In:
Advanced Materials Research, Trans Tech Publications, Ltd., Vol. 781-784 ( 2013-9), p. 531-535
Abstract:
A new cocrystal (3,4-Hbpt)-(H 2 oba) (3,4-Hbpt =3-(3-pyridyl)-5-(4-pyridyl)- 1-H-1,2,4-triazole and H 2 oba=4,4-oxybis (benzoic acid)), was prepared via self-assembly in the presence of cobalt acetate as template by hydrothermal reactions. The title complex was characterized by single-crystal X-ray diffraction, elemental analysis and IR spectroscopy. Structural analysis reveals that the complex belongs to monoclinic system, space group P2 1 /c. The two carboxylate groups from H 2 oba are not deprotonated and form two kinds of strong intermolecular hydrogen bonds with 3,4-Hbpt, which linking the molecules into one-dimensional chains. Furthermore, the one-dimensional chains are connected by the hydrogen bond interaction to form two-dimensional lamellar structures. Intermolecular hydrogen bonds may be effective in the stabilization of the crystal structure.
Type of Medium:
Online Resource
ISSN:
1662-8985
DOI:
10.4028/www.scientific.net/AMR.781-784
DOI:
10.4028/www.scientific.net/AMR.781-784.531
Language:
Unknown
Publisher:
Trans Tech Publications, Ltd.
Publication Date:
2013
detail.hit.zdb_id:
2265002-7
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