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  • 1
    Online Resource
    Online Resource
    Wiley ; 2019
    In:  physica status solidi (RRL) – Rapid Research Letters Vol. 13, No. 5 ( 2019-05)
    In: physica status solidi (RRL) – Rapid Research Letters, Wiley, Vol. 13, No. 5 ( 2019-05)
    Abstract: The efficiency in HIT (heterojunction with intrinsic thin film) solar cells strongly depends on the passivation of dangling bonds at the a‐Si:H/c‐Si interface by hydrogen, introduced during the plasma‐enhanced CVD process. Herein, controlled defects that are introduced by Ar ion irradiation have been studied. It has been observed by hard X‐ray photoemission spectroscopy (HAXPES) that during Ar ion implantation, Si–H bonds in the a‐Si:H layer are broken and become dangling bonds. The number of dangling bonds in the a‐Si:H layer has been quantified, and the electronic states associated to them have been identified, which explains previously observed photoluminescence transitions.
    Type of Medium: Online Resource
    ISSN: 1862-6254 , 1862-6270
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2019
    detail.hit.zdb_id: 2259465-6
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  • 2
    In: Small, Wiley, Vol. 19, No. 22 ( 2023-06)
    Abstract: This work reports for the first time a highly efficient single‐crystal cesium tin triiodide (CsSnI 3 ) perovskite nanowire solar cell. With a perfect lattice structure, low carrier trap density (≈5 × 10 10 cm −3 ), long carrier lifetime (46.7 ns), and excellent carrier mobility ( 〉 600 cm 2 V −1 s −1 ), single‐crystal CsSnI 3 perovskite nanowires enable a very attractive feature for flexible perovskite photovoltaics to power active micro‐scale electronic devices. Using CsSnI 3 single‐crystal nanowire in conjunction with highly conductive wide bandgap semiconductors as front‐surface‐field layers, an unprecedented efficiency of 11.7% under AM 1.5G illumination is achieved. This work demonstrates the feasibility of all‐inorganic tin‐based perovskite solar cells via crystallinity and device‐structure improvement for the high‐performance, and thus paves the way for the energy supply to flexible wearable devices in the future.
    Type of Medium: Online Resource
    ISSN: 1613-6810 , 1613-6829
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2023
    detail.hit.zdb_id: 2168935-0
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  • 3
    In: physica status solidi (a), Wiley, Vol. 218, No. 17 ( 2021-09)
    Abstract: Silicon nanowire (SiNW) radial junction (RJ) solar cells using hydrogenated microcrystalline silicon (μc‐Si:H) as absorber material have been studied. Since 2013, the performance of such RJ devices has been limited by the low fill factor (FF) and open‐circuit voltage ( V OC ). Thanks to the use of n‐type hydrogenated microcrystalline silicon oxide (μc‐SiO x :H) as a bottom doped layer, the authors developed μc‐Si:H RJ solar cells with a FF of 69.7% and a V OC of 0.41 V yielding a power conversion efficiency of 4.1%, which is more than 40% higher than the previously published efficiency record of 2.9%. Herein, the role of n‐type μc‐SiO x :H in the improvement of FF is highlighted.
    Type of Medium: Online Resource
    ISSN: 1862-6300 , 1862-6319
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2021
    detail.hit.zdb_id: 1481091-8
    detail.hit.zdb_id: 208850-2
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  • 4
    Online Resource
    Online Resource
    Wiley ; 2016
    In:  physica status solidi (a) Vol. 213, No. 7 ( 2016-07), p. 1760-1766
    In: physica status solidi (a), Wiley, Vol. 213, No. 7 ( 2016-07), p. 1760-1766
    Abstract: We evaluate the use of p‐type silicon oxide (p‐SiO x ) dielectric layers as a boron diffusion source for n‐type crystalline silicon (c‐Si) substrates. The p‐SiO x layers grown on n‐type c‐Si substrates by plasma enhanced chemical vapor deposition using a gas mixture of He/hexamethyldisiloxane/CO 2 /B 2 H 6 are thermally stable and do not peel off during annealing up to 1050 °C, making them effective diffusion sources. The layers were examined before and after annealing with characterization techniques including spectroscopic ellipsometry and secondary ion mass spectrometry. We observe that there is a reduction in the thickness of the p‐SiO x layer after annealing by about 50%, and that boron diffuses into the n‐type c‐Si substrate, forming a p + layer, limited by the formation of a carbon‐rich layer above the c‐Si surface. The concentration of holes in the diffused region was measured by the electrochemical capacitance–voltage technique, and it was found that essentially all the boron that diffused into the n‐type c‐Si was active, unaffected by the presence of carbon and oxygen atoms. The concentration of carriers can be controlled by the initial thickness of the p‐SiO x layers and the depth of the p + /n junction can be controlled by the time of annealing. A surface carrier concentration of 3 × 10 19  at cm −3 and a sheet resistance of the order of 120 Ω sq −1 was obtained upon annealing at 1050 °C for 30 min.
    Type of Medium: Online Resource
    ISSN: 1862-6300 , 1862-6319
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2016
    detail.hit.zdb_id: 1481091-8
    detail.hit.zdb_id: 208850-2
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  • 5
    In: Plasma Processes and Polymers, Wiley, Vol. 19, No. 9 ( 2022-09)
    Abstract: Compared to current c‐Si solar cell technologies, fired passivating contacts (FPCs) can reduce the thermal budget of the solar cell fabrication process. In this study, a simplified process flow for the fabrication of these contacts is investigated along with the use of two hole transport materials: p‐type nanocrystalline silicon ((p) nc‐Si:H) and nanocrystalline silicon oxide ((p) nc‐SiO x :H). More specifically, the passivation properties provided by the FPC stack are assessed at different stages of the manufacturing. The hydrogenation process is studied using in situ modulated photoluminescence (MPL) which allows to measure in real time the effective minority carrier lifetime in the sample during a process step. The increase of passivation observed during the deposition of the capping silicon‐nitride (a‐SiN x :H) layer by plasma‐enhanced chemical vapor deposition is shown to be due to both annealing of the sample and the deposition in presence of silane in the plasma, while the exposure to an NH 3 and H 2 plasma is mostly detrimental for the passivation properties. The in situ MPL measurements additionally allow us to show that the improvement of the passivation properties happens during the first few minutes of a‐SiN x :H deposition.
    Type of Medium: Online Resource
    ISSN: 1612-8850 , 1612-8869
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2022
    detail.hit.zdb_id: 2159694-3
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  • 6
    In: Progress in Photovoltaics: Research and Applications, Wiley, Vol. 26, No. 6 ( 2018-06), p. 369-376
    Abstract: Silicon heterojunction solar cells with pyramidal textured surfaces created by different etching conditions and their properties related to device efficiency (short‐circuit current density and open‐circuit voltage) are studied. An easy‐to‐apply model is proposed to estimate reflection losses, optimize the multilayer structure of the solar cell, and enhance photovoltaic conversion efficiency. The effects of etching treatments and pyramid geometry on overall device performance are discussed in detail. The study is completed by measurement of pyramid vertex angles of different textures. A difference from the expected and generally accepted theoretical value of 70.52° is demonstrated and explained based on observation from high‐resolution transmission electron microscopy. The multilayer structure of silicon heterojunction solar cells is optimized with respect to various pyramid vertex angles, using the designed optical model to minimize absorption and reflection losses.
    Type of Medium: Online Resource
    ISSN: 1062-7995 , 1099-159X
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2018
    detail.hit.zdb_id: 2023295-0
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  • 7
    Online Resource
    Online Resource
    Wiley ; 2012
    In:  physica status solidi c Vol. 9, No. 6 ( 2012-06), p. 1484-1486
    In: physica status solidi c, Wiley, Vol. 9, No. 6 ( 2012-06), p. 1484-1486
    Abstract: The exact role of hydrogen in the crystallization process is still a subject of broad controversies due to the complexity of the overall plasma enhanced chemical vapor deposition (PECVD) process. We have investigated by ellipsometry the amorphous‐to‐microcrystalline the phase transition in intrinsic and doped hydrogenated amorphous silicon (a‐Si:H) thin films during their exposure to a hydrogen plasma in conditions of chemical transport. The whole ellipsometry diagnostics reveal that, while intrinsic and phosphorus‐doped a‐Si:H present a similar trend during the plasma treatment, boron‐doped a‐Si:H differs by special features such as a rapid formation of the hydrogen–rich subsurface layer and an early amorphous‐to‐microcrystalline phase transition. The particular behavior of boron‐doped material is also pointed out through the time‐evolution of the self‐bias voltage on the radio‐frequency electrode during the hydrogen plasma treatment (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
    Type of Medium: Online Resource
    ISSN: 1862-6351 , 1610-1642
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2012
    detail.hit.zdb_id: 2105580-4
    detail.hit.zdb_id: 2102966-0
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  • 8
    In: Solar RRL, Wiley, Vol. 6, No. 8 ( 2022-08)
    Abstract: When solar cells are used as the photoanode for direct water splitting, the output voltage required typically exceeds that of a single‐junction photovoltaic device. Toward this application, in this work, triple radial junction silicon nanowire (3RJ SiNW) solar cells are fabricated via a plasma‐assisted vapor‐liquid‐solid method using hydrogenated amorphous silicon (a‐Si:H) for all the absorber layers, as well as for the doped ones. A high open‐circuit voltage ( V OC ) of 2.05 V, short‐circuit current density ( J SC ) of 3.8 mA cm −2 , and power conversion efficiency of 4.4% are obtained for solar cells with areas of 0.03 cm 2 by optimizing the density of SiNWs grown on ZnO:Al/Ag/Corning glass substrates. For lower‐efficiency devices, however, V OC values as high as 2.2 V are consistently achieved. At these higher voltages, large variations in J SC are observed, attributed to small local variations in SiNW density. Herein, for the first time, the excellent potential of 3D radial junction solar cells for applications requiring high voltages and high surface areas, such as water splitting is demonstrated.
    Type of Medium: Online Resource
    ISSN: 2367-198X , 2367-198X
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2022
    detail.hit.zdb_id: 2882014-9
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  • 9
    Online Resource
    Online Resource
    Wiley ; 2022
    In:  physica status solidi (RRL) – Rapid Research Letters Vol. 16, No. 5 ( 2022-05)
    In: physica status solidi (RRL) – Rapid Research Letters, Wiley, Vol. 16, No. 5 ( 2022-05)
    Abstract: Research on Si compatible direct bandgap semiconductors is a hot topic due to the high demand of Si compatible optoelectronics. The group IV compounds, namely GeSn, has been studied extensively in its different forms: thin films, nanowires (NWs), and nanocrystals. Importantly, the attention being paid to GeSn NWs has increased in recent years thanks to two key factors: 1) better crystalline quality due to an easier strain relaxation in NWs; and 2) extraordinary Sn content (up to 30 at.%) associated to a very fast NW growth ( 〉 20 nm s −1 ). Therefore, to effectively control the growth of GeSn NWs is a key issue for a practical application. Herein, various control aspects including the nature of the catalysts, the morphology of the NWs, and their Sn content are presented.
    Type of Medium: Online Resource
    ISSN: 1862-6254 , 1862-6270
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2022
    detail.hit.zdb_id: 2259465-6
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  • 10
    Online Resource
    Online Resource
    Wiley ; 2022
    In:  physica status solidi (RRL) – Rapid Research Letters Vol. 16, No. 12 ( 2022-12)
    In: physica status solidi (RRL) – Rapid Research Letters, Wiley, Vol. 16, No. 12 ( 2022-12)
    Abstract: Crystalline Si (c‐Si) thin films have been widely studied for their application to solar cells and flexible electronics. However, their application at large scale is limited by their fabrication process. As reviewed in this paper, many approaches have been studied, but only some of them have been made into large‐scale industrial production. The standard wire sawing of Si ingots cannot be scaled down to produce thin c‐Si wafers and films due to the brittle nature of c‐Si material, the resulting significant thickness variations, and the waste of material. Therefore, techniques based on the kerf‐less processes including “top‐down” and “bottom‐up” approaches have been developed in recent decades. In this review, photovoltaic applications of thin c‐Si wafers with thicknesses ranging from 50 μm down to 1 μm are presented first. Then, methods to fabricate c‐Si thin films based on both approaches are detailed, including slim‐cut, “smart‐cut,” epi‐free, as well as various growth processes such as molecular beam epitaxy, liquid phase epitaxy, ion beam, and chemical vapor deposition processes at a wide range of growth temperatures, from 1000 °C down to 150 °C. The advantages and disadvantages of these methods are presented and compared.
    Type of Medium: Online Resource
    ISSN: 1862-6254 , 1862-6270
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2022
    detail.hit.zdb_id: 2259465-6
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