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  • Trans Tech Publications, Ltd.  (2)
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  • Trans Tech Publications, Ltd.  (2)
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  • 1
    Online Resource
    Online Resource
    Trans Tech Publications, Ltd. ; 2013
    In:  Advanced Materials Research Vol. 825 ( 2013-10), p. 92-95
    In: Advanced Materials Research, Trans Tech Publications, Ltd., Vol. 825 ( 2013-10), p. 92-95
    Abstract: Nanostructure forms of semiconductor materials are of great interest. Among these compounds, copper sulfide as a variable stoichiometric composition attracts considerable attention. In the present study, copper sulfide nanoparticles were synthesized biologically from a chalcopyrite concentratemainly containing chalcopyrite (46%) and pyrite (23%). Firstly, the copper contents of the concentrate were bioleached using thermophile bacteria, then the grown Fusarium oxysporum was added to the prepared solution and the biosynthesized nanoparticles collected and their characteristics compared with the product derived from the pure copper sulfate solution. The characterization was performed by UV spectrometry, Fourier Transform Infrared Spectroscopy (FTIR), Energy Dispersive X-ray Spectroscopy (EDS), Thermogravimetery (TG), Differential Scanning Calorimetery (DSC), Mass Spectrometery (MS), and Transmission Electron Microscopy (TEM). Finally, it wasproved that the produced nanoparticles had a covellite composition and their size was about 5-40 nm.
    Type of Medium: Online Resource
    ISSN: 1662-8985
    URL: Issue
    Language: Unknown
    Publisher: Trans Tech Publications, Ltd.
    Publication Date: 2013
    detail.hit.zdb_id: 2265002-7
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  • 2
    Online Resource
    Online Resource
    Trans Tech Publications, Ltd. ; 2017
    In:  Solid State Phenomena Vol. 262 ( 2017-8), p. 16-19
    In: Solid State Phenomena, Trans Tech Publications, Ltd., Vol. 262 ( 2017-8), p. 16-19
    Abstract: The objective of this study is to improve the understanding of copper sulfides dissolution and to use this knowledge for optimization of process parameters for commercial application of electrochemical bioleaching of chalcopyrite concentrates in stirred bioreactors. From the results of this study, the importance of the oxidation reduction potential (ORP) on the catalytic interaction between chalcopyrite and pyrite can be pointed out as the main parameters for successful bioprocessing of chalcopyrite concentrates. Under these conditions, the optimization of the average particle size of feed (D80) and adjusting the ORP in the range between 400-450 mV are important criteria for increasing the electrochemical bioleaching rate of chalcopyrite concentrates. It seems that the main reason for the increased copper recovery could be the control and prevention of chalcopyrite passivation resulting from improved galvanic interaction between copper sulfide minerals, here especially chalcopyrite and pyrite in the selected ORP range and the right particle size distribution of feed. At optimum conditions, the copper extraction from chalcopyrite flotation concentrate during 7 days of continuous electrochemical bioleaching operations in stirred tanks was about 95%, which should be high enough to justify the process economically.
    Type of Medium: Online Resource
    ISSN: 1662-9779
    URL: Issue
    Language: Unknown
    Publisher: Trans Tech Publications, Ltd.
    Publication Date: 2017
    detail.hit.zdb_id: 2051138-3
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