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  • The Electrochemical Society  (5)
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  • The Electrochemical Society  (5)
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  • 1
    Online Resource
    Online Resource
    The Electrochemical Society ; 2007
    In:  Journal of The Electrochemical Society Vol. 154, No. 7 ( 2007), p. J185-
    In: Journal of The Electrochemical Society, The Electrochemical Society, Vol. 154, No. 7 ( 2007), p. J185-
    Type of Medium: Online Resource
    ISSN: 0013-4651
    RVK:
    Language: English
    Publisher: The Electrochemical Society
    Publication Date: 2007
    detail.hit.zdb_id: 219244-5
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  • 2
    Online Resource
    Online Resource
    The Electrochemical Society ; 2021
    In:  ECS Transactions Vol. 103, No. 1 ( 2021-07-09), p. 201-209
    In: ECS Transactions, The Electrochemical Society, Vol. 103, No. 1 ( 2021-07-09), p. 201-209
    Abstract: Solid Oxide Fuel Cells (SOFCs) provides an efficient and clean pathway to generate electricity. In addition to hydrogen, SOFCs also hold the possibility for the utilization of a variety of carbon containing fuels. A practical kilowatt-class SOFC system fueled by methane has been preliminarily integrated previously. This study intended to obtain the optimized working conditions for the pre-reformer, with which the SOFC module can exhibit higher electrical performance. Detailed thermodynamic analysis and experimental measurements of steam methane reforming (SMR) were carried out under different steam to carbon ratios (S/C) and temperatures, where the experimental results matched well with the thermodynamic calculation. Based on the optimized working condition of SMR, the electrical performance and stability of a planar single-layer stack (10×10 cm 2 ) fueled by the reformate syngas was evaluated. The maximum electrical efficiency reached 65.39% (LHV) at 750ºC, and 50-hour stable operation under 50% (LHV) electrical efficiency was achieved.
    Type of Medium: Online Resource
    ISSN: 1938-5862 , 1938-6737
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2021
    detail.hit.zdb_id: 2217591-X
    detail.hit.zdb_id: 2251888-5
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  • 3
    Online Resource
    Online Resource
    The Electrochemical Society ; 2021
    In:  ECS Transactions Vol. 103, No. 1 ( 2021-07-09), p. 861-871
    In: ECS Transactions, The Electrochemical Society, Vol. 103, No. 1 ( 2021-07-09), p. 861-871
    Abstract: Heat and electricity are deeply coupled in solid oxide fuel cell (SOFC) stacks, and the balance and control between them are vital to the steady working condition and outputs. Therefore, studying the balance mechanism of heat and electricity is important to achieve the safe and stable operation of the SOFC stacks. In this paper, a semi-empirical simulation model of a kilowatt-level SOFC stack was established. Based on this model, the effects of different operating temperatures, flow rates, air to H 2 ratios (AHR), and steam to carbon (S/C) ratios on the thermoelectric balance state of the SOFC stack were analyzed. Results show that the I-V curve can be separated into three parts: unbalance zone, unsustainable zone, and the self-heat balance zone by the self-heat balance voltage (SHBV) and the critical voltage (CV). The approximate voltage scope of the balance zone under different conditions is 0.6~0.9 V.
    Type of Medium: Online Resource
    ISSN: 1938-5862 , 1938-6737
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2021
    detail.hit.zdb_id: 2217591-X
    detail.hit.zdb_id: 2251888-5
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  • 4
    Online Resource
    Online Resource
    The Electrochemical Society ; 2021
    In:  ECS Meeting Abstracts Vol. MA2021-03, No. 1 ( 2021-07-23), p. 158-158
    In: ECS Meeting Abstracts, The Electrochemical Society, Vol. MA2021-03, No. 1 ( 2021-07-23), p. 158-158
    Abstract: Solid oxide fuel cells (SOFC) can directly convert chemical energy into electrical energy with high power generation efficiency. However, the power generation process is always accompanied by the release of heat, and the balance of heat and electricity is important to the safe and stable operation of the SOFC stack. In this paper, a semi-empirical model of a kilowatt-level SOFC stack was established based on the experiment data that was operated in Xuzhou HuaTsing Jingkun Energy Co. Ltd. Based on this model, the effects of different operating temperatures, fuel and air flow rates, air-to-hydrogen ratio and other factors on the thermoelectric balance were analyzed with hydrogen fuel. In addition, methanol was also selected to study the thermo-electric balance performance. The results shows that the SOFC stack would meet the thermal balance on a special voltage, called self-heating balance voltage, but which varies under different conditions. With the increase of the fuel and air flow rates, the self-heating balance voltage and the limited voltage that shows the heat is surpass the power are decreases clearly. However, the self-heating balance voltage and the limited voltage changes differently under different air-to-hydrogen ratios. The air-to-hydrogen ratio enlarges from 2.4 to 3.6, the self-heating balance voltage and the limited voltage decreases by -4.14% and -2.42% by increasing air rates, however changes 1.26% and -3.07% by decreasing hydrogen rates, respectively.
    Type of Medium: Online Resource
    ISSN: 2151-2043
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2021
    detail.hit.zdb_id: 2438749-6
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  • 5
    Online Resource
    Online Resource
    The Electrochemical Society ; 2021
    In:  ECS Meeting Abstracts Vol. MA2021-03, No. 1 ( 2021-07-23), p. 31-31
    In: ECS Meeting Abstracts, The Electrochemical Society, Vol. MA2021-03, No. 1 ( 2021-07-23), p. 31-31
    Abstract: Abstract: Solid Oxide Fuel Cells (SOFCs) is an efficient and clean pathway to generate electricity. In addition to hydrogen, SOFCs also provide the possibility for the utilization of a variety of carbon containing fuels. However, the application of carbon-based fuels in SOFC remains to be further studied. In this study, an external reformer was used to create appropriate reforming syngas from methanol and avoid carbon deposition. The performance and the efficiency of SOFC were researched with methanol-reformed syngas as fuel. The thermodynamic calculation and experimental work of water vapor reforming reaction of methanol fuel were carried out to study the composition of reforming gas under different temperature and steam-carbon ratio conditions, where the experimental results and the computational results matched well. The mole fraction of hydrogen in reformed syngas was about 55% within the temperature of 700~800 ℃, nevertheless, this value reached 70% if the moisture was removed. Therefore, the reformed syngas should be applied to SOFCs before being condensed and dried. Based on the comparison between the experimental results and the calculated ones, the appropriate components were selected to prepare the reforming syngas, feeding into the anode of SOFC to test the performance and the efficiency. Optimal temperature and steam-carbon ratio conditions for methanol vapor reforming were obtained. Under these conditions, the power density of SOFC exceeded 0.4 W/cm 2 and the efficiency reached 50% (LHV). The main conclusions confirmed the high efficiency and feasibility of the methanol-fueled SOFC power generation system.
    Type of Medium: Online Resource
    ISSN: 2151-2043
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2021
    detail.hit.zdb_id: 2438749-6
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