In:
Zeitschrift für Naturforschung B, Walter de Gruyter GmbH, Vol. 43, No. 8 ( 1988-8-1), p. 927-932
Abstract:
Several fortuitous preparations and high yield rational syntheses for [(Me 3 P) 2 M(PMe 2 )]: (1: M = Co; 2: M = Ni) are described. 1 crystallizes in the space group P1̄ (no. 2); a = 975.6(5). b = 943.6(5), c - 904.2(5) pm. α= 63.8(1)°, β = 79.1(1)°, γ = 72.8(1)°. Mixed metal complexes L 2 Co(PR 2 ) 2 NiL 2 (L = PMe 3 ; R = Me, Ph) evaded detection giving symmetric products exclusively. An improved synthesis of LiP(C 6 H 5 ) 2 ·dioxane is also described.
Type of Medium:
Online Resource
ISSN:
1865-7117
,
0932-0776
DOI:
10.1515/znb-1988-0801
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
1988
detail.hit.zdb_id:
2078109-X
detail.hit.zdb_id:
124635-5
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