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  • The Electrochemical Society  (12)
  • 1
    Online Resource
    Online Resource
    The Electrochemical Society ; 2019
    In:  ECS Journal of Solid State Science and Technology Vol. 8, No. 7 ( 2019), p. Q3041-Q3045
    In: ECS Journal of Solid State Science and Technology, The Electrochemical Society, Vol. 8, No. 7 ( 2019), p. Q3041-Q3045
    Type of Medium: Online Resource
    ISSN: 2162-8769 , 2162-8777
    Language: English
    Publisher: The Electrochemical Society
    Publication Date: 2019
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  • 2
    Online Resource
    Online Resource
    The Electrochemical Society ; 2019
    In:  ECS Journal of Solid State Science and Technology Vol. 8, No. 12 ( 2019), p. P799-P804
    In: ECS Journal of Solid State Science and Technology, The Electrochemical Society, Vol. 8, No. 12 ( 2019), p. P799-P804
    Type of Medium: Online Resource
    ISSN: 2162-8769 , 2162-8777
    Language: English
    Publisher: The Electrochemical Society
    Publication Date: 2019
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  • 3
    Online Resource
    Online Resource
    The Electrochemical Society ; 2020
    In:  ECS Journal of Solid State Science and Technology Vol. 9, No. 2 ( 2020-02-10), p. 025003-
    In: ECS Journal of Solid State Science and Technology, The Electrochemical Society, Vol. 9, No. 2 ( 2020-02-10), p. 025003-
    Type of Medium: Online Resource
    ISSN: 2162-8777
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2020
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  • 4
    Online Resource
    Online Resource
    The Electrochemical Society ; 2021
    In:  ECS Meeting Abstracts Vol. MA2021-02, No. 35 ( 2021-10-19), p. 1910-1910
    In: ECS Meeting Abstracts, The Electrochemical Society, Vol. MA2021-02, No. 35 ( 2021-10-19), p. 1910-1910
    Type of Medium: Online Resource
    ISSN: 2151-2043
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2021
    detail.hit.zdb_id: 2438749-6
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  • 5
    Online Resource
    Online Resource
    The Electrochemical Society ; 2020
    In:  ECS Meeting Abstracts Vol. MA2020-01, No. 23 ( 2020-05-01), p. 1329-1329
    In: ECS Meeting Abstracts, The Electrochemical Society, Vol. MA2020-01, No. 23 ( 2020-05-01), p. 1329-1329
    Abstract: β-Ga 2 O 3 is a next-generation semiconductor material having ultra-wide bandgap energy of 4.8 eV and excellent electrical properties. So it is expected to be suitable for various applications such as power electronics, solar-blind UV photodetectors and gas sensors. However, there are some issues to overcome in order for β-Ga 2 O 3 to be commercialized. Among them, crystal defects are important factor that significantly affects device performance. Defects are formed intrinsically during the growth process, or caused by high-energy plasma ion during dry etching. It has been reported that the electrical characteristics are deteriorated in the device such as MOSFET and MISFET fabricated by inductively coupled plasma etching. Unlike dry etching, which can cause damage by plasma ions, wet etching is a damage-free process that uses a chemical reaction between the target material and etchant. In addition, wet etching may be used for removing defects by using the etching characteristic, which the chemically unstable defect areas are preferentially etched. However, β-Ga 2 O 3 hardly reacts with etchant at room temperature, and has been reported to have etch rate of several tens of nm/min when acid etchant are used at higher than 100 °C. In our study, we have tried to increase the etch rate of β-Ga 2 O 3 and remove defects effectively by Photo-electrochemical (PEC) etching. PEC etching is a method that promotes the reaction by irradiated light having energy above bandgap and applied external bias. Single crystalline β-Ga 2 O 3 thin films are cleaved in the [100] direction with mechanical force from single crystalline β-Ga 2 O 3 substrate. Ti/Au was deposited to form Ohmic contact with β-Ga 2 O 3 thin films. With the PEC etching method, we could etch at a lower temperature than conventional wet etching. In addition, it was confirmed that the etch rate can be controlled according to the external bias condition. The details of our experiment conditions and results will be presented at the meeting.
    Type of Medium: Online Resource
    ISSN: 2151-2043
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2020
    detail.hit.zdb_id: 2438749-6
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  • 6
    Online Resource
    Online Resource
    The Electrochemical Society ; 2022
    In:  Journal of The Electrochemical Society Vol. 169, No. 6 ( 2022-06-01), p. 063517-
    In: Journal of The Electrochemical Society, The Electrochemical Society, Vol. 169, No. 6 ( 2022-06-01), p. 063517-
    Abstract: The progress of artificial synaptic devices is vital to the realization of the consciousness of effectual bioinspired neuromorphic computing systems. In this study, we fabricated an ITO/ZnO/PTAA/Ag artificial synaptic memristor based on a low-cost solution process. The fabricated device exhibited uniform gradual bipolar resistive switching with excellent endurance and self-rectifying behavior owing to the bilayer heterojunction structure of ZnO/PTAA. The growth of the conducting filament can be efficiently controlled by modulating the current compliance and voltage during the SET process. Modification of conductance states was also observed by simulations to stimuli, which are essential for synaptic function in neuromorphic computing. Various pulse measurements were performed to mimic synaptic behaviors, including long-term potentiation, long-term depression, spike-rate-dependent plasticity, paired-pulse facilitation, and post-tetanic potentiation. Moreover, we reveal that the real device shows an approximately similar pattern recognition rate as the ideal device owing to a more uniform conductance update.
    Type of Medium: Online Resource
    ISSN: 0013-4651 , 1945-7111
    RVK:
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2022
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  • 7
    Online Resource
    Online Resource
    The Electrochemical Society ; 2019
    In:  ECS Meeting Abstracts Vol. MA2019-01, No. 26 ( 2019-05-01), p. 1291-1291
    In: ECS Meeting Abstracts, The Electrochemical Society, Vol. MA2019-01, No. 26 ( 2019-05-01), p. 1291-1291
    Abstract: Hexagonal boron nitride (h-BN) is widely used as a two-dimentional (2D) insulating material. Owing to its high breakdown field (8-12 MV/cm), wide band gap (5.2-5.9 eV), and thermal⋅chemical stability, h-BN is employed as a dielectric layer of 2D integrated electronic device. Unlike to other insulating materials, h-BN has an atomically flat surface free from the dangling bond at the interface. Therefore, it is less affected by trap charges and mismatch of the lattice structure. Without any complicated process, it is possible to obtain an atomically thin flake by mechanical exfoliation and is easy to apply to extremely thin electronic device application such as field effect transistor and complementary metal-oxide semiconductor. Dielectric layer of semiconductor device must maintain its insulating property in extreme condition. It is of great importance to find out the breakdown field to ensure the stability of the device. However, the atoms constituting the lattice of the insulator can be damaged by protons, heavy ions and cosmic rays. These rays make an irreversible degradation on the insulating materials, and the destruction of the lattice structure can be accompanied. It poses a critical hazard on the performance of the device in that degradation of insulator lead to lower the breakdown field of dielectric layer. Measurement of changes of the breakdown field by radiation can define the safe operating voltage range of the device. H-BN is a next-generation insulating material, but the effect of radiation on h-BN has not been fully studied. In this work, we quantitatively analyzed the damage on h-BN and effect on breakdown field from varying proton-ray irradiation conditions. We fabricated pre-patterned source/drain electrode of Ti/Au on a Si/SiO 2 wafer. A thin h-BN flake was mechanically exfoliated from the high-crystalline h-BN bulk crystal. Prepared flakes were transferred to the substrate by dry transfer method. We employed atomic force microscope to measure the thickness of h-BN. H-BN flakes were proton-irradiated under varying condition of power (5MeV, 10MeV) and fluence (1×10 13 , 5×10 13 ). To measure breakdown field, graphene was used as a top electrode on h-BN to creat a vertical structure. We proceeded a electrical measurement to find out the hard breakdown field of pristine and irradiated h-BN flakes respectively. Mean value of the breakdown field of pristine h-BN flakes is 10.532 MV/cm, comparable with value of reported exfoliated h-BN. Whereas the breakdown field of proton-irradiated h-BN flakes ranged from 1 to 7 MV/cm. We used density functional theory and molecular dynamics simulation to estimate the mechanism of damaging on the lattice structure of h-BN. Proton irradiation causes irreversible degradation on atomic structure of h-BN, such as interstitial or vacant defects. This triggered a sudden current jump and failure at a lower voltage. We can enable more stable operation by considering the expected breakdown field of the device under the condition of radiation. Details of our work will be discussed in the presentation.
    Type of Medium: Online Resource
    ISSN: 2151-2043
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2019
    detail.hit.zdb_id: 2438749-6
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  • 8
    Online Resource
    Online Resource
    The Electrochemical Society ; 2020
    In:  ECS Journal of Solid State Science and Technology Vol. 9, No. 3 ( 2020-03-26), p. 035008-
    In: ECS Journal of Solid State Science and Technology, The Electrochemical Society, Vol. 9, No. 3 ( 2020-03-26), p. 035008-
    Type of Medium: Online Resource
    ISSN: 2162-8777
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2020
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  • 9
    Online Resource
    Online Resource
    The Electrochemical Society ; 2021
    In:  ECS Journal of Solid State Science and Technology Vol. 10, No. 12 ( 2021-12-01), p. 125004-
    In: ECS Journal of Solid State Science and Technology, The Electrochemical Society, Vol. 10, No. 12 ( 2021-12-01), p. 125004-
    Abstract: 2-dimensional (100) plane β phase Ga 2 O 3 ( β -Ga 2 O 3 ) flake based field effect transistor (FET) was fabricated, and its electrical characteristics was analyzed. The (100) plane β -Ga 2 O 3 flake was mechanically exfoliated from the side wall of 2 ¯ 01 plane β -Ga 2 O 3 bulk substrate. The minimum thickness of 57.3 nm was obtained for the very thin (100) plane β -Ga 2 O 3 channel layer of the FET using inductively coupled plasma etching with BCl 3 /N 2 chemistry. The current-voltage characteristics of the FET with various β -Ga 2 O 3 channel thickness was investigated. The dependence of the channel thickness on the drain current density, threshold voltage, transconductance, and field effect mobility was studied. The hydrogen response of the (100) plane Ga 2 O 3 flake based FET with catalytic Pt gate surface was measured in the range of 10–500 ppm at 400 °C, and modeled with a dissociative Langmuir isotherm. The device showed a reliable responsivity to the different concentration of hydrogen exposure, and the responsivity of 25.02% was observed for the 500 ppm hydrogen at 400 °C.
    Type of Medium: Online Resource
    ISSN: 2162-8769 , 2162-8777
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2021
    Location Call Number Limitation Availability
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  • 10
    Online Resource
    Online Resource
    The Electrochemical Society ; 2019
    In:  ECS Meeting Abstracts Vol. MA2019-01, No. 26 ( 2019-05-01), p. 1266-1266
    In: ECS Meeting Abstracts, The Electrochemical Society, Vol. MA2019-01, No. 26 ( 2019-05-01), p. 1266-1266
    Abstract: β-Ga 2 O 3 is an intriguing material for high efficiency power devices because of its large direct bandgap (4.85 eV), high breakdown field (~8 MV/cm) and excellent thermal and chemical stability. Baliga’s figure of merit of β-Ga 2 O 3 is 3214.1, superior to those of other materials such as GaN (846.0) or SiC (317.1). Interestingly, although β-Ga 2 O 3 is not a van der Waals material, β-Ga 2 O 3 can be mechanically exfoliated from single crystal substrate into thin layer due to the large anisotropy of the unit cell. The fabrication of high crystal quality β-Ga 2 O 3 nanolayer devices could pave a way for next-generation high-power nanoelectronics devices. In power device operation, the premature electrical induced by the concentrated electric fields limits the device operation under a high bias voltage, and threaten the reliability of devices. Various techniques such as recess gate or field-plate configurations have been proposed to relieve the electric field concentration and prevent premature breakdown. Adopting gate field plate, source field plate, or multiple field plate greatly enhance the performance of power devices, which can be applied to β-Ga 2 O 3 based nanoelectronic power devices that can unlock the full potential of β-Ga 2 O 3 . Due to the exceptional mechanical and electronic properties of 2D materials, researches about 2D materials has been at the forefront of this area during the last years. Studies on fabrication of functional devices based on 2D materials, including integration with themselves, are exploding. Among 2D materials, hexagonal boron nitride (h-BN) has been used as a dielectric material of 2D devices due to its excellent thermal conduc tivity (1700 – 2000 W/m∙K) and high dielectric constant (8 – 12 MV/cm), as well as defect-free and atomically flat surface, which can easily be obtained through mechanical exfoliation method. In our work, we used h-BN as a gate field plate dielectric layer by precise and selective transfer on β-Ga 2 O 3 channel by using PDMS film. SiO 2 dielectric layer was deposited on devices, followed by metal deposition for source field plate. By applying dual field plate structure β-Ga 2 O 3 based power devices can show excellent performance in high voltage condition than conventional metal-semiconductor field effect transistors (MESFETs). β-Ga 2 O 3 MESFETs with h-BN gate field plate were fabricated by using the β-Ga 2 O 3 and h-BN flakes obtained from respective crystals. Ohmic metal (Ti/Au) was deposited on both end of mechanically exfoliated β-Ga 2 O 3 flakes, followed by precise positioning of exfoliated h-BN flakes on the channel. Top-gate electrode (Ni/Au) was deposited to fabricate β-Ga 2 O 3 MESFETs, with a part of the electrode overlapped with h-BN to achieve a stepped gate field-plate structure. After deposition of SiO 2 layer as dielectric layer of source field plate, selective etching of SiO 2 layer was performed to construct source field plate structure. Fabricated β-Ga 2 O 3 MESFETs showed excellent n-type DC output and transfer characteristics even after storage for one month in ambient air, which shows excellent long-term air-stability. Three-terminal off-state breakdown voltage of dual field-plated β-Ga 2 O 3 MESFET was measured, which shows improvement in breakdown voltage compared with that of conventional β-Ga 2 O 3 MESFET. The distribution of electric fields was calculated by Silvaco Atlas device simulation framework to study the effect of source field plate and h-BN gate field plate on electric field, which explain the improvement of breakdown voltage in those structure. By adopting dual field plate structure, ease of distribution of concentrated electric field was observed. In this study, we present that the performance of β-Ga 2 O 3 MESFET as a power device can be greatly improved by adopting dual field plate structure, paving a way to the high-power nanoelectronic devices of β-Ga 2 O 3 . The details of our work will be discussed in the conference.
    Type of Medium: Online Resource
    ISSN: 2151-2043
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2019
    detail.hit.zdb_id: 2438749-6
    Location Call Number Limitation Availability
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