In:
Advanced Materials Research, Trans Tech Publications, Ltd., Vol. 233-235 ( 2011-5), p. 2808-2811
Abstract:
2,3-bis(2-pyridyl)-5,6-dihydropyrazine and a protonated phenanthroline (Phen) have been synthesized and the structure of protonated Phen is established by X-ray diffraction single crystal structure analysis. The coordination reactions of Phen, 2,2'- bipyridine and 2,3-bis(2-pyridyl)-5,6-dihydropyrazine with rare earth ions in low pH have been studied. The results show that 2,3-bis(2-pyridyl)-5,6-dihydropyrazine is hydrolyzed to be 2,2’-pyridil and protonated ethylenediamine. Meanwhile, Phen combines with proton, which results that nitrogen atoms can not coordinate with rare earth ions. The molecular formula of protonated Phen is C 12 H 8 N 2 HCl·H 2 O. It crystallizes in the triclinic space group P -1 (2), with a = 7.1212(14) Å, b = 7.2786(15) Å, c = 20.817(4) Å, α = 90.00º, β = 96.69(3) º, γ = 90.00 º, V = 1071.65(379) Å 3 , Z = 4.
Type of Medium:
Online Resource
ISSN:
1662-8985
DOI:
10.4028/www.scientific.net/AMR.233-235
DOI:
10.4028/www.scientific.net/AMR.233-235.2808
Language:
Unknown
Publisher:
Trans Tech Publications, Ltd.
Publication Date:
2011
detail.hit.zdb_id:
2265002-7
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