ISSN:
1572-8870
Keywords:
Anionic polymerization
;
block copolymer
;
ring-opening polymerization
;
poly(ferrocene)
;
nanostructures
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The novel block copolymers, polystyrene-b-poly(ferrocenylphosphine) and polyisoprene-b-poly(ferrocenylphosphine), were synthesized by anionic polymerization, utilizing the living organic anions to initiate the ring-opening polymerization of a phosphorus-bridged [1]ferrocenophane. The resulting block copolymers possess narrow polydispersities and have potentially coordinating phosphorus sites in the polymer backbone. These materials are of interest as precursors to metallized self-assembled nanoscale architectures.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1021484010088
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