In:
Zeitschrift für Naturforschung B, Walter de Gruyter GmbH, Vol. 77, No. 7-8 ( 2022-07-26), p. 555-559
Abstract:
A new coordination polymer {[Cd(BIPA)(DCPS)](H 2 O)} n ( 1 ) was constructed with bis(4-(1H-imidazole-1-yl)phenyl)amine and 4,4′-sulfonyldibenzoate ligands. The complex 1 features (BIPA–Cd–BIPA) n and (DCPS–Cd–DCPS) n helical chains in a 3D architecture assembled via hydrogen bonds. A spectroscopic study of complex 1 in the crystalline state showed an intense red-shifted photoluminescence as compared with the ligands BIPA and DCPS 2− , which can be attributed to the ligand-to-metal charge transfer (LMCT) transitions.
Type of Medium:
Online Resource
ISSN:
0932-0776
,
1865-7117
DOI:
10.1515/znb-2022-0023
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
2022
detail.hit.zdb_id:
2078109-X
detail.hit.zdb_id:
124635-5
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