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  • The Electrochemical Society  (2)
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  • The Electrochemical Society  (2)
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  • 1
    Online Resource
    Online Resource
    The Electrochemical Society ; 2022
    In:  ECS Journal of Solid State Science and Technology Vol. 11, No. 7 ( 2022-07-01), p. 071010-
    In: ECS Journal of Solid State Science and Technology, The Electrochemical Society, Vol. 11, No. 7 ( 2022-07-01), p. 071010-
    Abstract: A pure MnO 2 cube and MnO 2 cube/r-GO nanocomposite were synthesized by the simple hydrothermal method. The structural formation, morphological and chemical composition of as-prepared MnO 2 cube/r-GO nanocomposite were characterized by powder X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). The FE-SEM and TEM images were revealed that the MnO 2 cubes are homogeneously distributed on the surface of r-GO nanosheets. The electrochemical results showed that the high specific capacitance of MnO 2 cube/r-GO nanocomposite was 1570 F g −1 at a current density of 2 A g −1 in 1 M Na 2 SO 4 electrolyte solution. The long life-term cycling performance of MnO 2 cube/r-GO nanocomposite were delivered at outstanding capacitance retention of 99.3% subsequently 10,000 charge-discharge cycles at 8 A g −1 . Moreover, we construct the asymmetric supercapacitor (ASC) of MnO 2 /r-GO//r-GO for practical application. Herein, MnO 2 /r-GO act as an anode material and r-GO as a cathode material. The assembled device shows a high specific capacitance of 92.49 F g −1 at 1 A g −1 , high power density of 1.5860 W kg −1 , and a high energy density of 17.7555 Wh kg −1 at 8 A g −1 . Furthermore, the ASC device exhibits excellent capacitance retention of 98% after 10000 sequential charge-discharge cycles in 1 M Na 2 SO 4 electrolyte solution. Based on the electrochemical performance as-prepared MnO 2 cube/r-GO nanocomposite considered as the potential electrode material for energy storage application.
    Type of Medium: Online Resource
    ISSN: 2162-8769 , 2162-8777
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2022
    Location Call Number Limitation Availability
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  • 2
    Online Resource
    Online Resource
    The Electrochemical Society ; 2022
    In:  ECS Journal of Solid State Science and Technology Vol. 11, No. 9 ( 2022-09-01), p. 091001-
    In: ECS Journal of Solid State Science and Technology, The Electrochemical Society, Vol. 11, No. 9 ( 2022-09-01), p. 091001-
    Abstract: Herein, we offer the study on the conductive polymer of polypyrrole and iron oxide (Fe 2 O 3 @PPy) nanocomposites, which are prepared via a simple chemical oxidation method for energy storage applications. The synthesized nanocomposites are confirmed by the physico-chemical properties through Fourier Transform Infra-red Spectroscopy (FTIR), X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM) and X-ray Photoelectron Spectroscopy (XPS) results along with Electrochemical Impedance Spectroscopy (EIS), Cyclic Voltammetry (CV), Galvanostatic Charge–Discharge (GCD) and stability analyses. The surface morphological studies of SEM and high TEM images substantiated the formation of Fe 2 O 3 @PPy nanocomposite via the polymerization process. The prepared Fe 2 O 3 @PPy nanocomposites deliver at a specific capacity of 395.45 C g −1 at 5 mV s −1 scan rate. Moreover, Fe 2 O 3 @PPy nanocomposite shows outstanding cycling stability of capacity 94.3% even after 10000 cycles of charge-discharge at the highest current density value of 10 A g −1 . The remarkable electrochemical energy storage manner of as-synthesized Fe 2 O 3 @PPy nanocomposite is considered a potential electrode for supercapacitor application. The higher electrochemical performance of this Fe 2 O 3 @PPy nanocomposite it’s suitable for numerous applications like batteries, sensors, photocatalysts, solar cells and commercial requirements.
    Type of Medium: Online Resource
    ISSN: 2162-8769 , 2162-8777
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2022
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
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