions (i.e., the initial 48 to 108 d of storage) but improved afterward. The air temperature following the time of the peak CH 4 flux and the length of the active methanogenesis period (i.e., when the daily CH 4 emissions ≥ 7.6 g m −2 d −1 ) were highly correlated with CH 4 emissions ( R 2 = 0.98, p 〈 0.01). Methane conversion factors (MCFs) ranged from 0.08 to 0.52 for the different manures. The MCFs generated from existing CH 4 emission models were correlated ( R 2 = 0.68, p = 0.02) to MCFs calculated for the active methanogenesis period for manure containing wood bedding. A temperature component was added that improved the accuracy ( R 2 = 0.82, p 〈 0.01). This demonstrated that an improved understanding of lag period dynamics will enhance stored dairy manure greenhouse gas emission inventory calculations. Core Ideas CH 4 emissions and MCFs from six dairy slurries varied despite identical storage conditions. Postpeak CH 4 emissions were more consistent among slurries compared with prepeak periods. CH 4 emissions represented ∼96% of the overall GHG budget. N 2 O emissions were low but represented an 8× greater portion of the GHG budget for tie‐stall than free‐stall systems.
    Type of Medium: Online Resource
    ISSN: 0047-2425 , 1537-2537
    Language: English
    Publisher: Wiley
    Publication Date: 2016
    detail.hit.zdb_id: 120525-0
    detail.hit.zdb_id: 2050469-X
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  • 5
    In: Journal of Environmental Quality, Wiley, Vol. 48, No. 4 ( 2019-07), p. 1006-1015
    Abstract: There is an incentive for dairy farmers to maximize crop production while minimizing costs and environmental impacts. In cold climates, farmers have limited opportunity to balance field activities and manure storage requirements while limiting nutrient losses. A revised DeNitrification DeComposition (DNDC) model for simulating tile drainage was used to investigate fertilizer scenarios when applying dairy slurry or urea on silage corn ( Zea mays L.) to examine N losses over a multidecadal horizon at locations in eastern Canada and the US Midwest. Management scenarios included timing (spring, fall, split, and sidedress) and method of application (injected [10 cm], incorporated [5 cm] , and broadcast). Reactive N losses (NO 3 − from drainage and runoff, N 2 O, and NH 3 ) were greatest from broadcast, followed by incorporated and then injected applications. Among the fertilizer timing scenarios, fall manure application resulted in the greatest N loss, primarily due to increased N leaching in non‐growing‐season periods, with 58% more N loss per metric ton of silage than spring application. Split and sidedress mineral fertilizer had the lowest N losses, with average reductions of 9.5 and 4.9%, respectively, relative to a single application. Split application mitigated losses more so than sidedress by reducing the soil pH shift due to urea hydrolysis and NH 3 volatilization during the warmer June period. This assessment helps to distinguish which fertilizer practices are more effective in reducing N loss over a long‐term time horizon. Reactive N loss is ranked across 18 fertilizer management practices, which could assist farmers in weighing the tradeoffs between field trafficability, manure storage capacity, and expected N loss. Core Ideas The impacts of climate variability were often greater than the impacts of fertilizer management. Fall‐applied manure resulted in more N loss than spring‐applied, primarily from N leaching. Lowest N loss occurred from split and sidedress urea at all three locations. More NH 3 volatilization and N 2 O losses occurred from organic fertilizer, but N leaching was similar. Similar fertilizer management recommendations can be made across all three locations.
    Type of Medium: Online Resource
    ISSN: 0047-2425 , 1537-2537
    Language: English
    Publisher: Wiley
    Publication Date: 2019
    detail.hit.zdb_id: 120525-0
    detail.hit.zdb_id: 2050469-X
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  • 6
    In: Journal of Environmental Quality, Wiley, Vol. 52, No. 3 ( 2023-05), p. 596-609
    Abstract: Canada's changing livestock sectors require contrasting strategies for manureshed management. Manure nutrient hotspots are relatively uncommon in Canada. Concentrations of manure nutrients around major cities are a priority for manureshed solutions. Livestock concentrations near large cities are a health concern. Strategies are needed to address changing animal sectors and growing cities especially in southern Canada.
    Type of Medium: Online Resource
    ISSN: 0047-2425 , 1537-2537
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2023
    detail.hit.zdb_id: 120525-0
    detail.hit.zdb_id: 2050469-X
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  • 7
    Online Resource
    Online Resource
    Wiley ; 2020
    In:  Journal of Environmental Quality Vol. 49, No. 2 ( 2020-03), p. 509-515
    In: Journal of Environmental Quality, Wiley, Vol. 49, No. 2 ( 2020-03), p. 509-515
    Abstract: Organic waste materials are sources of anthropogenic methane (CH 4 ) emissions. Anaerobic digestion (AD) is a technology that produces biogas from organic waste materials, and CH 4 is the primary component of biogas. Unintended emission of CH 4 from biogas facilities could undercut the environmental benefits of this technology. The objective of this study was to determine if the implementation of an AD system affected ambient CH 4 concentrations ([CH 4 ]) on a commercial dairy farm over 5 yr, from before installation into full operation. Concentrations at 4.5‐m height on a tower receiving wind that originated from various directions, comprising components of the dairy farm such as the AD facility, crop fields, or main barn, were measured using a closed‐path tunable diode laser trace‐gas analyzer. In 2012 and 2013, the first 2 yr of AD operation, [CH 4 ] was not significantly different than pre‐AD levels in 2011 (2.04 ± 0.01 μl L −1 ). However, mean [CH 4 ] increased to 2.47 ± 0.03 and 2.48 ± 0.04 μl L −1 in 2014 and 2015, respectively, and the occurrence of high [CH 4 ] ( 〉 10 μl L −1 ) increased from  〈 0.05% in Year 1 (pre‐AD) to 12% in Years 4 and 5. These elevated concentrations were related to an increased use of food waste feedstocks over time and suggest that the biogas system was a source of fugitive CH 4 emissions. Food waste materials have a high biogas potential and are a valuable resource that require appropriate facility design and management to fully harness their benefits.
    Type of Medium: Online Resource
    ISSN: 0047-2425 , 1537-2537
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2020
    detail.hit.zdb_id: 120525-0
    detail.hit.zdb_id: 2050469-X
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  • 8
    In: Global Change Biology, Wiley, Vol. 22, No. 3 ( 2016-03), p. 1244-1255
    Abstract: Perennial crops can deliver a wide range of ecosystem services compared to annual crops. Some of these benefits are achieved by lengthening the growing season, which increases the period of crop water and nutrient uptake, pointing to a potential role for perennial systems to mitigate soil nitrous oxide (N 2 O) emissions. Employing a micrometeorological method, we tested this hypothesis in a 3‐year field experiment with a perennial grass‐legume mixture and an annual corn monoculture. Given that N 2 O emissions are strongly dependent on the method of fertilizer application, two manure application options commonly used by farmers for each crop were studied: injection vs. broadcast application for the perennial; fall vs. spring application for the annual. Across the 3 years, lower N 2 O emissions ( P  〈   0.001) were measured for the perennial compared to the annual crop, even though annual N 2 O emissions increased tenfold for the perennial after ploughing. The percentage of N 2 O lost per unit of fertilizer applied was 3.7, 3.1 and 1.3 times higher for the annual for each consecutive year. Differences in soil organic matter due to the contrasting root systems of these crops are probably a major factor behind the N 2 O reduction. We found that a specific manure management practice can lead to increases or reductions in annual N 2 O emissions depending on environmental variables. The number of freeze‐thaw cycles during winter and the amount of rainfall after fertilization in spring were key factors. Therefore, general manure management recommendations should be avoided because interannual weather variability has the potential to determine if a specific practice is beneficial or detrimental. The lower N 2 O emissions of perennial crops deserve further research attention and must be considered in future land‐use decisions. Increasing the proportion of perennial crops in agricultural landscapes may provide an overlooked opportunity to regulate N 2 O emissions.
    Type of Medium: Online Resource
    ISSN: 1354-1013 , 1365-2486
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2016
    detail.hit.zdb_id: 2020313-5
    SSG: 12
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  • 9
    Online Resource
    Online Resource
    Wiley ; 2023
    In:  Journal of Environmental Quality Vol. 52, No. 4 ( 2023-07), p. 939-947
    In: Journal of Environmental Quality, Wiley, Vol. 52, No. 4 ( 2023-07), p. 939-947
    Abstract: Data showed peak manure temperature could be higher or lower than peak air temperature. Differences between manure and air temperature in the warmest month were −2.2 to 2.6°C. Generally, manure temperature declined relative to air temperature as manure depth increased. The ratio of manure surface area to volume can be used to improve manure temperature estimates. Wind speed and climate influence the difference between manure and air temperature in the warmest month.
    Type of Medium: Online Resource
    ISSN: 0047-2425 , 1537-2537
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2023
    detail.hit.zdb_id: 120525-0
    detail.hit.zdb_id: 2050469-X
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  • 10
    Online Resource
    Online Resource
    Wiley ; 2016
    In:  Journal of Environmental Quality Vol. 45, No. 6 ( 2016-11), p. 2038-2043
    In: Journal of Environmental Quality, Wiley, Vol. 45, No. 6 ( 2016-11), p. 2038-2043
    Abstract: When liquid manure is removed from storages for land application, “sludge” generally remains at the bottom of the tank. This may serve as an inoculum when fresh manure is subsequently added, thereby increasing methane (CH 4 ) emissions. Previous pilot‐scale studies have shown that completely emptying storages can decrease CH 4 emissions; however, no farm‐scale studies have been conducted to quantify the effect of sludge removal. In this study, a commercial dairy farm removed as much manure and sludge from their concrete storage as possible in the fall (∼2% by volume remained). Emissions of CH 4 were measured during the following winter, spring, and summer, and compared with emissions measured the preceding 2 yr when most of the sludge had not been removed (∼14% of tank volume remained). Emissions were measured using a micrometeorological technique, utilizing open‐path CH 4 lasers. Contrary to what was hypothesized, removing the majority of sludge in fall did not delay the onset of CH 4 emissions and did not decrease emissions the following summer. In fact, annual CH 4 emissions were ∼16% higher. It is possible that fall removal provided sufficient time for microbial dynamics to be restored before the following summer when emissions were high. Future farm‐scale research should examine the effect of spring (rather than fall) emptying for on‐farm CH 4 mitigation in both concrete tanks and earthen storages. Core Ideas Pilot‐scale studies suggest that complete manure storage emptying reduces CH 4 emissions. The effect of fall sludge removal for on‐farm concrete tanks was evaluated. Sludge removal in fall did not reduce subsequent CH 4 emissions over the next 240 d. Fall removal of sludge did not delay the onset of CH 4 emissions in summer storage. Methane fluxes increased with temperature in July.
    Type of Medium: Online Resource
    ISSN: 0047-2425 , 1537-2537
    Language: English
    Publisher: Wiley
    Publication Date: 2016
    detail.hit.zdb_id: 120525-0
    detail.hit.zdb_id: 2050469-X
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