In:
Angewandte Chemie, Wiley, Vol. 130, No. 28 ( 2018-07-09), p. 8604-8608
Abstract:
Magnetic and dielectric properties have been tuned simultaneously by external stimuli with rapid and sensitive response, which is crucial to monitor the magnetic state via capacitive measurement. Herein, positive charged Fe II ions were linked via negative charged [(Tp)Fe III (CN) 3 ] − (Tp=hydrotris(pyrazolyl)borate) units to form a neutral chain. The spin‐crossover (SCO) on Fe II sites could be sensitively triggered via thermal treatment, light irradiation, and pressure. SCO switched the spin state of the Fe II ions and antiferromagnetic interactions between Fe III and Fe II ions, resulting in significant change in magnetization. Moreover, SCO induced rotation of negative charged [(Tp)Fe III (CN) 3 ] − units, generating dielectric anomaly due to geometric change of charges distribution. This work provides a rational way to manipulate simultaneous variations in magnetic and dielectric properties utilizing SCO as an actuator to tune spin arrangement, magnetic coupling, and charge distribution.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.v130.28
DOI:
10.1002/ange.201802774
Language:
English
Publisher:
Wiley
Publication Date:
2018
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